• Title/Summary/Keyword: ACF 공정

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A Study on Hybrid DeNOx Process Using Selective Catalytic Reduction and Adsorption (선택적촉매환원과 흡착을 이용한 복합 탈질공정 연구)

  • Moon, Seung-Hyun;Jeon, Dong-Hwan;Park, Sung-Youl
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.12
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    • pp.1329-1336
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    • 2007
  • This study was carried out to develop an efficient process abating high NO concentration. A hybrid process of selective catalytic reduction(SCR) and activated carbon fiber(ACF) adsorption was newly designed and tested. Used ACF in NO adsorption was regenerated by simultaneously applying heat and vacuum. The result of ACF regeneration was for superior in the desorption condition at $140^{\circ}C$ and vacuum 600 mmHg. A commercial catalyst was used at the conditions of reaction temperature at $300^{\circ}C$, $NH_3/NO$ mole ratio = 1.0 for SCR process. NO evolved from ACF regeneration reactor could be removed by SCR reactor up to 98%. But high concentration of NO was exhausted from SCR reactor for one minute when the flue gas of NO 300 ppm and deserted NO from ACF regeneration were simultaneously treated by the same SCR reactor. Therefore, it is necessary to use additional small sized SCR reactor or to increase $NH_3$ concentration for a short time along with NO concentration rather than to mix flue gas with the gas evolving from ACF regeneration at fixed $NH_3$ inlet concentration. The hybrid process of SCR and ACF showed high NO removal efficiency over 80% at any time courses. Through the repeated cycles, stable DeNOx efficiency was maintained, indicating that the hybrid process would be a good countermeasure to the spotaneously high NO concentration instead of increasing the SCR capacity.

Effect of Pre-Treatment by Ozone on Chemical Surface Modification of Activated Carbon Fiber (오존에 의한 전처리가 활성탄소섬유 화학적 표면개질에 미치는 영향)

  • Jang, Jung Hee;Han, Gi Bo;Kim, Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.6
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    • pp.415-421
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    • 2013
  • To increase specific surface property of activated carbon fiber(ACF), chemical activation(CA) using alkali metals and surface treatment(ST) using oxidant was widely used. The CA and ST process developed micro-pore on the surface of ACF by chemical reaction of the alkali metals and oxidative of oxidant, respectively. To improve the efficiency of CA process for developing micro-pores on the surface of ACF, the ST process was adopted as an pre-treatment method. After treatment of ST process, ACF properties was investigated depending on the ST pre-treatment process. FT-IR, TG and elemental analysis of the ACF are carried out, and an adsorption property of ACF was also evaluated using toluene(which in typical volatile organic matter). Once the single CA process is used, the surface area and adsorption capacity of ACF were increased from 1,483 to 1,988 $m^2/g$ and from 0.22 to 0.27 $g_{-Tol.}/g_{-ACF}$, respectively. On the other hands, once the ST and CA processes are used successively, the surface area and adsorption capacity of ACF are greatly increase(where the surface area is 2,743 $m^2/g$ and the adsorption capacity is 0.37 $g_{-Tol.}/g_{-ACF}$). It indicates that the combined process of ST and CA can improve the surface process properties of ACF.

다이오드 레이저를 이용한 이방 전도성 필름(ACF) 접합

  • 류광현;서명희;남기중;곽노흥
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2005.09a
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    • pp.45-48
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    • 2005
  • 디스플레이 모듈에서 hot plate를 이용한 이방 전도성 필름(ACF: Anisotropic Conductive Film) 접합의 공정을 고출력 다이오드 레이저를 이용한 공정으로 대체하였다. 다이오드 레이저를 이용한 ACF 접합은 공정 시간을 기존보다 줄일 수 있으며 평탄도 및 응용성에 있어서 hot plate 공정보다 뛰어나다. 또한 다양한 샘플에도 지그 및 레이저광의 자유로운 변형으로 응용성이 매우 뛰어나다. 에너지 분포가 고른 선광을 이용하여 ACF 접합을 수행하였다. 레이저 에너지 밀도 $100\;W/cm^2$, 압력 20 kg, 레이저 조사시간 4초 이상에서 800 gf/cm 이상의 인장력을 얻을 수 있었고 기존의 공정 시간을 두 배 이상 단축하였다.

