• 제목/요약/키워드: Absorption

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Absorption of Carbon Dioxide into Aqueous AMP Solutions

  • Won Seob So;Don
    • 한국환경과학회지
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    • 제2권1호
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    • pp.79-84
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    • 1993
  • The rates of absorption of carbon dioxide into aqueous solutions of 2-amino-2-methyl-1 propanol (AMP) were measured using a semibatch stirred vessel with a plane gas-liquid interface at $25^{\circ}C$. The absorption rates under the fast reaction regime were analysed using chemical absorption theory. The reaction was found to be first order with respect to both $CO_2$ and the amine.

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Automatic Detection of Absorption Features for Hyperspectral Images

  • Hsu, Pai-Hui;Tseng, Yi-Hsing
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 2003년도 Proceedings of ACRS 2003 ISRS
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    • pp.700-702
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    • 2003
  • A new method for automatic detection of absorption features is proposed. This method is based on the modulus maximum of the scale-space image calculated by continuous wavelet transform. This method is computationally efficient as compared to traditional methods. The continuum removal algorithm is than implemented on the detected absorption features to reduce some additive factors caused by other absorbing of materials. The results show that the chlorophyll absorption features are detected exactly.

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Remarks on Single-Frequency Two-Photon Absorption$^\dag$

  • Lee, Duck-Hwan
    • Bulletin of the Korean Chemical Society
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    • 제8권4호
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    • pp.338-340
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    • 1987
  • The single-frequency two-photon absorption tensor is carefully rederived and examined. It is pointed out that the conventionally used tensor, which has been formally deduced from the different-frequency two-photon absorption tensor, can give an incorrect absolute two-photon absorption rate. The identity forbidded selection rule and the polarization ratio expressions are also examined with the new tensor.

다파장 Dual-spot Aethalometer를 이용한 갈색탄소의 광흡수계수 평가 (Estimation of Light Absorption by Brown Carbon Particles using Multi-wavelength Dual-spot Aethalometer)

  • 유근혜;유재명;박승식
    • 한국대기환경학회지
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    • 제34권2호
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    • pp.207-222
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    • 2018
  • In this study, light absorption of carbonaceous species in $PM_{2.5}$ was investigated using a dual-spot 7-wavelength Aethalometer(model AE33) with 1-min time interval between January 01 and September 30, 2017 at an urban site of Gwangju. During the study period, two Asian dust (AD) events occurred in April (AD I) and May (AD II), respectively, during which light absorption in total suspended particles was observed. Black carbon (BC) was the dominant light absorbing aerosol component at all wavelengths over the study period. Light absorption coefficients by aerosol particles were found to have 2.7~3.3 times higher at 370 nm than at 880 nm. This would be attributed to light absorbing organic aerosols, which is called brown carbon (BrC), as well as BC as absorbing agents of aerosol particles. Monthly average absorption ${{\AA}}ngstr{\ddot{o}}m$ exponent ($AAE_{370-950nm}$) calculated over wavelength range of 370~950 nm ranged from 1.10 to 1.35, which was lower than the $AAE_{370-520nm}$ values ranging from 1.19~1.68 that was enhanced due to the presence of BrC. The estimated $AAE_{370-660nm}$ of BrC ranged from 2.2 to 7.5 with an average of 4.22, which was fairly consistent to the values reported by previous studies. The BrC absorption at 370 nm contributed 10.4~28.4% to the total aerosol absorption, with higher contribution in winter and spring and lower in summer. Average $PM_{10}$ and $PM_{2.5}$ concentrations were $108{\pm}36$ and $24{\pm}14{\mu}g/m^3$ during AD I, respectively, and $164{\pm}66$ and $43{\pm}26{\mu}g/m^3$ during AD II, respectively, implying the greater contribution of local pollution and/or regional pollution to $PM_{2.5}$ during the AD II. BC concentration and aerosol light absorption at 370 nm were relatively high in AD II, compared to those in AD I. Strong spectral dependence of aerosol light absorption was clearly found during the two AD events. $AAE_{370-660nm}$ of both light absorbing organic aerosols and dust particles during the AD I and II was $4.8{\pm}0.5$ and $6.2{\pm}0.7$, respectively. Higher AAE value during the AD II could be attributed to mixed enhanced urban pollution and dust aerosols. Absorption contribution by the light absorbing organic and dust aerosols estimated at 370 nm to the total light absorption was approximately 19% before and after the AD events, but it increased to 32.9~35.0% during the AD events. In conclusion, results from this study support enhancement of the aerosol light absorption due to Asian dust particles observed at the site.

