• 방재와보험
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• s.36
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• pp.31-33
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• 1988

1960년대까지는 저팽창단백포가 유류화재의 진압에 주로 사용되었으니 불소화합물 계면활성제로부터 유출된 합성 AFFF를 개발하면서 해수로도 이의 사용이 가능하고 지역 및 유출화재 예방에서 AFFF 특유의 초기진압효과 및 대형화재를 방지한다는 장점 때문에 널리 사용되고 있으며, 석유화학산업의 저장탱크지역 및 공정지역에서 AFFF와 FPF가 주로 사용되며 부두시설(Oilrig, Marine Tanker, 해상 / 해변터미널)에는 AFFF의 사용이 지배적이다. 현재 사용되고 있는 foam으로는 단백포(Protein: PF), 불화단백포(Fluoroprotein: FPF), 막형성 불화단백포(Film Forming Fluoroprotein Foam: FFFP), 고팽창폼(High Expansion Foam), 수성막 형성폼(Aqueous Film Foaming Foam: AFFF), 알콜폼(Alcohol Resistant Foam: ATD) 등이 있으니 본고에서는 AFFF 중심으로 소개한다.

• Applied Chemistry for Engineering
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• v.34 no.6
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• pp.603-607
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• 2023

Aqueous film forming foam (AFFF) is a critical fire suppression agent used in combating hydrocarbon fires. This type of fire suppressant is highly effective due to its ability to form a protective film, dissipate heat, inhibit combustion, and utilize a blend of chemical substances to extinguish fires. While these properties offer significant advantages in responding to hydrocarbon fires, AFFF is distinct in its deployment as it is dispensed in the form of foam. Therefore, the rheological analysis of AFFF foam using a rheometer plays a crucial role in predicting the spray characteristics of AFFF for combating hydrocarbon fires, and this is closely associated with effective fire suppression. In this study, we conducted rheometer experiments to confirm the non-Newtonian behavior (shear-thinning) of AFFF foam and obtained data on the form's stability. These experimental data are expected to contribute to enhancing the efficiency of fire suppression systems utilizing AFFF.

• Journal of the Korean Society of Safety
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• v.24 no.5
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• pp.21-27
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• 2009

Effective way of cooking oil fire extinguishment is using water mist system which has cooling and smothering effects. Low pressure water mist system has advantage because it is compatible with existing sprinkler systems. To increase the effectiveness of low pressure water mist system, additives can be used which increase the momentum of water particle and the chemical effect. In this experiment, aqueous film forming form(AFFF) agent is used as additive and the effect of additive concentration and water pressure are experimented. For the extinguishment of cooking oil fire such as soybean and olive oils, AFFF agent is effective and can decrease the fire extinguishing time and water consumption.

• Fire Science and Engineering
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• v.10 no.3
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• pp.29-40
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• 1996

The AFFF(Aqueous Film Forming Foam : 3M Company's Light Water) agent are synthetic compounds that foams which are similar to those produced by protein based materials. The foam extinguishing agent was used In the extinguisher was the AFFF agent. We sought, however, to make other foams by using halon 1301 (CF$_3$Br) and halon alternatives, such as HCFC Blend A($CHCIF_2$ 82%, $CF_3$CHCIF 9.5%m $C_{10}$$H_{16}$ 3.75%), HFC-227ea ($CF_3$ $CHFCF_3$) We selected these alternatives instead of air in order to raise the expansion ratio of the AFFF agent. By these means we discovered that it is possible to increase the expansion ratio of the AFFF agent up to 44:1 and up to 24:1 when HFC-227ea was used as a halon alternatives. Therefore our new foam extinguishing agents can be used in a portable extinguish agents can be used in a portable extinguishers.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 1996.11a
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• pp.57-61
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• 1996

Our goal was to make a cost-effective automatic fire extinguishing system for the engine compartment use of automobiles. We designed this system for the engine compartment. This system consists of 1)foam extinguisher, 2)four nozzles, 3)a pipe arrangement, and 4)an extinguishing device which is equipped with a glass bulb as detector. First and foremost, the extinguishing device was carefully designed to keep the system cost to a minimum. Second, a AFFF foam extinguisher was used because no other fire-fighting agents proved effective against fire in the engine compartment. The AFFF(Aqueous Film Forming Foam) agent which was used in the extinguisher is the 3M company's Light Water. We sought, however, to make other foams by using Halon 1301 and Halon alternatives such as HCFC Blend A, HFC-227ea. We selected these alternatives instead of air in order to raise the expansion ratio of the AFFF agent. By these means we discovered that it is possible to increase the expansion ration of the AFFF agent up to 44:1. We then demonstrated that our automatic fire extinguishing system is the most effective and lowest cost-system yet devised for passenger cars.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 1997.11a
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• pp.598-605
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• 1997

