• Korean Journal of Chemical Engineering
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• 제35권12호
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• pp.2468-2473
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• 2018

Nitrogen-doped activated carbon fibers (ACFs) were prepared by chemical vapor deposition using melamine powder and acetonitrile for introducing quaternary nitrogen on the commercial ACFs, subsequently heated at $950^{\circ}C$ and activated by steam. Adsorption experiments of nitrate in aqueous solution were also conducted to evaluate adsorption capacity of the prepared ACFs using ion chromatography. The amount of introduced nitrogen content and nitrogen species on activated carbon fibers was examined by CHN elemental analyzer and X-ray photoelectron spectroscopy, respectively. As a result, adsorption capacity of quaternary nitrogen-doped ACF (ST-ML-AN-ST) was 0.75 mmol/g, indicating ca. two-times higher than that of untreated ACF (0.38 mmol/g). According to the adsorption data, the Langmuir isotherm model was the best fit. The prepared samples were also regenerated using hydrochloric acid. After regeneration, the adsorption capacity of the nitrogen-doped ACF (ST-ML-AN-ST) showed ca. 80% on average, implying that a portion of nitrates was adsorbed on the prepared ACFs irreversibly.

• Composites Research
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• 제36권6호
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• pp.402-407
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• 2023

Activated carbon fibers (ACFs) are fibrous form of activated carbon (AC) with higher mechanical strength and flexibility, which make them suitable for building modules for applications including directional gas flow such as air and gas purification. Similarly, ACFs are anticipated to excel in the efficient capture of CO₂. However, due to the difficulties in fabricating monofilament carbon fibers at a laboratory scale, most of the studies regarding ACFs for CO₂ capture have relied on electrospun carbon fibers. In this study, we fabricated monofilament carbon fibers from PAN-based monofilament precursors by stabilization and carbonization. Then, ACFs were successfully prepared by chemical activation using KOH. Different weight ratios ranging from 1:1 to 1:4 were employed in the fabrication of ACFs, and the samples were designated as ACF-1 to ACF-4, respectively. As a function of KOH ratio, increase in surface area could be observed. However, the CO₂ adsorption trend did not follow the surface area trend, and the ACF-3 with second largest surface area exhibited the highest CO₂ adsorption capacity. To understand the phenomena, nitrogen content and ultramicropore distribution, which are important factors determining CO₂ adsorption capacity, were considered. As a result, while nitrogen content could not explain the phenomena, ultramicropore distribution could provide a reasoning that the excessive etching led ACF-4 to develop micropore structure with a broader distribution, resulting in high surface area yet deteriorated CO₂ adsorption.

• 한국산업융합학회 논문집
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• 제26권6_3호
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• pp.1333-1339
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• 2023

To produce activated carbon fibers, the process is carried out through either physical activation method or chemical activation method. In this study, we present the results regarding the characteristics of activated carbon fibers manufactured under various conditions through the quantitative control of steam. The yield after activation indicates a decreasing trend with the increase in steam quantity and activation time. Additionally, specific surface area characteristics exhibit variations based on activation time and steam flow rate. The SEM analysis results reveal that higher steam flow rates lead to the presence of both mesopores and macropores on the surface of activated carbon fibers (ACF).

• Carbon letters
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• 제1권2호
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• pp.82-86
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• 2000

The present research was undertaken to evaluate the possibility of water purification filter with activated carbon fibers (ACFs) using a very low cost precursor consisting of phenolic resin coated on glass fibers. The simplified procedure involving coating, curing and activation and a very low cost glass fiber as a raw material were adopted in order to reduce manufacturing cost. The breakthrough curves of the manufactured ACFs and the commercial activated carbon (AC, Calgon F-200) were investigated in the initial concentration range from 19 to 49 ppm for benzene, toluene and ethylbenzene. From breakthrough profiles, the manufactured ACFs had significantly faster adsorption kinetics than the AC. Especially the benzene breakthrough curves, the manufactured ACF (13 g of ACF with 32% of carbon on the glass) was over the limited level (5 ppb) after flowing of 32 l at initial concentration of 15 ppm, while the commercial AC was shown about 3 ppm in initial adsorption.

• 한국연초학회지
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• 제25권2호
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• pp.111-119
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• 2003

In this work, Rayon-based activated carbon fiber(KF-1500) was treated by HN $O_3$ and $H_2$S $O_4$ with different conditions. Specific surface areas(SSA, $S_{BET}$) of the treated activated carbon fibers were decreased by acidic treatment but, total surface acidities and surface functional groups were increased. In spite of the decrease of SSA, propylamin(PPA) adsorption and removal ability by activated carbon fiber(ACF) were increased by nitric acid treatment compared with the raw-ACF(KF-1500) and coconut based activated carbon. However, acidic treated activated carbon fibers were available to removal for various amines and contaminants by adsorption.n.