신흡수용액을 이용한 중온수 흡수식 냉동기의 사이클 해석 (Cycle Analysis of Hot Water Driven Absorption Refrigerator with New Working Absorption Solution)

  • 권오경;윤재호;문춘근;윤정인
    • 대한기계학회논문집B
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    • 제26권9호
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    • pp.1241-1248
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    • 2002
  • Performance extension of the absorption refrigerator with LiBr solution is often faced to operate very close to the crystallization limit. Especially in the development of an air-cooled cycle, the crystallization of working solution in the system is a very difficult problem to overcome. This paper describes the cycle of hot water driven absorption system using a new working absorption solution instead of LiBr solution to improve the efficiency. In this study, we found out the characteristics of new working absorption solution through the cycle simulation and compared LiBr solution to evaluate. The effect of cooling water temperature, weak solution flow rate, hot water temperature and hot water flow rate were also examined. The COP is increased 22% higher in the case of LiBr+Li1+LiC1+LiNO$_3$$H_2O$, 2% LiBr+HO(CH$_2$)$_3$OH+$H_2O$ than that of LiBr solution for the same operation condition.

Absorption of SO2 at High Temperatures by Ionic Liquids and the Absorption Mechanism

  • Tian, Shidong;Hou, Yucui;Wu, Weize;Ren, Shuhang;Qian, Jianguo
    • Bulletin of the Korean Chemical Society
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    • 제35권9호
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    • pp.2791-2796
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    • 2014
  • The capture of $SO_2$ at or close to the temperatures of real flue gas is much more attractive in application. In this work, two kinds of ionic liquids (ILs) based on lactate anion were used to absorb $SO_2$ at high temperatures from 100 to $120^{\circ}C$. The ILs show high absorption capacities of over one mol $SO_2$ per mol IL at $110^{\circ}C$. The absorption of $SO_2$ by the ILs based on lactate anion is reversible and the ILs can be reused for the capture of $SO_2$ at high temperatures with high absorption capacity and thermal stability. Furthermore, the absorption mechanism of $SO_2$ by the ILs was studied by FT-IR, $^1H$ NMR and $^{13}C$ NMR spectra. It has been found that there are strong chemical interactions between the ILs and $SO_2$. Also the absorption mechanism is different when there is water present in ILs compared to when there is not.

Broadband metamaterial absorber using resistive layers

  • Kim, Y.J.;Yoo, Y.J.;Hwang, J.S.;Son, H.M.;Rhee, J.Y.;Kim, K.W.;Lee, Y. P.
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.359.1-359.1
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    • 2016
  • The electromagnetic (EM) properties of media, such as propagation, focusing and scattering, strongly rely on the electric permittivity and the magnetic permeability of media. Recently, artificially-created metamaterials (MMs) composed of periodically-arranged unit cells with tailored electric permittivity and magnetic permeability have drawn wide interest due to their capability of adjusting the EM response. MM absorbers using the conventional sandwich structures usually have very high absorption at a certain frequency, and the absorption properties of MMs can be adjusted simply by changing the geometrical parameters of unit cell. In this work, we suggested an incident-angle-independent broadband perfect absorber based on resistive layers. We analyze the absorption mechanism based on the impedance matching with the free space and the distribution of surface currents at specific frequencies. From the simulation, the absorption was expected to be higher than 96% in 1.4-6.0 GHz. The corresponding experimental absorption was found to be higher than 96% in 1.4-4.0 GHz, and the absorption turned out to be slightly lower than 96% in 4.0-6.0 GHz owing to the irregularity in the thickness of resistive layers.