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Substitutability of coagulation process by pre-treatment of coagulation·flotation using natural algae coagulant (천연조류제거제를 활용한 응집·부상 전처리공정의 기존 응집공정 대체 가능성)

  • Jang, Yeo-Ju;Jung, Jin-Hong;Lim, Hyun-Man;Chang, Hyang-Youn;Kim, Weon-Jae
    • Journal of Korean Society of Water and Wastewater
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    • v.31 no.1
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    • pp.39-50
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    • 2017
  • In the coagulation/sedimentation (C/S) process of the water treatment process, the inflow of massive algal bloom causes many problems including fouling of filter media. This study was conducted to find out the way to remove the algae's harmful effects by addition of pre-treatment prior to C/S process. Many Jar-tests were conducted such as (1) ACF (Algae Coagulation Flotation) process using natural algae coagulant (Water $Health^{(R)}$), (2) ACF + C/S process and (3) C/S process with a variety of conditions using cultured algae. The average values of turbidity were (1) 0.42 NTU for ACF process, (2) 0.13 NTU for ACF + C/S process and (3) 0.25 NTU for C/S process. It was shown that the treatment efficiency of ACF process could get low turbidity results, and ACF + C/S process could achieve more efficient results than those of C/S process. Any negative effects of ACF process to the efficiency of C/S process were not observed in ACF + C/S process. In order to reduce the unfavorable effects of algae, it was found out that the introduction of ACF process in the forms of (1) ACF or (2) ACF + C/S could be one of the effective and alternative solutions.

The Adsorption Characteristics by the Optimun Activation Process of PAN-based Carbon Fiber and SO2 Adsorption Characteristics by the Impregnated Nanoparticles (PAN계 ACF의 최적 활성화 공정에 따른 흡착특성과 나노입자 첨착에 의한 SO2 흡착특성)

  • Lee, Jin-Jae;Kim, Young-Chai
    • Applied Chemistry for Engineering
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    • v.17 no.5
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    • pp.532-538
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    • 2006
  • The carbonization and activation conditions for the PAN-based ACF of various grade were investigated to obtain the optimun activation condition with high surface area. And the surface properties and the absorption performance of toxic gas for terror were examined toward the PAN-ACF with the highest surface area. In the test results the surface area increased with increase of the activation temperature, but decreased with increase of the carbonization temperature. After carbonization condition ($900^{\circ}C$-15min) and activation condition ($900^{\circ}C$-30 min), we got the ACF with the highest surface area of $1204m^2/g$. In the absorption test of iodine and toxic gas for terror, this ACF showed more excellent absorption performance than the existing carbon-based adsorbent. Also, in order to give the function characteristic for a selective absorption, the stable nanoparticles of the Ag, Pt, Cu, Pd were prepared and impregnated on the PAN-based ACF in replacement of the existing method supporting metal catalysis. And were analyzed the surface characteristics and the $SO_{2}$ adsorption characteristics. In the $SO_{2}$ absorption performance test of the PAN-ACF with the impregnated nanoparticles, it wasn't change breakthrough time of Ag, Pt, Cu nanoparticle supported the PAN-ACF comparing with breakthrough time (326 sec) of the non supported PAN-ACF but Pd nanoparticle supported the PAN-ACF achieved excellent $SO_{2}$ absorption performance which has break-through time 925 sec.

Adsorption/Desorption Properties of ACF on Toluene and MEK with Operation Condition (공정 조건에 따른 톨루엔 및 MEK에 대한 ACF의 흡·탈착 특성)

  • Baek, Geun-Ho;Kim, Jung-Su;Jang, Hyun-Tae;Cha, Wang-Seog
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.6
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    • pp.2898-2903
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    • 2011
  • Adsorption/desorption characteristics of low concentration methylethylketone(MEK) and toluene vapors in beds packed with activated carbon fibers(ACF) was investigated. Performance of ACF adsorption was characterized by the equilibrium capacity, time to reach equilibrium and desorption efficiency. Experiments were carried out to define the effect of operation variables, such as feed concentration, flow rate, moisture content and bed height. The breakthrough time was shorten with the increase of temperature, flow rate and feed concentration. In addition, an increase of packed height of adsorbents lengthen the breakthrough time. The ACF loaded with MEK and toluene was satisfactorily regenerated by programed heating. It is observed that MEK is more easily removed than toluene at below temperature of $150^{\circ}C$.

Investigation of Treatment Efficiency for Advanced Processes of Water Treatment Plants in Korea (국내 정수장 고도정수처리 공정에서 공정별 처리효율 조사)

  • Mun, Sung-Min;Choi, Suing-Il;Sohn, Jin-Sik;Yoon, Je-Yong
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.3
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    • pp.323-329
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    • 2005
  • Advanced processes such as ozonation or activated carbon filtration (ACF) in water treatment plants have been used in Korea since 1994. At present, seventeen drinking water treatment plants are currently operating. This survey compares the treatment performance of advanced processes in eight plants which have comparable water quality data. The three parameters (DOC, $UV_{254}$, and $KMnO_4$ consumption) of water quality were selected as an indicator of treatment efficiency. The treatment efficiency of ozonation and ACF processes was found to vary with large deviations in each plant. Treatment efficiency of DOC, $UV_{254}$, and $KMnO_4$ consumption by post ozonation ranged from 3 to 11%, 6 to 33%, and 12 to 28% respectively. On the other hand, for ACF, treatment efficiency of DOC, $UV_{254}$, and $KMnO_4$ consumption ranged from 7 to 38%, 8 to 48%, and 16 to 66% respectively. These large deviations indicate the advanced processes of water treatment plants to be further optimized.