• Journal of the Korean institute of surface engineering
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• v.42 no.3
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• pp.109-115
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• 2009

Magnesium is one of the lightest metals, and magnesium alloys have excellent physical and mechanical properties such as high stiffness/weight ratios, good castability, good vibration and shock absorption. However their poor corrosion resistance, wear resistance, hardness and so on, have limited their application. To improve these defects, many techniques are developed. Micro arc oxidation(MAO) is a one of the surface treatments under anodic oxidation in which ceramic coating is directly formed on the surface of magnesium alloy. In this study, the characteristics of anodic film were examined after coating the AZ31B magnesium alloy through the MAO process. MAO was carried out in potassium hydroxide, potassium fluoride, and various concentration of sodium silicate in electrolyte. The morphology and chemical composition of the coating layer were characterized by SEM, XRD, EPMA and EDS. The hardness of anodic films was measured by micro-vickers hardness tester. As a result, the morphology and composition of anodic film were changed by concentration of sodium silicate. Thickness and Si composition of anodic film was increased with increasing concentration of sodium silicate in electrolyte. The hardness of anodic film was highly increased when the concentration of sodium silicate was above 40 g/l in electrolyte.

• Journal of the Korean institute of surface engineering
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• v.50 no.5
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• pp.308-314
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• 2017

Anodic film formation behavior of AZ31 Mg alloy was studied as a function of NaOH concentration in 1 M $Na_2CO_3$ + 0.5 M $Na_2SiO_3$ solution under the application of a constant anodic current density, based on the analyses of voltage-time curves, surface appearances and morphologies of the anodically formed PEO (plasma electrolytic oxidation) films. The anodic film formation voltage and its fluctuations became largely lowered with increasing added NaOH concentration in the solution. Two different types of film defects, large size dark spots indented from the original surface and locally extruded white spots, were observed on the PEO-treated surface, depending on the concentration of added NaOH. The large size dark spots appeared only when added NaOH concentration is less than 0.2 M and they seem to result from the local detachments of porous PEO films. The white spots were observed to be very porous and locally extruded and their size became smaller with increasing added NaOH concentration. The white spot defects disappeared completely when more than 0.8 M NaOH is added in the solution. Concludingly it is suggested that the presence of enough concentration of $OH^-$ ions in the carbonate and silicate ion-containing electrolyte can prevent local thickening and/or detachment of the PEO films on the AZ31 Mg alloy surface and lower the PEO film formation voltage less than 70 V.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2004.08a
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• pp.55-62
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• 2004

In this study, the effects of Ca content and processing variables on hot rolling properties of gravity cast AZ31-xCa alloys were evaluated systematically. The number and length of side crack were decreased with increasing preheating temperature and decreasing reduction ratio per pass and Ca content. The UTS and YS were not strongly dependent on the Ca content but the elongation decreased with increasing Ca content. The decrease of elongation in Ca containing alloys was least when the sheets were fabricated under preheating temperature of $400^{\circ}C$ and reduction ratio per pass of $15\%$. The sheets had the sound external features with little side cracks by homogenization of gravity cast AZ31-xCa alloys before hot rolling. In the cases of AZ31-xCa alloys containing under $1wt.\%$ Ca, the annealed sheets after homogenization and hot rolling had the similar tensile properties to those of AZ31 sheet.

• Transactions of Materials Processing
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• v.17 no.8
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• pp.558-563
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• 2008

The initial strain, the applied stress exponent, the activation energy, and rupture time in AZ31 magnesium alloy have been measured in order to predict the deformation mechanism and rupture life of creep over the temperature range of 423-443K. Creep tests were carried out under constant applied stress and temperature, and the lever type tester and automatic temperature controller was used for it, respectively. The experimental results showed that the applied stress exponent was about 9.74, and the activation energy for creep, 113.6KJ/mol was less than that of the self diffusion of Mg alloy including aluminum. From the results, the mechanism for creep deformation seems to be controlled by cross slip at the temperature range of 423-443K. Also the higher the applied stress and temperature, the higher the initial strain. And the rupture time for creep decreased as quadratic function with increasing the initial strain in double logarithmic axis.

