• Title/Summary/Keyword: Absolute configuration

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Intercorrelation between Photonic Band and Etch Current on Rugate Photonic Crystals (Rugate 광결정에서 광학띠와 식각전류의 상관관계)

  • Park, Jongsun;Kim, Yongmin
    • Journal of Integrative Natural Science
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    • v.2 no.3
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    • pp.207-210
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    • 2009
  • Multiple rugate structures can be etched on a silicon wafer and placed in the same physical location, showing that many sharp spectral lines can be obtained in the optical reflectivity spectrum. Porous silicon samples were prepared by electrochemical etch of heavily doped p-type silicon wafers. The etching solution consisted of a 3:1 volume mixture of aqueous 48% hydrofluoric acid and absolute ethanol. Galvanostatic etch was carried out in a Teflon cell by using a two-electrode configuration with a Pt mesh counterelectrode. A sinusoidal current density waveform varying between 51.5 and $74.6mA/cm^2$ is applied. The anodization current was supplied by a Keithley 2420 high-precision constant current source which is controlled by a computer to allow the formation of PSi multilayer.

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Synthesis and Characterization of Optically Active mer-[Co(L)2](CIO4)[L=4(S)-1-(2-pyridyl)-3-oxo-4-amino-2-azapentane(S-alaampH) and 4(S)-1-(2-pyridyl)-3-oxo-4-aza-7-thiaoctane (S-metampH)] (광학활성인 mer-[Co(L)2](CIO4)착물의 합성과 성질 [L=4(S)-1-(2-pyridyl)-3-oxo-amino-2-azapentane(S-alaampH)와 4(S)-1-(2-pyridyl)-3-oxo-4-aza-7-thiaoctane (S-metampH)])

CLASSIFICATION OF LAKE SEDIMENTS BY USING HYDROCYCLONES

  • Jo, Young-Min;Jang, Hyun-Tae
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2001.11a
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    • pp.64-69
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    • 2001
  • The present work provides a result from the preliminary experiment for hydrocyclone technology. In this work, local lake sediments and waste coal fly ash were used as test samples, prior to the application of hydrocyclone technology to the waste sludge thickening. A few cyclones based on the Rietema standard geometry were prepared. Chemical analysis of the sediments showed that more organic contaminants were in smaller particles. The experimental tests further showed that physical characteristics of particles, configuration of the cyclone and operation condition would affect the separation efficiency. The current results showed that small size cyclones might improve the separation and concentration of the lake sediments, and higher inlet velocity would increase the concentration rate of under flow and absolute concentration of sediment particles.

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Cobalt(III) Complex of Ethylenediamine-N,N'-di-S-${\alpha}$-Propionic Acid (Ethylenediamine-N,N'-di-S-${\alpha}$-Propionic Acid의 코발트(III) 착물)

  • Moo Jin Jun;Yoon Bong Park;Chang Yun Han;Sung Rack Choi
    • Journal of the Korean Chemical Society
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    • v.29 no.3
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    • pp.247-251
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    • 1985
  • Dichloro cobalt(III) complex of a flexible tetradentate ligand of ethylenediamine-N,N'-di-S-${\alpha}$-propionic acid (eddp) has been prepared via the air-oxidation technique. Only ${\Delta}$-cis isomer has been yielded showing high stereoselectivity of the eddp ligand. Elemental analysis, ir, nmr and electronic absorption spectra have been used to characterize the complex and the absolute configuration of the complex is assigned by means of the nmr spectroscopy.

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Optical Rotatory Power and Molecular Structure. (Part 1{\sim}2$) (Part 1) ${\alpha}$-1, 2, 3, 4, 5, 6-Hexahalocyclohexane. (旋光性과 分子構造 (第1報${\sim}$第2報) (第1報) ${\alpha}$-1,2,3,4,5,6-Hexahalocyclohexane에 關하여)

  • Kong, Chang-Lyoul;Kim, Shoon-Kyung
    • Journal of the Korean Chemical Society
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    • v.5 no.1
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    • pp.48-51
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    • 1961
  • A calculation of the optical activity of the ${\alpha}$-1,2,3,4,5,6-Hexahalocyclohexane is presented based upon the Kirkwood's polarizability theory of optical rotatory power. The calculated specific rotation of the compound are given in the following table. The close agreements demonstrates the applicability of the polarizability theory to the compounds whose optical activity is due to steric interference. The agreement in sign also confirms the validity of the absolute configuration of the ${\alpha}$-1,2,3,4,5,6-Hexahalocyclohexane given by O. Hassel.

