• Korean Journal of Metals and Materials
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• v.47 no.2
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• pp.59-70
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• 2009

This study is concerned with the correlation between microstructure and mechanical properties in heat affected zones (HAZs) of API X80 pipeline steels containing complex oxides. Three kinds of specimens were fabricated by varying alloying elements of Ti, Al, and Mg to form complex oxides, and their microstructures, Vickers hardness, Charpy impact properties were investigated. The number of complex oxides increased as the excess amount of Ti, Al, and Mg was included in the steels. The simulated HAZs containing a number of oxides showed a high volume fraction of acicular ferrite region because oxides acted as nucleation sites for acicular ferrite. According to the correlation study between thermal input, volume fraction of acicular ferrite region, and Charpy impact properties, the ductile fracture occurred predominantly when the volume fraction of acicular ferrite region was 65% or higher, and the Charpy absorbed energy was excellent over 200 J. When the volume fraction of acicular ferrite region was 35% or lower, the Charpy absorbed energy was poor below 50 J as the brittle cleavage fracture occurred. These findings suggested that the active nucleation of acicular ferrite in the oxide-containing steel HAZs was associated with the great improvement of Charpy impact properties of the HAZs.

• Corrosion Science and Technology
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• v.5 no.4
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• pp.117-122
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• 2006

Hydrogen permeation measurements have been carried out on API X65 grade linepipe steel. In order to study the effect of steel microstructure on hydrogen diffusion behavior in linepipe steel, the accelerated cooling condition was applied and then three different kinds of microstructures were obtained. Hydrogen permeation measurement has been performed in reference to modified ISO17081 (2004) and ZIS Z3113 method. Hydrogen trapping parameters in these steels were evaluated in terms of the effective diffusivity ($D_{eff}$), permeability ($J_{ss}L$) and the amount of diffusible hydrogen. In this study, microstructures which affect both hydrogen trapping and diffusion were degenerated pearlite (DP), acicular ferrite (AF), bainite and martensite/austenite constituents (MA). The low $D_{eff}$ and $J_{ss}L$ mean that more hydrogen can be trapped reversibly or irreversibly and the corresponding steel microstructure is dominant hydrogen trapping site. The large amount of diffusible hydrogen means that corresponding steel microstructure is predominantly reversible. The results of this study suggest that the hydrogen trapping efficiency increases in the order of DP, bainite and AF, while AF is the most efficient reversible trap.

• Journal of Welding and Joining
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• v.12 no.4
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• pp.41-49
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• 1994

This study is to compare the welding quality of API 5L-X65 Steel- pipe's for natural gas transmission piping applied by SAW at shop and by GTAW-SMAW at site. The results can be summarized as follows; 1) Tensile strength of the welded zone by SAW(611.5 MPa) and by GTAW-SMAW(608.6 MPa) was maintained greater than that of the base metal(583.5 MPa). 2) Hardness of the welded zone and HAZ by SAW(Hv 194.8) & GTAW-SMAW (Hv 196.1) was slightly increased above that of the base metal (Hv 168.8), but less than the maximum allowable hardness(Hv 248). 3) Impact value of the welded zone by SAW(126.8 J) & GTAW-SMAW(88 J) became lower than that of the base metal(282.5 J), but was above the requirement of API 5L(68J). 4) Microscopic structure of the welded zone and HAZ by both SAW & GTAW-SMAW became fine-grained.

• Proceedings of the KSME Conference
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• 2001.06a
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• pp.453-458
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• 2001

Pipelines have the highest capacity and are the safest and the least environmentally disruptive way for gas or oil transmission. Recently, failures due to corrosion defects have become of major concern in maintaining pipeline integrity. A number of solutions have been developed for the assessment of remaining strength of corroded pipelines. However, these solutions are known to be dependent on material properties and pipeline geometries. In this paper, a Fitness-For-Purpose type limit load solution for corroded gas pipelines made of the X65 steel is proposed. For this purpose, a series of burst tests with various types of corrosion defects are performed. Finite element simulations are carried out to derive an appropriate failure criterion. And then, further, extensive finite element analyses are performed to obtain the FFP type limit load solution for corroded X65 gas pipelines as a function of defect depth, length and pipeline geometry. And also, a window based computer program far the assessment of corrosion defect, which is named as COPAP(COrroded Pipeline Assessment Program) has been developed on the basis of proposed limit load solution.

• Korean Journal of Materials Research
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• v.32 no.3
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• pp.168-179
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• 2022

Microbiologically Influenced Corrosion (MIC) occurring in underground buried pipes of API 5L X65 steel was investigated. MIC is a corrosion phenomenon caused by microorganisms in soil; it affects steel materials in wet atmosphere. The microstructure and mechanical properties resulting from MIC were analyzed by OM, SEM/EDS, and mapping. Corrosion of pipe cross section was composed of ① surface film, ② iron oxide, and ③ surface/internal microbial corrosive by-product similar to surface corrosion pattern. The surface film is an area where concentrations of C/O components are on average 65 %/16 %; the main components of Fe Oxide were measured and found to be 48Fe-42O. The MIC area is divided into surface and inner areas, where high concentrations of N of 6 %/5 % are detected, respectively, in addition to the C/O component. The high concentration of C/O components observed on pipe surfaces and cross sections is considered to be MIC due to the various bacteria present. It is assumed that this is related to the heat-shrinkable sheet, which is a corrosion-resistant coating layer that becomes the MIC by-product component. The MIC generated on the pipe surface and cross section is inferred to have a high concentration of N components. High concentrations of N components occur frequently on surface and inner regions; these regions were investigated and Na/Mg/Ca basic substances were found to have accumulated as well. Therefore, it is presumed that the corrosion of buried pipes is due to the MIC of the NRB (nitrate reducing bacteria) reaction in the soil.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2005.10a
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• pp.808-813
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• 2005

