• Corrosion Science and Technology
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• 제6권5호
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• pp.261-268
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• 2007

Embedded sensors were used as an in-situcorrosion-sensing device for aircraft and vehicular structures protected by organic coatings. Results are presented changes associated with a standard Airforce aircraft coating and a standard Army vehicle coating were monitored by embedded sensors. These coatings consisted of a polyurethane topcoat and an epoxy primer, however are formulated to provide different characteristics. The ac-dc-ac testing method was used to accelerate the degradation of these coatings while being immersed in a NaCl medium. Electrochemical impedance spectroscopy and electrochemical noise measurement experiments were used to monitor the induced changes. A comparison of the results between coatings subjected to the ac-dc-ac exposure and coatings subjected to only constant immersion in the NaCl medium is presented. The results were used to demonstrate the effectiveness of the ac-dc-ac method at accelerating the degradation of an organic coating without observably changing the normal mechanism of degradation. The data highlights the different features of the coating systems and tracks them while the coating is being degraded. The aircraft coating was characterized by a high-resistant topcoat that can mask corrosion/primer degradation at the primer/substrate interface whereas the vehicle coating was characterized by a low-resistant topcoat with an effective corrosion inhibiting primer. Details of the ac-dc-ac degradation were evaluated by using an equivalent circuit to help interpret the electrochemical impedance data.

• Journal of Advanced Marine Engineering and Technology
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• 제23권6호
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• pp.761-769
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• 1999

In this paper the effect of aging heat treatment to the Corrosion behavior for the Nimonic 80A superalloy was studied by AC Impedance methods. Tested solution was 3.5% with tempera-ture $25^{\circ}C$ Electro-chemical corrosion test were carried out for the Nimonic 80A super-alloy which solution heat treated at $1080^{\circ}C$ for 8 hours followed by aging heat treated at $650^{\circ}C,\;700^{\circ}C,\;750^{\circ}C\;800^{\circ}C$ and $850^{\circ}C$ with 16hours under vacuum environment. The obtained results were as follows; 1. Base metal and solution-treated materials were exhibited similar corrosion tendency as Ran-dle equivalent cell. The value of passive film resistance was 579 ohms for the base metal and 124,770 ohms for the solutionized metal such a difference was arose by the ${{\gamma}_^'}$ precipitate on the metal surface during heat treatment. 2. The measure value of $R_p$ for heat-treated at $650^{\circ}C,\;700^{\circ}C,\;800^{\circ}C$and $850^{\circ}C$ were 97,943, 93, 111, 26,961, 15,798 and 11,780ohm respectively. Which indicated that the passive film resistance Rp was reduced as aging temperature increased due to the growth of grain size and sensitization at the grain boundary. 3. The similar tendency was exhibited for corrosion behavior of the electro-chemical corrosion polarization method and AC impedance method and confirmed that AC impedance method was useful tool for corrosion research.

• 동력기계공학회지
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• 제20권5호
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• pp.29-36
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• 2016

Aluminum alloys have been widely used in engine materials, cold & hot-water storage vessels and piping etc., Furthermore, the aluminum alloy of AC8A have been widely used in mold casting material of engine piston for various vehicles because of its properties of temperature, wear and corrosion resistance. Therefore, it is considered that evaluation of corrosion resistance as well as wear resistance of AC8A material is also important to improve its property and to prolong its lifetime. In previous paper, the effect of solution($510^{\circ}C$:4hrs) and tempering($190^{\circ}C$: 16, 24, and 36 hrs)heat treatments to corrosion resistance and hardness were investigated using electrochemical method. In this study, in order to examine completely the effect of the tempering hours to hardness variation and corrosion resistance, the results of solution($510^{\circ}C$:4hrs) and tempering($190^{\circ}C$: 2, 4, 8 and 12hrs)heat treatments to hardness and corrosion resistance were investigated using electrochemical method. The hardness decreased with solution heat treatment compared to mold casting condition, but its value increased with tempering heat treatment. Furthermore, the corrosion resistance increased with decreasing of the hardness, and decreased with increasing of the hardness reversely. And the tempering heat treatment temperature at $190^{\circ}C$ for 8 hrs exhibited the highest value of the hardness and also indicated the highest corrosion current density. However, the values of hardness and corrosion current density was again increasingly decreased with increasing of tempering hours than 8 hrs, Consequently, it is suggested that decision of the optimum. tempering hours is very important to improve the corrosion or wear resistance.

