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Reforming of Propane by Carbon Dioxide using Ni/γ-A12O3 Catalysts (Ni/γ-Al2O3 촉매상에서 이산화탄소에 의한 프로판의 개질)

  • Kim, K. H.;Kim, J. H.;Chang, S. C.;Park, D. W.
    • Applied Chemistry for Engineering
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    • v.8 no.3
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    • pp.382-388
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    • 1997
  • Reforming of propane by carbon dioxide using NiO/${\gamma}$-$A1_2O_3$ was carried out in a pulse or continuous kid bed reactor. NiO/${\gamma}$-$Al_2O_3$ showed higher dissociation ability of $CO_2$ than NiO/${\gamma}$-$Al_2O_3$, and the former exhibited higher conversion of propane than the latter. The presence of oxygen in the reaction mixture of propane and $CO_2$ increased the conversion of propane and reduced the amount of carbon deposit on the catalyst surface. Mechanical mixture catalyst of NiO/${\gamma}$-$Al_2O_3$ and $Ga_2O_3$ showed higher stability to deactivation than NiO/${\gamma}$-$Al_2O_3$ itself. The synergistic effect between NiO/${\gamma}$-$Al_2O_3$ and $Al_2O_3$ was also observed in this study.

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The Relationship between Perceived Justice and Customer Attitude in an Integrated On·Offline Commerce : Focusing on the Moderation Effect of Commerce Industry Type (통합된 온·오프라인 상거래에서 지각된 공정성과 고객태도 간 관계 : 상거래 산업유형의 조절효과를 중심으로)

  • Moon, Yunji
    • Journal of Information Technology Applications and Management
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    • v.26 no.2
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    • pp.41-60
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    • 2019
  • O2O(Online-to-Offline) commerce, a kind of multi-channel, is used in various industries such as accommodation, food and beverage, transportation, and real estate. The O2O commerce, a channel of integrating online and offline, overcomes the limitations of traditional online commerce, where a customer made a purchase decision without direct experience. Despite this advantage of O2O, if the online-offline channel is not effectively linked, customer's complaints would occur due to service failure. This study, with regard to O2O service failure circumstances, intends to investigate the effect of customer's perceived justice on their emotional response, recovery satisfaction, followed by intention to repurchase. Perceived justice in this study is composed of distributive justice, interactional justice, and procedural justice. Furthermore, this study explores the moderation effect of O2O industry types in the relationship between perceived justice and emotion. An O2O industry type is classified into accommodation, food and beverage, and transportation. A hypothesized research model was empirically tested using a structural equation model. The current study collected 433 questionnaires and the target respondents are customers who have experienced service failure in O2O commerce. The empirical results showed that O2O commerce more effectively conducts service recovery strategy and causes positive customer response by integrating online and offline channel. One of the ultimate purposes of O2O service providers is to reduce the likelihood of service failures and to recover more quickly and efficiently by linking two channels rather than using a single channel. This study suggested that the O2O channel is effective in influencing customer satisfaction and loyalty by inducing customer's positive emotions in recovering service failure.

A Study on the Consumer Disputes and Protection Measures of the Digital Healthcare Market and O2O Service (디지털헬스케어 시장과 O2O서비스 소비자분쟁 및 보호방안)

  • Byeon, Seung Hyeok
    • Journal of Arbitration Studies
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    • v.30 no.4
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    • pp.121-138
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    • 2020
  • The O2O services in the healthcare sector have only been in full swing for about three years, and unlike existing O2O consumer goods, the scale and scope of the dispute are more complicated due to restrictions on medical treatment. In this study, O2O service platform operators and medical institutions' roles and responsibilities were redefined as a countermeasure for resolving disputes in healthcare O2O services and the laws for changing the transaction environment. A change in institutional mechanisms was proposed. This study looked at the types of consumer disputes related to healthcare O2O services as insufficient information problems, problems in the course of medical service implementation, problems with immunity provisions for platform operators, cancellations, and non-compliance with refunds. All the information generated during transactions in the healthcare sector was extensive in scale and included the most sensitive information among personal information, stressing the importance of ensuring security. The area that started in the O2O range before the medical institution visit also proposed a plan to establish a system for the delivery of proven information as a pre-medical person. The scale and growth will grow faster, given that consumers can experience the information they want anytime, anywhere they want. However, the platform broker's role, a link player, will become more important because consumers who use the service will have their first meeting with non-face-to-face product providers. On the other hand, service providers may have side effects of misleading consumers by providing false information or misleading consumers through exaggerated advertisements. The O2O service market is expected to expand beyond distribution and dining out to the entire industry. However, since it is challenging to check accurate statistics on the detailed market, various disputes and consumer protection measures will be required for each detailed market, and comprehensive leading solutions will be essential in the future.