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A Study on Non-Metric Multidimensional Scaling Using A New Fitness Function (새로운 적합도 함수를 사용한 비계량형 다차원 척도법에 대한 연구)

  • Lee, Dong-Ju;Lee, Chang-Yong
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.34 no.2
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    • pp.60-67
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    • 2011
  • Since the non-metric Multidimensional scaling (nMDS), a data visualization technique, provides with insights about engineering, economic, and scientific applications, it is widely used for analyzing large non-metric multidimensional data sets. The nMDS requires a fitness function to measure fit of the proximity data by the distances among n objects. Most commonly used fitness functions are nonlinear and have a difficulty to find a good configuration. In this paper, we propose a new fitness function, an absolute value type, and show its advantages.

Synthesis and Cytotoxic Activity of (R)-(-)-PGME Amide of Diterpene Acid

  • Lim, Jin-A;Yook, Chan-Nam;You, Il-Soo;Oh, Hyun-Ju;Kim, Myung-Ju;Baek, Seung-Hwa
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.19 no.2
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    • pp.520-523
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    • 2005
  • (R)-(-)-PGME amide of diterpene acid (2) was assigned the absolute configuration from NMR correlation experiments. The compound (2) was tested for its growth inhibitory effects against tumor cell lines by the MTT method.

Asymmetric [2,3]-Wittig Rearrangements in the Presence of Sparteine Derivatives

  • Jahyo Kang;Won Oh Cho;Hyung Geun Cho;Hee Jin Oh
    • Bulletin of the Korean Chemical Society
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    • v.15 no.9
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    • pp.732-739
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    • 1994
  • Asymmetric [2,3]-Wittig rearrangements of allyl propargyl ethers in hexane were performed in the presence of s-butyllithium and (-)-${\alpha}$-isosparteine which is a $C_2$-symmetric chiral ligand for the alkyllithium reagent. The reactions of (Z)-or (E)-allyl 3-trimethylsilylpropargyl ethers at -78$^{\circ}C$ showed good diastereoselectivities (74-100%) and moderate enantioselectivities (29-71%). The absolute configurations of the rearrangement products were determined by the corresponding Mosher's esters. It was found that (-)-${\alpha}$ -isosparteine induced (R) configuration at the hydroxy carbon and syn stereochemistry more favorably. The possible transition state is discussed.

Evaluation of marginal fit of 2 CAD-CAM anatomic contour zirconia crown systems and lithium disilicate glass-ceramic crown

  • Ji, Min-Kyung;Park, Ji-Hee;Park, Sang-Won;Yun, Kwi-Dug;Oh, Gye-Jeong;Lim, Hyun-Pil
    • The Journal of Advanced Prosthodontics
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    • v.7 no.4
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    • pp.271-277
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    • 2015
  • PURPOSE. This study was to evaluate the marginal fit of two CAD-CAM anatomic contour zirconia crown systems compared to lithium disilicate glass-ceramic crowns. MATERIALS AND METHODS. Shoulder and deep chamfer margin were formed on each acrylic resin tooth model of a maxillary first premolar. Two CAD-CAM systems (Prettau$^{(R)}$Zirconia and ZENOSTAR$^{(R)}$ZR translucent) and lithium disilicate glass ceramic (IPS e.max$^{(R)}$press) crowns were made (n=16). Each crown was bonded to stone dies with resin cement (Rely X Unicem). Marginal gap and absolute marginal discrepancy of crowns were measured using a light microscope equipped with a digital camera (Leica DFC295) magnified by a factor of 100. Two-way analysis of variance (ANOVA) and post-hoc Tukey's HSD test were conducted to analyze the significance of crown marginal fit regarding the finish line configuration and the fabrication system. RESULTS. The mean marginal gap of lithium disilicate glass ceramic crowns (IPS e.max$^{(R)}$press) was significantly lower than that of the CAD-CAM anatomic contour zirconia crown system (Prettau$^{(R)}$Zirconia) (P<.05). Both fabrication systems and finish line configurations significantly influenced the absolute marginal discrepancy (P<.05). CONCLUSION. The lithium disilicate glass ceramic crown (IPS e.max$^{(R)}$press) had significantly smaller marginal gap than the CAD-CAM anatomic contour zirconia crown system (Prettau$^{(R)}$Zirconia). In terms of absolute marginal discrepancy, the CAD-CAM anatomic contour zirconia crown system (ZENOSTAR$^{(R)}$ZR translucent) had under-extended margin, whereas the CAD-CAM anatomic contour zirconia crown system (Prettau$^{(R)}$Zirconia) and lithium disilicate glass ceramic crowns (IPS e.max$^{(R)}$press) had overextended margins.