• Title/Summary/Keyword: Absorbent

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Solubility Measurement of Carbon Dioxide in Alkylcarbonates and Triacetin at High Pressure (고압에서 알킬카보네이트와 트리아세틴의 이산화탄소 용해도 측정)

  • Kim, Ji Won;Hong, Won Hi;Hong, Yeon Ki
    • Clean Technology
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    • v.21 no.2
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    • pp.124-129
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    • 2015
  • The constant-volume method was used to determine the solubility of CO2 in various physical absorbents such as DMPEG (dimethyl ether of polyethylene glycol), DEC (diethyl carbonate), DMC (dimethyl carbonate), and TAT (triacetin) in the total pressure range from 5 to 30 bar. The Peng-Robinson equation of state has been used to describe the equilibrium behavior of these mixtures. It was found that the solubility of absorbents was in the of DMPEG250 > TAT > DEC > DMC at the same temperature. Futhermore, the solubiity of blended absorbent of DMPEG250 and DEC is higher than that of DMPEG 250 alone. Therefore, blended absorbent of DMPEG250 and DEC is expected to be an effective and low cost absorbent for physical absorption in precombustion CO2 capture.

Preparation of PVDF Hollow Fiber Membrane and Absorption of SO2 from Flue Gas Using Bench Scale Gas-Liquid Contactor (PVDF 중공사막 제조 및 벤치규모 기-액 접촉기를 이용한 SO2 흡수특성)

  • Park, Hyun-Hee;Jo, Hang-Dae;Kim, In-Won;Lee, Hyung-Keun
    • Korean Chemical Engineering Research
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    • v.46 no.3
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    • pp.521-528
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    • 2008
  • The micro-porous asymmetric PVDF hollow fiber membranes for gas-liquid contactor were prepared by the dry-jet wet phase inversion process and the characteristics of hollow fiber membranes were evaluated by the gas permeation method and scanning electron microscope. The chemical absorbent for removal of $SO_2$ gas was sodium hydroxide at bench scale hollow fiber membrane contactor. The experiments were performed in a counter-current mode of operation with gas in the shell side and liquid in the fiber lumen of the module to examine the effect of various operating variables such as concentration of absorbent, gas flow rate, L/G ratio and concentration of inlet $SO_2$ gas on the $SO_2$ removal efficiency using PVDF hollow fiber membrane contactor. Membrane mass transfer coefficient($k_m$) was calculated by mathematical modeling. The volumetric overall mass transfer coefficient increased with increasing the concentration of absorbent and L/G ratio. The increase of the absorbent concentration and L/G ratio not only provides more sufficient alkalinity but also decreases liquid phase resistance. The volumetric overall mass transfer coefficient increased with increasing gas flow rate due to decreasing the gas phase resistance.

Research on Characteristics of Multifunctional Soil Binder Based on Polyacrylamide (폴리아크릴아마이드를 기반으로 하는 다기능성 토양안정제의 특성에 관한 연구)

  • Kim, Jin Kyung;Kim, Dae Ho;Joo, Sang Hyun;Lee, Myung Cheon
    • Applied Chemistry for Engineering
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    • v.29 no.2
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    • pp.155-161
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    • 2018
  • For the efficient recovering of collapsed sloped soil, using a soil binder that can support the soil strongly and help the growth of plants is very important. The soil binder should also have functions of recovering the soil ecologically as well as be environmental friendly materials. In this research, optimum values of the water content and permeability and direct shear strength were searched by adding the water absorbent and coagulant into the soil binder. The polyacrylamide (PAM) with various anionic strength, super absorbent polymer (SAP) and cellulose ether (CE) were used as a soil binder, water absorbent and coagulant, respectively. Effects of the soil binder on the characteristics of soil were observed by changing the mixing ratio of PAM, SAP and CE. Experimental results showed that the soil binder increased the direct shear strength tens of times and the water content around two times, whereas decreased the water permeability. Also, the addition of CE to increase the coagulation of SAP increased more of the direct shear strength and water content.

