• Title/Summary/Keyword: Absorbance of Dye

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Analysis of Absorbance for Tinted Dye Absorbed into Tinted Lenses by Spectrophotometric Method (분광광도법에 의한 칼라 렌즈 내 염색제에 대한 흡광도 분석)

  • Choi, Eun-Jung;Jung, Ju-Hyun
    • Journal of the Korean Chemical Society
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    • v.53 no.6
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    • pp.704-708
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    • 2009
  • We studied absorbance of tinted dye absorbed into tinted lenses by Spectrophotometric method. Used lenses and tinted dye were CR-39 plastic optical lenses and Ons & $Lavas^{(R)}$ Blue, respectively. Absorbance values of tinted dye absorbed into tinted lenses were obtained from the differences of absorbance values between tinted lenses and CR-30 lenses. Average concentrations of tinted dye absorbed into tinted lenses were obtained from the mass differences between tinted lenses and CR-30 lenses. The relationship between absorbance and average concentration for tinted dye absorbed into tinted lenses was also confirmed to follow Beer’s law. The absorption coefficient calculated from the tangent of the calibration curve was determined to be a=0.983 $Lg^{-1}cm^{-1}$.

Storage Stability and Color Reproducibility of Yellow and Red Dyes Extracted from Carthamus tinctorius L.

  • Shin, Youn-Sook;Yoo, Dong-Il
    • Textile Coloration and Finishing
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    • v.24 no.3
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    • pp.165-172
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    • 2012
  • The stability of yellow and red dyes prepared from safflower (Carthamus tinctorius L.) in aqueous solution and in solid state was investigated. External factors such as light irradiation and temperature on the stability were examined during storage. Changes in absorbance of dye solutions and the color changes of fabrics dyed after long time storage were measured. Also, color reproducibility during storage was investigated by dyeing test on various fabrics. Red colorant in aqueous solution was very unstable to light, resulting that about 40% of absorbance were lost in 12hrs. The absorbance of yellow dye solutions was not decreased within 84hrs. In aqueous medium, yellow dye was much more stable than carthamin. Both dyes are relatively stable for long storage when they are stored in solid state compared to when in aqueous solution. Color changes are marginal in both dyes.

Evaluation of Protein Content and Qaulity in Brown Rice by a Dye-binding Method (염색법에 의한 쌀 단백질의 함량 및 질의 평가에 관한 연구)

  • Kim, Seung-Kon;Lee, Chun-Yung;Park, Hoon
    • Korean Journal of Food Science and Technology
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    • v.3 no.2
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    • pp.101-104
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    • 1971
  • The dye-binding method based on the reaction of acidic orange-G dye with basic groups of protein molecule was investigated to observe its applicability to the determination of protein, basic amino acid and lysine contents in brown rice of several high-protein rice lines. The protein content of rice samples ranged from 7.91 to 10.53% and from 8.93 to 11.96% in terms of wet and dry bases, respectively. The correlation between dye-binding absorbance and protein content in terms of both dry and wet bases was highly significant; their correlation coefficients being $-0.955^{**}\;and\;-0.975^{**}$, respectively. The correlation of dye-binding absorbance lysine and basic amino acids were highly significant and their correlation coefficients were similar. Dye-binding absorbance-lysine showed a lower correlation than dye-binding absorbance-protein but a higher correlation than protein-lysine.

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Dyeing Properties of Morus alba L. Fruit Powder on the Silk Fabric (오디 분말을 이용한 견직물의 염색성)

  • Bai, Sang-Kyoung
    • Fashion & Textile Research Journal
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    • v.10 no.5
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    • pp.779-783
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    • 2008
  • The main colorant of Morus alba L. fruit is anthocyanin which is a kind of flavonoid group. In this article, the dyeing properties of colorant extracted from Morus alba L. fruit were investigated on some silk fabrics. The results were as follows: The maximum absorbance of Morus alba L. fruit showed at 284 nm, and 516 nm by UV-VIS spectrophotometer. The dye adsorption increased according as dye concentration. The optimal dyeing temperature was $60^{\circ}C$ and the dye equilibrium was reached 40 minutes after dyeing. The highest K/S value of the colorant obtained at bath ratio 40:1. The effect of pH of dye solution showed higher K/S value at acidic than alkaline condition. Almost Mordants except pre-Fe and Sn did not significantly increased dye adsorption. The pre mordanted silk fabrics showed RP, P, and post mordanted ones showed PB, GY. The color fastnesses to light, washing, and perspiration were modified at pre-Sn mordanted samples.

