• Journal of the Korean Chemical Society
• /
• v.46 no.6
• /
• pp.541-544
• /
• 2002

Prepartion of the title compounds at 0-5$^{\circ}C$ is reported along with their AM1 SCF MO calculations. The advantage of this procedure is the hight purity of the produ cts.

• Journal of the Korea Institute of Information Security & Cryptology
• /
• v.23 no.4
• /
• pp.639-653
• /
• 2013

Smart grid is a network of computers and power infrastructure that monitor and manage energy usage efficiently. Recently, the smart grid demonstration projects around the world, including the United States, Europe, Japan, and the technology being developed. The protection of the many components of the grid against cyber-threats has always been critical, but the recent Smart grid has been threatened by a variety of cyber and physical attacks. We model and analyze advanced metering infrastructure(AMI) in smart grid. Using attack countermeasure tree(ACT) we show qualitative and probabilistic security analysis of AMI. We implement using SHARPE(Symbolic Hierarchical Automated Reliability and Performance Evaluator) tool and calculate probability, ROA, ROI, Structure Importance, Birnbaum Importance.

• Korean Journal of Remote Sensing
• /
• v.36 no.6_1
• /
• pp.1323-1337
• /
• 2020

GEO-KOMPSAT-2A AMI (Advanced Meteorological Imager) radiometric calibration evaluation is an essential element not only for functional and performance verification of the payload but for the quality of the sensor data. AMI instrument consists of six reflective channels and ten thermal infrared ones. One of the key parameters representing radiometric properties of the sensor is a SNR (Signal-to-Noise Ratio) for the reflective channels and a NEdT (Noise Equivalent delta Temperature) for the IR ones respectively. Other important radiometric calibration parameters are a dynamic range and a gain value related with the responsivity of detectors. To verify major radiometric calibration performance of AMI, an offline radiometric evaluation tool was developed separately with a real-time AMI data processing system. Using the evaluation tool, validation activities were carried out during the GEO-KOMPSAT-2A In-Orbit Test period. The results from the evaluation tool were cross checked with those of the HARRIS, which is the AMI payload vendor. AMI radiometric evaluation activities were conducted through three phases for both sides (Side 1 and Side 2) of AMI payload. Results showed that performances of the key radiometric properties were outstanding with respect to the radiometric requirements of the payload. The effectiveness of the evaluation tool was verified as well.

• Korean Journal of Remote Sensing
• /
• v.37 no.2
• /
• pp.359-365
• /
• 2021

GEO-KOMPSAT-2A (GK2A) AMI (Advanced Meteorological Imager) Best Detector Select (BDS) map is pre-determined and uploaded before the satellite launch. After the launch, there is some possibility of a detector performance change driven by an abrupt temperature variation and thus the status of BDS map needs to be evaluated and updated if necessary. To investigate performance of entire elements of the detectors, AMI BDS analyses were conducted based on a technical note provided from the AMI vendor (L3HARRIS). The concept of the BDS analysis is to investigate the stability of signals from detectors while they are staring at targets (deep space and internal calibration target). For this purpose, Long Time Series (LTS) and Output Voltage vs. Bias Voltage (V-V) methods are used. The LTS for 30 secs and the V-V for two secs are spanned respectively for looking at the targets to compute noise components of detectors. To get the necessary data sets, these activities were conducted during the In-Orbit Test (IOT) period since a normal operation of AMI is stopped and special mission plans are commanded. With collected data sets during the GK2A IOT, AMI BDS map was intensively examined. It was found that about 1% of entire detector elements, which were evaluated at the ground test, showed characteristic changes and those degraded elements are replaced by alternative best ones. The stripping effects on AMI raw images due to the BDS problem were clearly removed when the new BDS map was applied.

• Journal of the Korean Institute of Telematics and Electronics
• /
• v.18 no.6
• /
• pp.30-37
• /
• 1981

Numerical calculations have beee made of the effect of grain size on the three-dimensional carrier density, the quantum efficiency, and the AMI efficiency of 30$\mu$m polycrystalliue silicon p-n junction solar cells. Quantum efficiencies calculated for the polycrystalline silicon solar cells are compared to the monocrystalline cases. An efficiency of 12% can theoretically be obtained with grain size 100$\mu$m, and 6% for 5$\mu$m grains.

• Annual Conference on Human and Language Technology
• /
• 2022.10a
• /
• pp.307-312
• /
• 2022

상호참조해결은 주어진 문서에서 멘션을 추출하고 동일한 개체의 멘션들을 군집화하는 작업이다. 기존 상호참조해결 연구의 멘션탐지 단계에서 진행한 가지치기는 모델이 계산한 점수를 바탕으로 순위화하여 정해진 비율의 멘션만을 상호참조해결에 사용하기 때문에 잘못 예측된 멘션을 입력하거나 정답 멘션을 제거할 가능성이 높다. 또한 멘션 탐지와 상호참조해결을 종단간 모델로 진행하여 학습 시간이 오래 걸리고 모델 복잡도가 높은 문제가 존재한다. 따라서 본 논문에서는 상호참조해결을 2단계 파이프라인 모델로 진행한다. 첫번째 멘션 탐지 단계에서 후보 단어 범위의 점수를 계산하여 멘션을 예측한다. 두번째 상호참조해결 단계에서는 멘션 탐지 단계에서 예측된 멘션을 그대로 이용해서 서로 상호참조 관계인 멘션 쌍을 예측한다. 실험 결과, 2단계 학습 방법을 통해 학습 시간을 단축하고 모델 복잡도를 축소하면서 종단간 모델과 유사한 성능을 유지하였다. 상호참조해결은 Light에서 68.27%, AMI에서 48.87%, Persuasion에서 69.06%, Switchboard에서 60.99%의 성능을 보였다.