Application of Super Water Absorbent for Edible Mushroom Production (식용버섯 재배시 초고흡수성 폴리머의 효과)

  • Kim, Myung-Kon;Yoon, Sook;Mun, Sung-Pil;Kim, Hyung-Moo;Chang, Tae-Bok;Hong, Jae-Sik
    • The Korean Journal of Mycology
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    • v.28 no.1
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    • pp.16-21
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    • 2000
  • Super water absorbent (CPAM-AS-hyd-1) was prepared by polymerization of acrylamide and allyl sulfonate salt with N,N'-methylene-bis-acrylamide as crosslinking agent, followed by alkaline hydrolysis and the effect on mycelial growth and sporophore production of edible mushrooms in the artificial cultivation was examined. The mycelial growth of edible mushrooms did not depend on the addition of super water absorbent upto 200 g of hydrated polymer gel per 100 cc medium. The proper hydrated polymer gel concentration for sporophore production of Pleurotus sajor-caju and Hericium erinaceus were 200 g and $200{\sim}250\;g$ per 100 cc medium, respectively. The proper hydrated polymer gel and puffed rice hull concentration for sporophore production of Flammulina velutipes was 200 g per 100 mm medium and 10% (v/v), respectively.

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Desulfurization Efficiency of Lime Absorbent in In-Furnace Desulfurization as Fly Ash Binder in Power Plant (발전소 비산재를 결합재로 활용한 로내탈황용 석회 흡수제의 탈황효율)

  • Seo, Jun-Hyung;Baek, Chul-Seoung;Cho, Jin-Sang;Ahn, Ji-Whan;Yoon, Do-Young;Cho, Kye-Hong
    • Resources Recycling
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    • v.27 no.3
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    • pp.58-65
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    • 2018
  • For the recycling of coal ash from the domestic circulating fluidized bed boilers, a lime-based sorbent with 0.2~0.4 mm size was prepared by using limestone powder and CFBC fly ash. Mixing a small amount of slaked lime in the lime-based absorbent lead the formation of calcium silicate on the surface of the particle and the strength of absorbent particle was improved. As a result of comparing the desulfurization characteristics, it was found that the conversion rate was about 10% higher than that of commercially available limestone desulfurization used in the furnace, which is confirmed that it can be used as a desulfurization absorbent.

The Effects of Water-Absorbent Softner Treatment on the End-Use Properties of Polyester Knitted Fabrics (흡습유연 처리에 의한 PET 소재의 성능 변화 분석)

  • Kwon, Young-Ah
    • Fashion & Textile Research Journal
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    • v.12 no.5
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    • pp.676-682
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    • 2010
  • Superior hydrophilic properties will allow varieties of polyester(PET) fiber materials, fabrics and industrial materials a broader scope of use. The purpose of this study was to investigate the effect of water-absorbent softener treatment on the end-use properties and the hand of polyester knitted fabrics. Two different fabrics were knitted for the summer ladies' outwear; PET jersey and PET mesh. Variables were softner treatment and stitch type(jersey and mesh). Mechanical properties of the fabric samples were measured by KES-FB system. From these, primary hand values(HV) were evaluated by the conversion equation (KW-403-KTU) and the total hand value(T.H.V.) was calculated according to the KN-304 Summer. Both water-absorbent softner treatment and stitch types affected mechanical properties and hand values of PET fabrics. Mesh were thicker than single jersey stitch. As they became thicker, tensile, shear, and compressional energy increased. It appeared that coefficient of friction of mesh stitch was larger than that of single jersey stitch. The coefficient of friction and the mean deviation of surface roughness were decreased by softener treatment. After softner treatment KOSHI and SHARI of the both PET jersey and PET mesh decreased. However, FUKURAMI values of PET jersey increased and that of PET mesh decreased. The T.H.V. of the treated PET jersey was lower than that of the untreated one, while the T.H.V. of the treated PET mesh was higher than that of the untreated one. Overall T.H.V. of the single jersey was better than that of the mesh before and after softner treatment.

An Evaluation of a super-absorbent polymer as the Nucleating Agent for a Capsule-type Ice Storage System (고흡수성고분자가 조핵제로 첨가된 빙축열용 축열재 개발)

  • Choi, Hyung-Joon;Hong, Seong-Ahn;Park, Won-Hoon
    • Solar Energy
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    • v.10 no.2
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    • pp.28-37
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    • 1990
  • A study was conducted to investigate the feasibility of using a super-absorbent polymer made from a acrylic acid copolymer for a capsule-type ice storage system. In a simple pyrex-tube test, 25% of distilled water samples tested turned out not be frozen at all at $-12^{\circ}C$ and the average supercooling of the samples frozen was $9.8^{\circ}C$. With the addition of 0.5wt% super-absorbent polymer, however, the supercooling of the distilled water was dramatically reduced and more than 35% of samples tested did not show any supercooling. The heat transfer characteristics of a capsule-type ice storage unit was also investigated with a distilled water as the phase-change material. With the addition of 0.5wt% polymer, the supercooling of water was not observed at all and thus an overall heat transfer was enhanced. Based on these results, it was concluded that a super-absorbent polymer is a potential candidate as the nucleating agent for an ice-storage system.