Decoloration in Dyebath by Dye Absorption of Chitin(Part I) (키틴의 염료 흡착에 의한 염액의 색소제거에 관한 연구(제1보))

  • 유혜자;이혜자;이전숙
    • Journal of the Korean Society of Clothing and Textiles
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    • v.24 no.3
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    • pp.385-392
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    • 2000
  • The adsorption ability of dyes on chitin, a natural polymer was investigated for decolorization of dye wastewater. Chitin was manufactured in lab by decalcification in dilute aqueous HCI solution and deproteination in dilute aqueous NaOH solution with shrimp shells. Absorbance of residue solution of dyebaths after dye adsorptions of chitin were measured in varieties of dye concentration and dipping periods. Four kinds of dyestuffs were used, C.I.Acid Blue 29. C.I.Direct Blue 6, C.I.Reactive Orange 12 and C.I.Basic Red 18. When chtin 1g was dipped in 0.05% of dyebath with stirring, maximum adsorption ratio of each kind of dyes was exhibited as 91.6% for C.I.Acid Blue 29, 95% for C.I.Direct Blue 6, 58.2% for C.I.Reactive Orange 13 and 75.8% for C.I.Basic Red 19. It shows that chitin has better adsorption abilities of ionic dyes of acid, direct and basic dye than non-ionic reactive dye. And chitin has better adsorption abilities of anionic acid direct dyes than cationic basic dye because of the presence of nitrogen atoms. All kinds of dyestuffs used showed speedy absorption effects by chitin, so chitin can absorb much amount of dyes in 5 mimutes reach to equilibrium of adsorption in 2 hours after dipping. Basic dye was absorbed the most speedily in 5 minutes, although maximum adsorption ratio is not high. That reason can be thought that chitin surface is essentially negatively charged due to polar funtional groups.

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Measurement of Spray Deposit Amount Using Spectrophotometer and Food Dye as Tracer

  • Rhee, J.Y.;Ahn, S.Y.
    • Agricultural and Biosystems Engineering
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    • v.1 no.1
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    • pp.16-21
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    • 2000
  • Measurement of spray deposit is necessary for evaluation of a chemical application technology. However it is not easy and time consuming. A simple method for measuring the deposition amount of spray using a tracer and a spectrophotometer was developed. Various materials were tested to determine an adequate tracer. Food dye was selected as a tracer, because it was cheep and easily treatable. Using NIRS(Near Infrared Reflection Spectrophotometer), a regression curves between maximum absorbance of a solution and concentration of the tracer were obtained. Yellow food dye solution showed a peak of spectrum at 452 nm, and absorbance of peak showed a tendency to increase as concentration increased. Green or pink food dye were tested and judged to be good tracers. However, tracer concentration should not exceed certain limits in order to measure maximum absorption. Using spraying liquid with known tracer concentration and known amount of washing liquid, spray deposit amount on real targets on leaves could be estimated at less than 13% error level.

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Relationship between the porosity of the nanostructured $TiO_2$ electrode and Dye Loading for Dye-sensitized Solar Cells (염료감응태양전지를 위한 $TiO_2$ 분말 기공도와 염료 흡착량의 관계)

  • Hwang, Seongjin;Jung, Hyunsang;Jeon, Jaeseung;Kim, Hyungsun
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.68.2-68.2
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    • 2010
  • Dye-sensitized solar cells (DSSC) show great promise as an inexpensive alternative to conventional p-n junction solar cells. Investigations into the various factors influencing the photovoltaic efficiency have recently been intensified. The conventional absorber electrode in DSSC is composed of compacted or sintered $TiO_2$ nanopowder that carries an anchored organic dye. The absorbance of incident light in the DSC is realized by specifically engineered dye molecules placed on the semiconductor electrode surface ($TiO_2$). The dye absorbs light at wavelengths up to about 920nm, the energy of the exited state of the molecule should be about 1.35eV above the electronic ground state corresponding to the ideal band gap of a single band gap solar cell. The dye molecules ar adhered onto the nanostrutured $TiO_2$ electrode by immersing the sintered electrode into a dye solution, typically 3mM in alcohol, for a long enough period to fully impregnate the electrode. However, the concentrations of the dye is slightly changed due to the evaporation of the alcohol. The dye is more expensive than other materials in DSSC and related to the efficiency of DSSC. Therefore, the concentrations of the dye should be carefully measured. In this study, we investigated to the dye loading on fired $TiO_2$ powder as a function of temperature by the TG-DTA and the dye solution by UV-visible spectroscopy after the impregnation process. The dye loading is related to the porosity of the nanostructured $TiO_2$ electrode.

