• Corrosion Science and Technology
• /
• 제22권2호
• /
• pp.90-98
• /
• 2023

In this study, cobalt oxide (Co₃O₄) and cobalt-doped magnetite (CoFe₂O₄) nanoparticles were synthesized by a hydrothermal method. They were then used as corrosion inhibitors for corrosion protection of AA2024-T3 aluminum alloys. These obtained nanoparticles were characterized by x-ray diffraction, field-emission scanning electron microscopy, and Zeta potential measurements. Corrosion inhibition activities of Co₃O₄ and CoFe₂O₄ nanoparticles were determined by performing electrochemical measurements for bare AA2024-T3 aluminum alloys in 0.05 M NaCl + 0.1 M Na₂SO₄ solution containing Co₃O₄ or CoFe₂O₄ nanoparticles. Corrosion protection for AA2024-T3 aluminum alloys by a water-based epoxy with or without the synthesized Co₃O₄ or CoFe₂O₄ nanoparticles was investigated by electrochemical impedance spectroscopy during immersion in 0.1 M NaCl solution. The corrosion protection of epoxy coating deposited on the AA2024-T3 surface was improved by incorporating Co₃O₄ or CoFe₂O₄ nanoparticles in the coating. The corrosion protection performance of the epoxy coating containing CoFe₂O₄ was higher than that of the epoxy coating containing Co₃O₄.

• 소성∙가공
• /
• 제16권7호
• /
• pp.521-529
• /
• 2007

This paper is concerned with the analysis on the surface expansion of AA 2024 and AA 1100 aluminum alloys in backward extrusion process. Due to heavy surface expansion appeared usually in the backward can extrusion process, the tribological conditions along the interface between the material and the punch land are very severe. In the present study, the surface expansion is analyzed especially under various process conditions. The main goal of this study is to investigate the influence of degree of reduction in height, geometries of punch nose, friction and hardening characteristics of different aluminum alloys on the material flow and thus on the surface expansion on the working material. Two different materials are selected for investigation as model materials and they are AA 2024 and AA 1100 aluminum alloys. The geometrical parameters employed in analysis include punch corner radius and punch nose angle. The geometry of punch follows basically the recommendation of ICFG and some variations of punch geometry are adopted to obtain quantitative information on the effect of geometrical parameters on material flow. Extensive simulation has been conducted by applying the rigid-plastic finite element method to the backward can extrusion process under different geometrical, material, and interface conditions. The simulation results are summarized in terms of surface expansion at different reduction in height, deformation patterns including pressure distributions along the interface between workpiece and punch, comparison of surface expansion between two model materials, geometrical and interfacial parametric effects on surface expansion, and load-stroke relationships.

• 소성∙가공
• /
• 제16권8호
• /
• pp.582-589
• /
• 2007

This paper is related to an analysis on the surface expansion in backward can extrusion process using spherical punches. It is generally known that the backward can extrusion process usually experiences severe normal pressure and heavy surface expansion. This is a reason why the backward can extrusion process is one of most difficult operations among many forging processes. Different punch nose radii have been applied to the simulation to investigate the effect of punch nose radius on the surface expansion, which is a major effort in this study. AA 2024 aluminum alloy is selected as a model material for investigation. Different frictional conditions have also been selected as a process parameter. The pressure applied on the punch has been also investigated since heavy surface expansion as well as high normal pressure on the tool usually leads to severe tribological conditions along the interface between material and tool. The simulation results are summarized in terms of surface expansion at different reduction in height, deformation patterns including strain distributions and maximum pressure exerted on the workpiece and punch, the effect of punch nose radius and the frictional condition on the surface expansion and the location and magnitude of maximum pressure exerted, respectively.

• 한국분말재료학회지
• /
• 제31권1호
• /
• pp.37-42
• /
• 2024

Friction stir spot welding (FSSW) is a solid-state joining process and a rapidly growing dissimilar material welding technology for joining metallic alloys in the automotive industry. Welding tool shape and process conditions must be appropriately controlled to obtain high bonding characteristics. In this study, FSSW is performed on dissimilar materials AA5052-H32 aluminum alloy sheet and SPRC440 steel sheet, and the influence of the shape of joining tool and tool insertion depth during joining is investigated. A new intermetallic compound is produced at the aluminum and steel sheets joint. When the insertion depth of the tool is insufficient, the intermetallic compound between the two sheets did not form uniformly. As the insertion depth increased, the intermetallic compound layer become uniform and continuous. The joint specimen shows higher values of tensile shear load as the diameter and insertion depth of the tool increase. This shows that the uniform formation of the intermetallic compound strengthens the bonding force between the joining specimens and increases the tensile shear load.