Electrical and Dielectric Characteristics of Zn-Pr-Co-Dy-M(M=Ni, Mg, Cr) Oxides-Based Varistors (Zn-Pr-Co-Dy-M(M=Ni, Mg, Cr) 산화물계 바리스터의 전기적, 유전적 특성)

  • 남춘우;박종아
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.9
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    • pp.924-929
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    • 2004
  • The microstructure, electrical and dielectric characteristics of $ZnO-{Pr}_6{O}_11-{CoO}-{Dy}_2{O}_3$-based varistors were investigated without and with various metal oxide additives(NiO, MgO, Cr$_2$O$_3$). The average grain size decreased in the range of 18.4 $\backsim$ 11.5 $\mu$m, in order of NiO\longrightarrowMgO\longrightarrow{Cr}_2{O}_3$ and the density decreased in the range of 5.62 \backsim 5.33 $g/{cm}^3$ in order of NiO\longrightarrowCr$_2$O$_3$\longrightarrowMgO. While, the nonlinear exponent increased In the range of 19.8$\backsim$67.4 in order of NiO\longrightarrowMgO\longrightarrow${Cr}_2{O}_3$ and the leakage current decreased in the range of 25.6 $\backsim$ 1.2 $\mu$A in order of NiO\longrightarrow${Cr}_2{O}_3$\longrightarrowMgO. Among all varistors, the Cr$_2$O$_3$-added varistor exhibited the highest nonlinearity, with a nonlinear exponent of 67.4 and a leakage current of 1.2 $\mu$A. Furthermore, this varistor exhibited the lowest dielectric dissipation factor of 0.0407.

Influence of Sintering Temperature on Electrical Properties of $ZnO-Pr_{6}O_{11}-CoO-Cr_{2}O_{3}-La_{2}O_{3}$ Based Varistors ($ZnO-Pr_{6}O_{11}-CoO-Cr_{2}O_{3}-La_{2}O_{3}$계 바리스터의 전기적 특성에 소결 온도의 영향)

  • 류정선;김향숙;남춘우
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.422-425
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    • 2001
  • The electrical properties of ZnO-Pr$_{6}$O$_{11}$-CoO-Cr$_2$O$_3$-La$_2$O$_3$ based varistors were investigated with sintering temperature in the range of 1240~130$0^{\circ}C$. The varistors sintered at 1240~126$0^{\circ}C$ exhibited high density, which was 5.50~5.70 g/㎤ corresponding to 95.2~98.6% of theoretical density The varistor voltage was decreased in range of 718.47~108.00 V/mm with increasing sintering temperature. The varistors sintered at 1240~126$0^{\circ}C$ exhibited good electrical properties, in which the nonlinear exponent is in the range of 79.25~49.22 and leakage current is in the range of 0.26~1.00 $\mu$A. In particular, the varistor sintered at 1240\`c showed very excellent electrical properties, in which the nonlinear exponent is 79.25 and leakage current is 0.26 $\mu$A.A.A.