• Journal of Advanced Marine Engineering and Technology
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• 제29권5호
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• pp.495-501
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• 2005

Al is a active metal that owes its resistance to a thin, protective, barrier oxide surface layer, which is stable in air and neutral aqueous solution. Thus Al alloys are widely used in architectural trim. cold & hot-water storage vessels and piping. However Al and most of its alloy may corrode with some forms such as pitting corrosion, intergranular corrosion and galvanic corrosion in the case of exposure to various industrial and marine atmosphere. Therefore a correct evaluation of corrosion resistance for their Al and Al alloys may be more important in a economical point of view. In this study. a relative evaluation of corrosion resistance for three kinds of Al alloys such as ALDC2, ALDC3, and ALDC8 series was carried out with electrochemical method. There is a tendency that corrosion potential is shifted to positive or negative direction by alloying components regardless of corrosion resistance. Moreover the data of corrosion properties obtained from cathodic Polarization curve, cyclic voltammogram and AC. DC impedance respectively showed a good correspondence each other against the corrosion resistance but variation of corrosion potential. passivity current density of anodic polarization curve and corrosion current density by Tafel extrapolation and Stern-Geary method didn't correspond with not only each other but also considerably the data of corrosion properties discussed above. Therefore it is suggested that an optimum electrochemical evaluation for corrosion resistance of Al alloy is to calculate the diffusion limiting current density of cathodic polarization curve, impedance of AC or DC and polarization resistance of cyclic voltammogram.

• 한국해양공학회지
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• 제11권2호
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• pp.57-69
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• 1997

The objetive of this study is to compare the mechanical proprties of 6000 series Al-Mg-Si aluminum alloy (AC120) with 5000 series Al-Mg aluminum alloy (TG25), and to investigate the influence of corrosion solution for fatigue life. Comparing of TG25 and AC120 alloy sheets, TG25 alloy sheets showing higher plastic ratio and total elongation have better formability than AC120 alloy sheets. The hardness of nugget area was a little higher than that of base metal area. Also, grain coarsening was observed in HAZ(Heat Affected Zone). In a corrosion fatigue experiment, the fatigue life decreased as concentration increased, when a dipping time was constant. The life decreased as dippling time increased, when a concentration was constant.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제51권2호
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• pp.74-79
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• 2002

We have been analyzed the interference problems already in steady state, especially AC corrosion when the gas pipeline is burred with power cable in the same submarine tunnel. In the next stage, we analyze the induced voltage in a fault condition of 154[kV] underground T/L. This paper presents the results of them which are limitation of safety voltage. meodeling of power cables, gas pipeline and grounding systems, analysis of induced voltage in a fault condition, and protection of Power line system.

• 전기화학회지
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• 제10권3호
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• pp.179-183
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• 2007

The corrosion behavior of metal covered with mortar under a wet-dry cyclic condition were investigated to apply for the measurement of corrosion rates of reinforcing steel in concrete structure. The carbon steel in mortar having t=3 mm cover thickness was exposed to the alternate condition of 6 h immersion in chloride containing solution and 18 h drying at $25^{\circ}C$ and 50%RH. The electrochemical phenomena of a carbon steel and mortar interface was explained by an equivalent circuit consisting of a solution resistance, a charge transfer resistance and a CPE(Constant Phase Element). The corrosion rates were monitored continuously during exposure using an AC impedance technique. Simultaneously, the current distribution over the working electrode during impedance measurement was analyzed from the phase shift, $\theta$, in an intermediate frequency. The result showed that corrosion rate monitoring using an AC impedance method is suitable under the given exposure conditions even during the drying period when the metal is covered with the wetted mortar.