• Journal of Electrochemical Science and Technology
• /
• 제10권2호
• /
• pp.148-158
• /
• 2019

The corrosion protection of AA2024 PPy coated samples doping with nanosized metal oxides, including $TiO_2$ and $CeO_2$ nanoparticles and $Nd_2O_3$ nanorods, during exposure to the solutions of 0.1 M $H_2SO_4$ and 3.5% NaCl was evaluated by electrochemical impedance spectroscopy (EIS) and linear polarization resistance (LPR) techniques. The nanorods of $Nd_2O_3$ were synthesized by cathodic pulse electrochemical deposition technique. The barrier properties of the different PPy coatings containing nanosized metal oxides immersed in $H_2SO_4$ solution were ranked as follows: $Nd_2O_3$ > $TiO_2$ > $CeO_2$. Therefore, the $Nd_2O_3$ coating sample provided the highest corrosion protection at any time of immersion up to 72 hours after immersing in $H_2SO_4$ solution. On the other hand, the $CeO_2$ coating sample displayed the best anticorrosive properties among the other coating samples after immersion in NaCl solution up to 28 days. This is due to the inhibition effect of cerium ions on aluminum alloys at near-neutral solutions.

• Corrosion Science and Technology
• /
• 제6권4호
• /
• pp.206-210
• /
• 2007

Aerospace aluminum alloys such as Al alloy 2024-T3 and 7075-T6 are subject to localized corrosion due the existence of intermetallics containing Cu, Mg or Zn. Chromate is currently widely used in the aerospace industry as the corrosion inhibitor for these alloys. However, chromate needs to be replaced due to its strong carcinogenicity. In this study, an extensive pigment screening has been performed to find replacements for chromates. Different categories of inhibitors were evaluated by immersion tests, DC polarization tests and other methods. Phosphates, zinc salts, cerium salts, vanadates and benzotriazole were found to be effective inhibitors for AA7075. Among those inhibitors, zinc phosphate was found to be the most effective in our novel, silane-based, one-step aqueous primer system. The performance of this primer is comparable to that of currently used chromate primers in accelerated corrosion tests, while it is completely chromate-free and its VOC is about 80% less than that of current primers. Studies by SEM/EDS showed that the unique structure of the superprimer accounts for the strong anti-corrosion performance of the zinc phosphate pigment. The self-assembled stratified double-layer structure of the superprimer is characterized by a less-penetrable hydrophobic layer at the top and a hydrophilic layer accommodating the inhibitors underneath. The top layer functions as the physical barrier against water ingress, while the lower layer functions as a reservoirfor the inhibitor, which is leached out only if the coating is damaged by a scratch or scribe. The presence of a silane in the primer further improves the adhesion and anti-corrosion performance of the primer.

• 열처리공학회지
• /
• 제37권3호
• /
• pp.121-127
• /
• 2024

We investigate the effect of T6 heat treatment on the microstructure and mechanical properties of AA365 (Al-10.3Si-0.37Mg-0.6Mn-0.11Fe, wt.%) alloy fabricated by vacuum-assisted high pressure die casting by means of thermodynamic calculation, X-ray diffraction, scanning and transmission electron microscopy, and tensile tests. The as-cast alloy consists of primary Al (with dendrite arm spacing of 10~15 ㎛), needle-like eutectic Si, and blocky α-AlFeMnSi phases. The solution treatment at 490 ℃ induces the spheroidization of eutectic Si and increase in the fraction of eutectic Si and α-AlFeMnSi phases. While as-cast alloy does not contain nano-sized precipitates, the T6-treated alloy contains fine β' and β' precipitates less than 20 nm that formed during aging at 190℃. T6 heat treatment improves the yield strength from 165 to 186 MPa due to the strengthening effect of β' and β' precipitates. However, the β' and β' precipitates reduce the strain hardening rate and accelerate the necking phenomenon, degrading the tensile strength (from 290 to 244 MPa) and fracture elongation (from 6.6 to 5.0%). Fractography reveals that the coarse α-AlFeMnSi and eutectic Si phases act as crack sites in both the as-cast and T6 treated alloys.