Structural integrity assessment of defected pipe is important in fitness for service evaluation and proper engineering assessment is needed to determine whether pipelines are still fit for service. This paper present a failure prediction of gas pipes made of APIl X65 steel with gouge using stress-modified true fracture strain, which is regarded as a criterion of ductile fracture. For this purpose, API X65 pipes with gouge are simulated using elastic-plastic FE analyses with the proposed ductile failure criterion and the resulting burst pressures are compared with experimental data. Agreements are quite good, which gives confidence in the use of the proposed criteria to defect assessment fer gas pipelines. Then, further extensive finite element analyses are performed to obtain the burst pressure solution of pipes with gouge as a function of defect depth, length and pipeline geometry.

• Journal of Welding and Joining
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• v.28 no.3
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• pp.65-72
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• 2010

Some structural members of large-scale marine vessels such as large-scale offshore structures and very large container ships are assembled by very thick plates of which thickness exceeds 60mm. Also, high-tensile steels have been selected to meet the required structural strength and fatigue strength. Generally, multi-pass welding method such as FCA(Flux-Core Arc) welding has been used to join the thick plates. Considering the welding residual stresses, fatigue strength of the welded joints of thick plates should be assured since the residual stress influences the fatigue strength. This paper presents a numerical procedure to investigate the residual stress of structure joined by multi-pass FCA welding so that it can be incorporated into the fatigue strength assessment considering the effect of welding residual stress. The residual stress distribution is also measured by X-Ray diffraction method. The residual stress obtained by the computational model also has been compared with that of experiment. The results of FEA are in very good agreement with the experimental measurements.

• Corrosion Science and Technology
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• v.2 no.3
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• pp.109-116
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• 2003

It is well known that SSCC (sulfide stress corrosion cracking) is caused by drastic ingression of hydrogen during the service and accumulation of hydrogen near the potential crack initiation site in the material. It is important to characterize the hydrogen trapping behavior to evaluate the service performance of the high strength pipeline steels. In this study. the relationship between the hydrogen trapping behavior and SSCC susceptibility is evaluated in terms of alloy composition, microstructure and carbide behavior. The hydrogen trapping behavior was measured by electrochemical hydrogen permeation test cell (Devanathan cell). The SSCC susceptibility is evaluated by constant extension rate test and constant strain lest method. The hydrogen trapping behavior is affected greatly by microstructure and nature of carbide particles. The fine TiC, and NbC in the matrix of ferritic structure acts as strong irreversible trap sites whereas the bainitic structure acts as reversible trap site. The SSCC susceptibility is closely related to not only the hydrogen trapping behavior but also the loading condition. As the activity of reversible trap site increases, SSCC susceptibility decreases under static loading condition below yield strength, whereas SSCC susceptibility increases under dynamic loading condition or above yield strength. As the activity of irreversible trap site increases. SSCC susceptibility increases regardless of loading condition. It is cased by the mixed effect of dislocation on hydrogen diffusion and trapping behavior.

• Corrosion Science and Technology
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• v.8 no.4
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• pp.133-138
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• 2009

For the corrosion protection of the natural gas transmission pipelines, two methods are used, cathodic protection and coating technique. In the case of cathodic protection, defects are embrittled by occurring hydrogen at the crack tip or material surface. It is however very important to evaluate whether cracks in the embrittled area can grow or not, especially in weld metal. In this work, on the basis of elastic plastic fracture mechanics, we performed the CTOD testing with various test conditions, such as testing rate and potential. The CTOD of the base metal and the weld metal showed a strong dependence of the test conditions. The CTOD decreased with decreasing testing rate and with increasing cathodic potential. The morphology of the fracture surface showed the quasi-cleavage at low testing rate and cathodic overprotection. The low CTOD was caused by hydrogen embrittlement at crack tip.

• Transactions of Materials Processing
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• v.33 no.3
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• pp.208-213
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• 2024

Ni-based superalloys have exceptional performance in high-temperature strength, corrosion resistance, etc, and it has been widely used in various applications that require corrosion resistance at high-temperature operations. However, the relatively expensive cost of the Ni-based superalloys is one of the major hurdles. The corrosion-resisted alloy(CRA) clad materials can be a cost-effective solution. In this study, finite element analysis of the hot rolling process for manufacturing of the Alloy 625/API X65 steel CRA clad plates is conducted. The stress-strain curves of the two materials are measured in compressive tests for various temperature and strain rate conditions, using the Gleeble tester. Then, strain hardening behavior is modeled following the modified Johnson-Cook model. Finite element analysis of the hot rolled cladding process is performed using this strain rate and temperature dependent hardening model. Finally, the thickness ratio of the CRA and base material is predicted and compared with experimental values.