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Characterization and Preparation of Glass-Ceramics in the System Fe_2O_3-CaO-SiO_2$ (I) (Fe_2O_3-CaO-SiO_2$계 결정화 유리의 제조 및 특성(I))

  • 이용근;최세영;김경남
    • Journal of the Korean Ceramic Society
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    • v.31 no.6
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    • pp.629-636
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    • 1994
  • The ferrimagnetic glass-ceramics in the system Fe2O3-CaO-SiO2 for hyperthermia were investigated. Glasses could be prepared up to the content of 40 wt% of Fe2O3 and below the weight ratio of 1.0 of CaO/SiO2. The maximum saturation magnetization and the maximum coercive force were 29.85 emu/g and 340.1 Oe respectively, for a glass 40Fe2O3.20CaO.40SiO2 composition heat-treated at 95$0^{\circ}C$ for 8 hours. And for a glass 40Fe2O3.30CaO.30SiO2 composition the maximum saturation magnetization and the maximum coercive force were 18.47 emu/g and 374.4 Oe heat-treated at 1,00$0^{\circ}C$ and 90$0^{\circ}C$ for 8 hours respectively. The maximum hysteresis loss was 1,726.3 cal/g for a glass 40Fe2O3.20CaO.40SiO2 composition heat-treated at 95$0^{\circ}C$ for 8 hours. It was found that the ferrimagnetic Fe2O3.CaO.SiO2 glass-ceramics was little injurious to human body as results of biocompatibility test and biotoxicity test.

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Microstructure and Electrical Properties of ZnO-$Pr_6$$O_{11}$-CoO-$Er_2$$O_3$ Based Varistors (ZnO-$Pr_6$$O_{11}$-CoO-$Er_2$$O_3$계 바리스터의 미세구조 및 전기적 성질)

  • 남춘우;박춘형
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.6
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    • pp.493-501
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    • 2000
  • The microstructure and electrical properties of ZnO-Pr$_{6}$/O$_{11}$-CoO-Er$_{2}$/O$_{3}$ based varistors were investigated with Er$_{2}$/O$_{3}$ additive content of the range 0.0 to 2.0 mol%. Most of the added Er$_{2}$/O$_{3}$ were segregated at the nodal points and grain boundaries and it coexisted with Pr$_{6}$/O$_{11}$ in the bulk intergranular layer. The average grain size was decreased in the range of 7.44 to 5.62${\mu}{\textrm}{m}$ at 130$0^{\circ}C$ and 18.36 to 9.11 at 135$0^{\circ}C$ with increasing Er$_{2}$/O sub 3/ additive content. The density of ceramics was in the range 4.87 to 5.08 g/cm$^3$ at 130$0^{\circ}C$ and 5.35 to 5.62 g/cm$^3$at 135$0^{\circ}C$. At 130$0^{\circ}C$ the varistors without Er$_{2}$/O$_{3}$ exhibited 29.66 in the nonlinear exponent and 28.23 $\mu$A in the leakage current whereas the varistors with 0.5 mol% Er$_{2}$/O$_{3}$ exhibited a high nonlinearity which is 52.78 in thenonlinear exhibited and 9.75 $\mu$A in the leakage current. At 135$0^{\circ}C$ the varistors without Er$_{2}$/O$_{3}$ exhibited a very poor nonlinearity indicating 2.08 in the nonlinear exponent and 133.79 $\mu$A in the leakage current whereas the varistors with 1.0mol% Er$_{2}$/O$_{3}$ exhibited a relatively high nonlinearity which is 36.79 in the nonlinear exponent and 5.92 $\mu$A in the leakage current. Therefore Er$_{2}$/O$_{3}$ was additive which greatly improve the nonlinearity. It is believed that ZnO-0.5 mol% Pr$_{6}$/O$_{11}$-1.0 mol% CoO-0.5 mol% Er$_{2}$/O$_{3}$ based ceramicss will be usefully used as a basic composition to develop the advanced pr$_{6}$/O$_{11}$-based ZnO varistors.ristors.ristors.