In recent years, the number of vehicle fires, as well as the number of motor vehicles, has been increasing rapidly. Therefore, several types of automatic fire suppression systems for the engine compartment of automobiles have been developed to extinguish automobile fires, and most of these systems use halon 1301 as a fire extinguishing agent. Due to environmental concerns, the phase-out of halons has been announced, so now there is a need to replace halon 1301. For this, a 1,1,1,2,3,3,3-heptaflouropropane (HFC-227ea, FM-$200^{TM}$) gas-filled Aqueous Film- Forming foam (known as AFFF) extinguisher was devised even though air foam extinguishers could be used. This is because the air in the foam bubbles is a source of oxygen required for the combustion reaction. It can be surmised that it is possible to increase the fire extinguishing efficiency of AFFF by filling in foam bubbles with a gaseous extinguishing agent. The best choice is the FM-$200^{TM}$ gas-filled AFFF, Which has the maximum expansion ratio of 62:1. This makes it possible for the expanded foam to rapidly fill the engine compartment.

• Fire Science and Engineering
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• v.27 no.6
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• pp.8-14
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• 2013

This research is to evaluate the fire extinguishing performance at a mixing ratio of pressurized air in the fire extinguishing system of compressed air foam (CAF) which injects compressed air into foam liquid and then discharging. The experimental device is made use of exclusive foam extinguishing facility for compressed air foam that is produces based on Canada National Laboratory and UL 162 standard, apply model of oil fire (B Class) 20 unit in accordance with "Standard of Model Approval and Product Inspection for Fire Extinguishing Agent" to the fire Extinguishing model. Compressed air is injected through the air mixture and study the tendency depending on increasing air foam ratio 1 : 4, 1 : 7, 1 : 10. In addition, the comparison experiments between synthetic surfactants foam and AFFF carry out with it at the air foam ratio 1 : 4. As a result, in the condition of same discharging flow, fire extinguishing effect of AFFF is the fastest at the air foam ratio 1 : 7 and the slowest at 1 : 10. Moreover, the fire extinguishing effect of AFFF in the comparison expeiments between AFFF and synthetic surfactants foam is faster than the other.

• Applied Chemistry for Engineering
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• v.35 no.3
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• pp.239-247
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• 2024

When a fire occurs on a naval vessel, rapid suppression and control are essential to mitigate potential human and material losses. Due to the nature of naval vessels, the risk of fuel fires is significant, making the use of aqueous film-forming foam (AFFF) crucial for effective fire suppression. Additionally, the possibility of fires occurring within compartments on the vessel must also be considered. Understanding the trajectory and application range of AFFF in such environments is vital, necessitating the design of firefighting systems tailored to compartmental conditions. In this study, an analysis was conducted to investigate the feasibility of applying spray height and angle for AFFF using computational fluid dynamics (CFD) methodology as a validation tool. Based on these findings, CFD analysis results applicable to compartment environments on naval vessels were obtained. These results will serve as the foundation for the development of firefighting systems capable of promptly responding to fuel fires within naval vessel compartments.

• Fire Science and Engineering
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• v.16 no.1
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• pp.1-7
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• 2002

Halogen-based fire suppressing agents have environmental problems because they cause the stratospheric ozone depletion and globe warming. Hence, fire suppression system using fine water mist became the center of interest as a substitution of halon. As a study about this, it is in progress to make the optimum droplet size by using water mist nozzles and to improve the extinguishing performance of water mist by using additives. Before this study, the extinguishing time of ethanol and n-heptane pool fire was measured with changing of water mist droplet size, flow density, discharge pressure, and fire size. In this study, on adding the additives to improve physical and chemical extinguishing performance of water mist, the extinguishing performance would evaluate and the optimum condition would find out. As a result, in case of ethanol pan 1 pool fire, the extinguishing time of the water mist by adding of 2.5 wt% NaCl and 0.3% AFFF got shorter 27% and 60% than the pure water mist. Adding of AFFF was to decrease the flame temperature by forming thin film on the fuel surface and to decrease the evaporation of n-heptane fuel. In case of NaCl, alkali salt crystals showed on the flame surface.

• Fire Science and Engineering
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• v.23 no.2
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• pp.78-84
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• 2009

We carried out fire extinguishing experiments with three kinds of water mist nozzle system. Fire extinguishing experiment according to installed nozzle height and fuel pan location was done. And fire extinguishing performance was compared with plain water and foam agent mixed solution. Water mist nozzle height was varied with 4m, 3.5m and 3m and position of fuel fan was varied 0.5m and 1m from the center of water mist nozzle. Foam agent that used in this experiment is 3% type of AFFF (Aqueous Film Forming Foam) solution. Experimental result showed the door opening effect was little. Fire extinguishing performance of foam agent mixture water mist was better than the plain water mist only.