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Performance Analysis of Absorbent for Post-combustion CO2 Capture by Regeneration (연소 후 CO2 포집을 위한 흡수제의 재생반응에 의한 성능 해석)

  • KIL, TAEHYOUNG;LEE, DONGHO;JO, SUNGHO;YI, CHANGKEUN;PARK, YEONGSEONG;RYU, HOJUNG
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.1
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    • pp.83-94
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    • 2016
  • Performance of absorbent for post-combustion $CO_2$ capture was measured and discussed. Fully saturated fresh absorbent (P2-15F) and absorbents sampled from absorption and regeneration reactor of continuous $CO_2$ capture process, P2-15A, P2-15R, respectively, were used as representative absorbents. Small scale fluidized bed reactor (0.05 m I.D., 0.8 m high) which can measure exhaust gas concentration and weight change simultaneously was used to analyze regeneration characteristics for those absorbents. Exhausted moles of $CO_2$ and $H_2O$ were measured with increasing temperature. $H_2O/CO$ ratio and working capacity were determined and discussed to confirm reason of reactivity decay after continuous operation. Moreover, possibility of side reaction was checked based on the $H_2O/CO_2$ mole ratio. Finally, suitable regeneration temperature range was confirmed based on the trend of working capacity with temperature.

Responses of Low-Quality Soil Microbial Community Structure and Activities to Application of a Mixed Material of Humic Acid, Biochar, and Super Absorbent Polymer

  • Li, Fangze;Men, Shuhui;Zhang, Shiwei;Huang, Juan;Puyang, Xuehua;Wu, Zhenqing;Huang, Zhanbin
    • Journal of Microbiology and Biotechnology
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    • v.30 no.9
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    • pp.1310-1320
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    • 2020
  • Low-quality soil for land reuse is a crucial problem in vegetation quality and especially to waste disposal sites in mining areas. It is necessary to find suitable materials to improve the soil quality and especially to increase soil microbial diversity and activity. In this study, pot experiments were conducted to investigate the effect of a mixed material of humic acid, super absorbent polymer and biochar on low-quality soil indexes and the microbial community response. The indexes included soil physicochemical properties and the corresponding plant growth. The results showed that the mixed material could improve chemical properties and physical structure of soil by increasing the bulk density, porosity, macro aggregate, and promote the mineralization of nutrient elements in soil. The best performance was achieved by adding 3 g·kg-1 super absorbent polymer, 3 g·kg-1 humic acid, and 10 g·kg-1 biochar to soil with plant total nitrogen, dry weight and height increased by 85.18%, 266.41% and 74.06%, respectively. Physicochemical properties caused changes in soil microbial diversity. Acidobacteria, Bacteroidetes, Chloroflexi, Cyanobacteria, Firmicutes, Nitrospirae, Planctomycetes, and Proteobacteria were significantly positively correlated with most of the physical, chemical and plant indicators. Actinobacteria and Armatimonadetes were significantly negatively correlated with most measurement factors. Therefore, this study can contribute to improving the understanding of low-quality soil and how it affects soil microbial functions and sustainability.

Preparation of Adsorbent from Sewage Sludge by Steam Activation and Adsorption Characteristic (하수슬러지의 수증기 활성화법을 이용한 흡착제 제조와 흡착특성)

  • Jung, Dong-Hyun;Chun, Young-Nam
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.5
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    • pp.515-520
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    • 2007
  • Recently, the treat of sludge is usually progressed by ocean disposal. But it will be totally banned by content of its heavy metal according to London Dumping Convention, gradually. The stable way of treat of sewage sludge should be examined urgently. To solve the problem, recently, there are efficient and environment-oriented method. One of them is to produce absorbent through the activation. This study produces absorbent through steam activation. As basic experiment, optimum activation condition for preparation of good absorbent is researched through study of the fellowing variables : steam flow rate, activated temperature, activation time. As the result of this with standard on iodine adsorptivity, it is chosen, that steam flow rate "30 mL/hr", activation temperature $"500^{\circ}C"$, activation time "60 minutes". At the time, iodine adsorptivity and yield shown that 228.4 mg/g, 77.23%. And also, by using nitrogen adsorption, SEM and EDS are confirmed that pore development, specific surface area, mean pore size, chemical component and content. Pore developed by steam activation is also confirmed that it is micropore.