• Title/Summary/Keyword: AGET ATRP

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4-Arm Star Shaped and Linear Block Copolymers for Copper Phthalocyanine Dispersion (4-Arm 스타형과 선형 블록 공중합체의 구리 프탈로시아닌 분산 연구)

  • Kim, Byoungjae;Jeong, Jonghwa;Jung, Ji-Hye;Kim, Bong-Soo;Jung, Ki-Suck;Paik, Hyun-Jong
    • Polymer(Korea)
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    • v.38 no.5
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    • pp.671-675
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    • 2014
  • Well-defined star shaped and linear block copolymers were synthesized to study the dispersion stability of copper phthalocyanine (CuPc). We synthesized dispersants using (2-dimethylamino) ethyl methacrylate (DMAEMA) and poly(ethylene glycol) methyl ether methacrylate) (PEGMA) by activators generated by electron transfer (AGET) atom transfer radical polymerization (ATRP). pDMAEMA-b-pPEGMA copolymers were characterized by GPC and NMR. Furthermore, we studied the effect of the dispersion stability of copper phthalocyanine by controlling the degree of polymerization of PEGMA as a stabilizing group. The 4-arm star shaped polymeric dispersant showed better dispersion stability of CuPc at $25^{\circ}C$ for 7 days.