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A Comparative Study of Carbon Absorption Measurement Using Hyperspectral Image and High Density LiDAR Data in Geojedo

  • Choi, Byoung Gil;Na, Young Woo;Shin, Young Seob
    • 한국측량학회지
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    • 제35권4호
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    • pp.231-240
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    • 2017
  • This paper aims to study a method to estimate precise carbon absorption by quantification of forest information that uses accurate LiDAR data, hyperspectral image. To estimate precise carbon absorption value by using spatial data, a problem was found out of carbon absorption value estimation method with statistical method, which is already existed method, and then offered optimized carbon absorption estimation method with spatial information by analyzing with methods of compare digital aerial photogrammetry and LiDAR data. It turned out possible Precise classification and quantification in case of using LiDAR and hyperspectral image. Various classification of tree species was possible with use of LiDAR and hyperspectral image. Classification of hyperspectral image was matched in general with field survey and Mahalanobis distance classification method. Precise forest resources could be extracted using high density LiDAR data. Compared with existing method, 19.7% in forest area, 19.2% in total carbon absorption, 0.9% in absorption per unit area of difference created, and improvement was found out to be estimated precisely in international code.

금속수소화물 수소 저장 용기 내부의 수소흡장에 대한 수치해석적 연구 (Numerical Study of Hydrogen Absorption in a Metal Hydride Hydrogen Storage Vessel)

  • 남진무;강경문;주현철
    • 한국수소및신에너지학회논문집
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    • 제21권4호
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    • pp.249-257
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    • 2010
  • In this paper, a three-dimensional hydrogen absorption model is developed to precisely study hydrogen absorption reaction and resultant heat and mass transport phenomena in metal hydride hydrogen storage vessels. The 3D model is first experimentally validated against the temperature evolution data available in the literature. In addition to model validation, the detailed simulation results shows that at the initial absorption stage, the vessel temperature and H/M ratio distributions are uniform throughout the entire vessel, indicating that the hydrogen absorption is so efficient during the early hydriding process and thus local cooling effect is not influential. On the other hand, nonuniform distributions are predicted at the latter absorption stage, which is mainly due to different degrees of cooling between the vessel wall and core regions. This numerical study provides the fundamental understanding of detailed heat and mass transfer phenomena during hydrogen absorption process and further indicates that efficient design of storage vessel and cooling system is critical to achieve fast hydrogen charging and high hydrogen storage efficiency.

2011년 봄 황사시기 제주도 고산에서의 황사와 오염입자의 광흡수 기여도 산정 (Estimation of the Light Absorption Contribution for Asian Dust and Polluted Particles at Gosan, Jeju during the Asian Dust Episode in the Spring 2011)

  • 이시혜;김상우;윤순창
    • 한국대기환경학회지
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    • 제28권4호
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    • pp.411-422
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    • 2012
  • Ground-based in-situ measurements of aerosol optical properties at Gosan climate observatory have been analyzed to investigate the optical contribution of Asian dust and polluted particles on light absorption in springtime 2011. During the Asian dust episode, the contribution of Asian dust particle to aerosol absorption coefficient estimated about 45% at 370 nm and about 23% at 520 nm. Especially, black carbon in dust plume contributes about 48% to aerosol light absorption at 520 nm since the airmass are transported from the Gobi and inner Mongolia deserts, and this airmass comes across the northeastern coast of China, near the Shandong Peninsula. In pollution case, the contributions of dust particle and black carbon to aerosol absorption coefficient estimated about 41% and 11% at 370 nm, respectively. However, pollution case shows the highest light absorption of 48% for brown carbon at 370 nm, which indicates the significantly high mass concentration of organic carbon ($6.3{\pm}2.2{\mu}g\;m^{-3}$) in pollution plume can contribute to the increase of light absorption at near-UV spectral region.