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Properties of Working Electrodes with Polystyrene Beads Addition in Dye Sensitized Solar Cells

  • Noh, Yunyoung;Choi, Minkyoung;Song, Ohsung
    • Journal of the Korean Ceramic Society
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    • v.52 no.5
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    • pp.380-383
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    • 2015
  • We prepared the $TiO_2$ layer with 0 ~ 4 wt% of polystyrene (PS) beads having a radius of 250 nm to increase the dye adsorption and energy conversion efficiency (ECE) of a dye sensitized solar cell (DSSC). Then, we fabricated DSSCs using $0.45cm^2$ active area. FE-SEM was used to characterize the microstructure consisting of $TiO_2$ layer and PS beads. UV-VIS-NIR was used to determine the optical absorbance of working electrodes (WEs). Solar simulator and potentiostat were used to determine the photovoltaic properties. We observed that pores having a radius of 250 nm were formed with the density of $0.15ea/{\mu}m^2$ in $TiO_2$ layers after conducting the sintering process. The absorbance in visible light regime was found to increase with the increase in the amount of PS beads. The ECE increased from 4.66% to 5.25% when the amount of PS beads was increased from 0 to 4 wt%. This is because the pores of PS beads increased the adsorption of dye. Our results indicate that the ECE of the DSSCs can be enhanced by the addition of an appropriate amount of PS beads into $TiO_2$ layers.

Decolorization Characteristics of Acid and Basic Dyes Using Modified Zero-valent Iron (개질 영가철을 이용한 산성 및 염기성 염료의 탈색 특성)

  • Choi, Jeong-Hak;Kim, Young-Hun
    • Journal of Environmental Science International
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    • v.25 no.12
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    • pp.1717-1726
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    • 2016
  • In this study, the reductive decolorization of three acid and basic dyes using modified zero-valent iron (i.e., acid-washed iron (Aw/Fe) and palladium coated iron (Pd/Fe)) at various pH conditions (pH 3~5) was experimentally investigated and the decolorization characteristics were evaluated by analyzing the absorbance spectra and reaction kinetics. In the case of acid dyes such as methyl orange and eriochrome black T, color removal efficiencies increased as initial pH of the dye solution decreased. However, the color removal of methylene blue, a basic dye, was not affected much by the initial pH and more than 70% of color was removed within 10 min. During the decolorization reaction, the absorbance of methyl orange (${\lambda}_{max}=464nm$) and eriochrome black T (${\lambda}_{max}=528nm$) decreased in the visible range but increased in the UV range. The absorbance of methylene blue (${\lambda}_{max}=664nm$) also decreased gradually in the visible range. Pseudo-zero order, pseudo-first order, and pseudo-second order kinetic models were used to analyze the reaction kinetics. The pseudo-second order kinetic model was found to be the best with good correlation. The decolorization reaction rate constants ($k_2$) of methylene blue were relatively higher than those of methyl orange and eriochrome black T. The reaction rate constants of methyl orange and eriochrome black T increased with a decrease in the initial pH.

The characteristics of dye containing PMMA films for the PDP filter

  • Oh, Hwa-Shin;Cho, Yong;Jung, Sang-Kooun;Sohn, Sang-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1364-1366
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    • 2006
  • Optical filters consisting of dye containing Polymethyl methacrylate(PMMA) thick films have been fabricated by a tape casting method. Their optical properties have been investigated as functions of dye contents in films and the film thickness. The absorbance coefficient in 588nm and 830nm could be calculated from the results.

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