• 한국재료학회지
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• 제9권2호
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• pp.205-210
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• 1999

The 250ppm hydrogen-charged Zircaloy-4 sheets, homogenized at $400^{\circ}C$ for 72hrs in vacuum, were corroded under the autoclave conditions of $350^{\circ}C$, 2350psi. The corrosion behavior of the Zircaloy-4 sheets was evaluated by measuring their weight gains with the exposure time. The electrical characteristics were investigated in the ranges of 5000~1x10\ulcornerHz using AC impedance technique in 1N $H_2$$SO_4$aqueous solution. The corrosion rate of the hydrogen charged specimen was more rapid than the normal specimen at the early stage of the corrosion. With a longer corrosion time, however, the normal specimen corroded faster than the hydrogen-charged specimen. At the same time the hydrogen pickup in the hydrogen-charged specimen was more suppressed compared with the normal specimen. Such appears to be occurred because the impedance for the movement of the hydrogen ion into the metal was higher in the hydrogen-charged specimen compared to normal specimen at the interface between the oxide layer and the uncorroded metal. Thus the corrosion rate of the hydrogen-charged specimen was likely to be decreased with a longer corrosion time.

• Corrosion Science and Technology
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• 제6권5호
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• pp.227-232
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• 2007

The corrosion behavior of carbon steel (N80) in carbon dioxide saturated 1%NaCl solution with and without acetic acid or acetate was investigated by weight-loss test, electrochemical methods (polarization curve, Electrochemical impedance spectroscopy). The major objective is to make clear that the effect of acetic acid and acetate on the corrosion of carbon steel in $Co_2$ environments. The results indicate that either acetic acid or acetate accelerates cathodic reducing reaction, facilitates dissolution of corrosion products on carbon steel, and so promotes the corrosion rate of carbon steel in carbon dioxide saturated NaCl solution. All Nyquist Plots are consisting of a capacitive loop in high frequency region, an inductive loop in medial frequency region and a capacitive arc in low frequency region. The high frequency capacitive loop, medial frequency inductive loop and low frequency capacitive arc are corresponding to the electron transfer reaction, the formation/adsorption of intermediates and dissolution of corrosion products respectively. All arc of the measured impedance reduced with the increase of the concentration of Ac-, especially HAc. However, the same phenomenon is not notable after reducing pH value by adding HCl. HAc is a stronger proton donor and can be reduced directly by electrochemical reaction firstly. Ac- can't participate in electrochemistry reaction directly, but $Ac^-$ an hydrate easily to create HAc in carbon dioxide saturated environments. HAc is as catalyst in $Co_2$ corrosion. As a result, the corrosion rate was accelerated in the presence of acetate ion even pH value of solution increased.

• Journal of Advanced Marine Engineering and Technology
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• 제33권3호
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• pp.387-394
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• 2009

It has been observed that coated steel structures are rapidly deteriorated than designed lifetime due to acid rain caused by air pollution etc.. Therefore improvement of corrosion resistance of anti-corrosive paint is very important in terms of safety and economic point of view. In this study corrosion resistance for five kinds of anti-corrosive paints including acryl, fluorine and epoxy resin series were investigated with electrochemical methods such as corrosion potential, polarization curves, impedance and cyclic voltammogram measurements etc.. There were somewhat good relationships between values measured by electrochemical methods such as corrosion current density obtained by cathodic and anodic polarization curves, value of impedance estimated with AC impedance, and polarization resistance on the cyclic voltammogram, for example, corrosion current density was decreased with increasing of values of impedance and polarization resistance on the cyclic voltammogram. However their relationships between corrosion current density and corrosion potential were not well coincided each other. Consequently it is considered that although a corrosion potential of F101 of fuoric resin series shifted to negative direction than other anti-corrosive paints, its corrosion resistance, indicating on the cathodic and anodic polarization curves, AC impedance curves and cyclic voltammogram, was the most superior to other paints, whereas A100 containing arcylic resin showed a relatively poor corrosion resistance compared to other paints.