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Application of Hybrid SNCR/SCR process for Improved N Ox Removals Efficiency of SNCR (SNCR의 N Ox 제거효율 향상을 위한 Hybrid SNCR/SCR 공정 응용)

  • 최상기;최성우
    • Journal of Environmental Science International
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    • v.12 no.9
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    • pp.997-1004
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    • 2003
  • The objective of this research was to test whether, under controlled laboratory conditions, hybrid SNCR/SCR process improves N $O_{x}$ removal efficiency in comparison with the SNCR only. The hybrid process is a combination of a redesigned existing SNCR with a new downstream SCR. N $O_{x}$ reduction experiments using a hybrid SNCR/SCR process have been conducted in simple NO/N $H_3$/ $O_2$ gas mixtures. Total gas flow rate was kept constant 4 liter/min throughout the SNCR and SCR reactors, where initial N $O_{x}$ concentration was 500 ppm in the presence of 5% or 15% $O_2$. Commercial catalysts, $V_2$ $O_{5}$ -W $O_3$-S $O_4$/Ti $O_2$, were used for SCR N $O_{x}$ reduction. The residence time and space velocity were around 1.67 seconds and 2,400 $h^{-1}$ or 6000 $h^{-1}$ in SNCR and SCR reactors, respectively. N $O_{x}$ reduction of the hybrid system was always higher than could be achieved by SNCR alone at a given value of N $H_{3SLIP}$. Optimization of the hybrid system performance requires maximizing N $O_{x}$ removal in the SNCR process. An analysis based on the hybrid system performance in this lab-scale work indicates that a equipment with N $O_{xi}$ =500 ppm will achieve a total N $O_{x}$ removal of about 90 percent with N $H_{3SLIP}$ $\leq$ 5 ppm only if the SNCR N $O_{x}$ reduction is at least 60 percent. A hybrid SNCR/SCR process has shown about 26∼37% more N $O_{x}$ reduction than a SNCR unit process in which a lower temperature of 85$0^{\circ}C$ turned out to be more effective.be more effective.

The Electrical and CO Gas Sensing Characteristics of ZnO-ZrO$_2$Composite Ceramics (ZnO-ZrO$_2$복합체의 전기적 성질과 일산화탄소 가스 감응특성)

  • 김태원;정승우;최우성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.436-439
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    • 1997
  • We investigated a electrical and CO gas sensing properties of pure ZnO and ZnO-ZrO$_2$ composite ceramics. We made 0∼20mo1% ZrO$_2$added ZnO composite ceramics and observed a microstructure of the broken side of the samples. The properties of the samples were studied with temperature, composition, arid a concentration of carbon monoxid. The measured 1000ppm CO sensitivities of pure ZnO were about 1∼1.42, and that of ZnO-ZrO$_2$were about 1∼10.6. In order words, the 1000ppm CO sensitivities of ZnO-ZrO$_2$composite ceramics were about 1∼2 times larger than that of pure ZnO with temperature. The measured 250ppm, 500ppm CO sensitivities of ZnO-ZrO$_2$composite ceramics were about ∼3.28. ∼5.04, respectively.

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The Statistical on Numerical Analysis for The Petrology and Bulk Chemical Composition. In Cheju Volcanic Island (제주화산도의 암석성분에 관한 통계학적인 수치해석)

  • 택훈
    • Journal of the Speleological Society of Korea
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    • v.14 no.15
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    • pp.42-90
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    • 1987
  • Lee, Moon Won reported by 63 kinds lescribing the petrography and bulk chemical Composition in Petrology of Cheju volcanic island. The total Chemical Composition data was analyzed by the program of FORTRAN77. First, the Conversition equations and the scatter diagram were examined to the analysis, by the least square method. Next, a statistical data requested a mean Value, maximum value, minimum value, the range, the standard deviation, the variance, the Standord Error and the Coefficient of variation. In the standard deviation, a small Composition is MnO and P$_2$O$\sub$5/, a large Composition is SiO$_2$, Mgo and FeO. The Standard error and the variance were the tandency looked like the Standard deviation well. However, the Coefficient Variation differs from the Standard deviation. Where, a large Coefficient of variation are H$_2$O$\^$-/ and H$_2$O$\^$+/, a small Coefficient of variation are Al$_2$O$_3$ and SiO$_2$. The Correlation of Coefficient Can be Calculated numerically from the relation between SiO$_2$, Al$_2$O$_3$ and TiO$_2$ to other Compositions.

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