• 분석과학
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• 제19권4호
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• pp.285-289
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• 2006

본 연구에서는 산 표면 처리한 입상 활성탄(GAC)과 활성 탄소섬유(ACF)에 의한 $Pb^{2+}$와 $Ni^{2+}$ 이온의 흡착 특성을 고찰하였다. 산 표면 처리용액으로는 1.0 M 질산 용액을 사용하였다. GAC와 ACF의 표면특성분석은 pH, 등전점(pHpzc), 그리고 원소분석기를 사용하였으며, 비표면적과 기공구조는 77K에서 $N_2$ 등온흡착 방법으로 측정하였다. 본 실험결과 GAC 와 ACF를 산으로 표면 처리한 경우 산소를 포함한 작용기가 증가하였다. 이처럼 산 표면 처리에 의해 증가된 표면 작용기에 따른 GAC 및 ACF의 기공이 막힘에도 불구하고, acidic-ACF > untreated-ACF > acdic-GAC > untreated-GAC 순으로 중금속 흡착능이 증가하였다.

• 한국수소및신에너지학회논문집
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• 제17권1호
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• pp.47-54
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• 2006

Activated carbon fibers (ACFs) with high surface area and pore volume were modified with metal Ni impregnation and fluorination and investigated hydrogen storage properties by volumetric method. Micropore volume values of ACFs obtained from surface modification with Ni impregnation and fluorination were decreased 9 and 35 %, respectively. Hydrogen storage capacities of fluorinated ACFs were slightly changed, on the other hand, that of Ni impregnated ACF was considerably increased. It means that hydrogen was not only adsorbed on ACF surface, but also on Ni metal surface by means of dissociation. Although the microphone volume of ACF modified with fluorination was decreased, its hydrogen storage were found not to be changed compared with fresh ACF. These results indicated that the surface of ACF after fluorination modification may be strongly attracted hydrogen due to high electronegativity of fluorine. Therefore, it was proven that hydrogen storage capacity was related with micropore volume and surface property of carbon materials as well as specific surface area.

• 한국안전학회지
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• 제31권1호
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• pp.66-73
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• 2016

Lyocell fibers were used as a precursor in order to improve yield and strength of cellulose-based precursor while manufacturing activated carbon fiber(ACF). Lyocell fibers as a precursor for the preparation of ACF were surface-modified by reaction with 3-aminopropyltriethoxysilane(APTES) and pre-treated with KOH and H3PO4. Using aforementioned precursor, ACFs were prepared by a series of stabilization, carbonization and activation process at high temperatures. On each process, FT-IR, TGA, UTM and SEM were used to observe fibers' physical properties including structure and porous surfaces. FT-IR results proved that surface modification was achieved during stabilization, carbonization and activation process. TGA results during carbonization process found that surface modified fibers with APTES 0.02 mol(A2) showed higher thermostability, and extended pre-treatment increased yield. Especially, yield was found to have an increase of 10~20 wt% with surface modification during activation process. UTM results showed that tensile strength has the same order of concentration of APTES after surface modification, however, was found to show lower tensile strength than lyocell fibers after stabilization process. SEM results revealed that more homogeneous porosity control could be proceed after modifying the surface for the effective removal of hazardous substances.

• 한국연초학회지
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• 제27권1호
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• pp.59-67
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• 2005

Activated carbon fiber (ACF) was surface modified by nitric acid to improve the adsorption efficiency of the propylamine. The adsorption amount of propylamine of the modified ACF increased $17\%$ more than that of as-received ACF. Desorption of propylamine from the propylamine saturated ACF was occurred in two steps, the first step started arround $50^{\circ}C$ showing the desorption of physically adsorbed propylamine and the second step started at $200^{\circ}C$ showing the decomposition of chemically adsorbed propylamine. Total desorption amount of propylamine from the modified ACF was larger than that of the as-received ACF because of increased functional groups. The oxygen and nitrogen contents on the modified ACF increased by 1.5 and 3 times compared with the as-received ACF. A part of propylamine adsorbed on ACF formed pyridine-like or pyrrolic structures with 2 carbons exposed on the surface of the ACF. It was found that propylamine reacted with strong or weak acidic functional groups such as -COOH or -OH existed on ACF surface.

• Carbon letters
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• 제5권4호
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• pp.186-190
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• 2004

In this work, a nickel metal (Ni) electroplating on the activated carbon fiber (Ni/ACFs) surfaces was carried out to remove the toxic hydrogen chloride (HCl) gas. The surface properties of the treated ACFs were determined by using nitrogen adsorption isotherms at 77 K, SEM, and X-ray diffraction (XRD) measurements. HCl removal efficiency was confirmed by a gas-detecting tube technique. As a result, the nickel metal contents on the ACF surfaces were increased with increasing the plating time. And, it was found that the specific surface area or the micropore volume of the ACFs studied was slightly decreased as increasing the plating time. Whereas, it was revealed that the HCl removal efficiency containing nickel metal showed higher efficiency values than that of untreated ACFs. These results indicated that the presence of nickel metal on the ACF surfaces played an important role in improving the HCl removal over the Ni/ACFs, due to the catalytic reactions between nickel and chlorine.