• Journal of the Korean institute of surface engineering
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• v.44 no.2
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• pp.44-49
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• 2011

The films formed on AZ31B magnesium alloy were prepared from alkaline solution composed of potassium permanganate and sodium hydroxide. The immersion tests were carried out at the different concentration of sodium hydroxide and pre-treatment method in 5 minute. The morphology and the phase composition of the film were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The corrosion behavior of the film in 5.0% NaCl solution was evaluated using potentiodyanmic polarization. Open circuit potential in developing film was examined with time. The thin and transparent film was mainly composed of MgO and $Mg(OH)_2$. The film with the best corrosion resistance was obtained at $70^{\circ}C$ bath temperature, 1.6 M concentration of sodium hydroxide and chemical pre-treatment.

• Journal of Korea Foundry Society
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• v.20 no.2
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• pp.110-115
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• 2000

In this study, the powders of Mg-3wt%Al-1wt%Zn-1wt%MM alloy were produced under vacuum condition by the inert gas atomization and the rapidly solidified powders were consolidated by the vacuum hot extrusion. Then the structural change of powders during extrusion was investigated. The effects of misch metal addition to AZ31 on mechanical properties of extruded bars were also examined. During extrusion of the rapidly solidified powders, their dendrite structure was broken into fragments and remained as grains of 2 ${\mu}m$ size in extruded bar. The Mg-Al-Ce intermetallic compounds formed in the interdendritic regions of powders were broken finely, too. The yield stress, tensile strength and ductility obtained in as-extruded Mg-3wt%Al-1wt%Zn-1wt%MM alloy were ${\sigma}_{0.2}=325$ MPa, ${\sigma}_{T.S.}=417$ MPa and ${\varepsilon}=16.8%$. All of these improvements on mechanical properties result from the refined micostructure and second-phase dispersions.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.12 no.2
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• pp.594-599
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• 2011

In this paper, the effect of the boundary conditions on the reliability and the cumulative distribution characteristics of the fatigue failure life is analyzed in a magnesium alloy AZ31. The boundary conditions are specimen thickness, stress ratio, and maximum fatigue load. The statistical data of the fatigue failure life are obtained by fatigue crack propagation tests under the detail conditions for each boundary condition. The 3-parameter Weibull distribution is used to analyze a statistical characteristics of the fatigue failure life in magnesium alloy AZ31. It is found that the statistical fatigue failure life is long in the case of a thicker specimen, a larger stress ratio, and a smaller maximum fatigue load. Under the opposite cases, the reliability on the fatigue failure life is rapidly dropped.

• Journal of Power System Engineering
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• v.17 no.4
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• pp.64-71
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• 2013

In this paper, finite element method was used for flow and strength analysis of AZ31 magnesium alloy under friction stir welding. The simulations were carried out by SYSWELD s/w, and the modeling of sheet was doned by unigraphics NX3 s/w. Welding variables for analysis were rotating speed and welding speed of tool. Also two-way factorial design method was applied to confirm the effect of welding variables on maximum temperature and stress of material used. From these results, the increaser welding speed of tool the decreaser maximum temperature, but the increaser maximum stress. Also the increaser rotating speed of tool the increaser maximum temperature, but the decreaser maximum stress. In addition the increaser welding speed of tool and the decreaser rotating speed of tool, the narrower heat effect zone. Finally rotating speed of tool influenced on maximum temperature more than welding speed of tool, and welding speed of tool influenced on maximum stress more than rotating speed of tool from the variance analysis.

• Design & Manufacturing
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• v.12 no.3
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• pp.42-47
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• 2018

Recently, in the surge of global environmental issues, there has been a great attention to lightweight materials in purpose of saving energy. Magnesium alloys not only have low specific gravity, and superb specific stiffness, but are also excellent in blocking vibrations and electromagnetic waves. So demand for this material is getting bigger rapidly throughout the industry. In this study, we examined the improvement of formability of magnesium alloy AZ31 material in warm working. Drawing, bending and shearing process were carried out by varying the forming temperature and the forming speed, and the influence of the variables on each process was studied. In the experiments, the high forming temperature and low forming speed results in high formability in the drawing process and the bending process. In the shearing process, as the forming temperature increases, the length of the fracture decreases.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2004.05a
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• pp.43-46
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• 2004

Since Mg alloy has many attractive advantages among the practically used metals, many researchers have been studied to develop useful process and material. However, study for sheet forming has not been a few because of low formability on room temperature. Formability and springback for AZ31 alloy sheet have been studied to develop the cold forming technology. The experimental and FE analysis were performed to analyzed the springback amounts by using a model of our on. A different three materials were used to investigate the effects of material characteristics. The springback amounts of Mg-alloy sheet formed part were larger than that of the other material.