• Korean Journal of Remote Sensing
• /
• v.38 no.2
• /
• pp.179-188
• /
• 2022

Global warming causes climate change and increases extreme weather events worldwide, and the occurrence of heatwaves and droughts is also increasing in Korea. For the monitoring of extreme weather, various satellite data such as LST (Land Surface Temperature), TCI (Temperature Condition Index), NDVI (Normalized Difference Vegetation Index), VCI (Vegetation Condition Index), and VHI (Vegetation Health Index) have been used. VHI, the combination of TCI and VCI, represents the vegetation stress affected by meteorological factors like precipitation and temperature and is frequently used to assess droughts under climate change. TCI and VCI require historical reference values for the LST and NDVI for each date and location. So, it is complicated to produce the VHI from the recent satellite GK2A (Geostationary Korea Multi-Purpose Satellite-2A). This study examined the retrieval of VHI using GK2A AMI (Advanced Meteorological Imager) by referencing the historical data from VIIRS (Visible Infrared Imaging Radiometer Suite) NDVI and LST as a proxy data. We found a close relationship between GK2A and VIIRS data needed for the retrieval of VHI. We produced the TCI, VCI, and VHI for GK2A during 2020-2021 at intervals of 8 days and carried out the interpretations of recent extreme weather events in Korea. GK2A VHI could express the changes in vegetation stress in 2020 due to various extreme weather events such as heatwaves (in March and June) and low temperatures (in April and July), and heavy rainfall (in August), while NOAA (National Oceanic and Atmospheric Administration) VHI could not well represent such characteristics. The GK2A VHI presented in this study can be utilized to monitor the vegetation stress due to heatwaves and droughts if the historical reference values of LST and NDVI can be adjusted in a more statistically significant way in the future work.

• Journal of the Korean Chemical Society
• /
• v.35 no.6
• /
• pp.636-644
• /
• 1991

The cationic polymerization of substituted oxethanes which have pendant energetic groups such as methoxy, azido, and nitrato are investigated theoretically using the semiempirical MINDO/3, MNDO, and AM1 methods. The nucleophilicity and basicity of substituted oxethanes can be explained by the negative charge on oxygen atom of oxetanes. The reactivity of propagation in the polymerization of oxetanes can be represented by the positive charge on carbon atom and the low LUMO energy of active species of oxetanes. The reaction of the energetic cyclic oxonium ion forms to the open chain carbenium ion forms is expected by computational stability energy of the oxonium and carbenium ion (about 10~20 kcal/mole) favoring the carbenium ion. The relative equilibrium concentration of cyclic oxonium and open carbenium ions is found to be a major determinant of mechanism, owing to the rapid equilibrium of these cation forms and the expectation based on clauclation that the prepolymer propagation step SN1 mechanism will be at least as fast as that for SN2 mechanism.

• Journal of the Korean Chemical Society
• /
• v.37 no.1
• /
• pp.62-67
• /
• 1993

The microscopic origin of nonlinear optical properties of quinoline derivatives have been investigated theoretically using MOPAC-AM1 method. In order to prepare promising nonlinear optical active polymers of polyquinoline derivatives, the optimized positions of strong electron donor and electron acceptor are determined in the heterocyclic ring for the energetically favorable structures. For each compound, the effect of the substituted positions on the microscopic nonlinear coefficients were investigated. Polyquinoline was already evaluated to have outstanding physical and mechanical properties so that its monomeric analogues were designed and synthesized for developing new second and third order nonlinear optical main chain polymers. Using the MOPAC-AM1 method, properties calculated include the intrinsic ground-state dipole moments, the polarizabilities, first and second hyperpolarizabilities under the condition of finite-field $(\omega$ = 0).

• Applied Chemistry for Engineering
• /
• v.20 no.2
• /
• pp.159-164
• /
• 2009

Monomers of oxetane high explosives were theoretically examined in terms of reactivity, reaction mechanism and process of polymerization substituted by azido $(-CH_2N_3)$, nitrato $(-CH_2ONO_2)$ and hydrazino $(-CH_2N_2H_3)$ which belong to the 5th class hazardous materials and have explosiveness under acid catalyst using MINDO/3, MNDO, and AMI methods for formal charge, heat of formation, and energy level. Nucleophilicity and base of oxetane high explosives could be explained by negative charge size of oxetane oxygen atom and reactivity of oxetane in the growth stage of polymerization under acid catalyzer could be expected to be governed by positive charge size of axial carbon atom and low LUMO energy of electrophile. It could be estimated that carbenium ion was more beneficial in the conversion process of oxetane high explosives than that of stabilization energy (13.90~31.02 kcal/mole) of oxonium ion. In addition, concentration of oxonium ion and carbenium ion in equilibrium state influenced mechanism and it was also estimated that $S_N1$ mechanism reacts faster than that of $S_N2$ in prepolymer growth stage considering quick equilibrium based on form and calculation of polymerization under acid catalyzer.