• 제목/요약/키워드: 7-MEGA

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Nanosulfated Silica as a Potential Heterogeneous Catalyst for the Synthesis of Nitrobenzene

  • Khairul Amri;Aan Sabilladin;Remi Ayu Pratika;Ari Sudarmanto;Hilda Ismail;Budhijanto;Mega Fia Lestari;Won-Chun Oh;Karna Wijaya
    • 한국재료학회지
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    • 제33권7호
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    • pp.265-272
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    • 2023
  • In this study, the synthesis of nitrobenzene was carried out using sulfated silica catalyst. The study delved into H2SO4/SiO2 as a solid acid catalyst and the effect of its weight variation, as well as the use of a microwave batch reactor in the synthesis of nitrobenzene. SiO2 was prepared using the sol-gel method from TEOS precursor. The formed gel was then refluxed with methanol and calcined at a temperature of 600 ℃. SiO2 with a 200-mesh size was impregnated with 98 % H2SO4 by mixing for 1 h. The resulting 33 % (w/w) H2SO4/SiO2 catalyst was separated by centrifugation, dried, and calcined at 600 ℃. The catalyst was then used as a solid acid catalyst in the synthesis of nitrobenzene. The weights of catalyst used were 0.5; 1; and 1.5 grams. The synthesis of nitrobenzene was carried out with a 1:3 ratio of benzene to nitric acid in a microwave batch reactor at 60 ℃ for 5 h. The resulting nitrobenzene liquid was analyzed using GC-MS to determine the selectivity of the catalyst. Likewise, the use of a microwave batch reactor was found to be appropriate and successful for the synthesis of nitrobenzene. The thermal energy produced by the microwave batch reactor was efficient enough to be used for the nitration reaction. Reactivity and selectivity tests demonstrated that 1 g of H2SO4/SiO2 could generate an average benzene conversion of 40.33 %.

충남지역 집단 번식농장 사육견의 심장사상충 감염률 조사 (Prevalence of canine heartworm infection among dogs on breeding farms in Chungnam province)

  • 이종훈;심상원;김희;김영진;안신욱;한귀섭
    • 한국동물위생학회지
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    • 제26권1호
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    • pp.19-26
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    • 2003
  • This study was attempted to survey on the prevalence of canine heartworm(Dirofilaria immitis) infection among 100 dogs(male 39, female 61) on the nine breeding farms in eastern Chungnam province in December 2002. Blood samples taken from dogs were examined for the presence of D immitis microfilaria by the modified Knott's test and an antigen test was using FASTest$\^$/ HW Antigne kit (Mega Cor A-6912 Horbranz-Austraia). 1. Eleven(11.0%) of the 100 examined dogs were microfilaria positive, while nineteen dogs(19.0%) were antigen positive, which suggested that the antigen test was more sensitive than the microfilarial test in detecting heartworm infection. 2. Infected dogs were observed higher more at 2 years older ages(4/48, 8.3%) and male(9/39, 23.1%) than young ages(4/48, 8.3%) and female(10/61, 16.4%). 3. The regional infection rates were of Gongju(15/43, 34.9%), Geumsan(4.27, 14.8%), while none of infection dogs in Yeongi(0/30, 0%). 4. Survey for hematological values of D immitis infected dogs : WBC and eosinophils were 21.4${\pm}$7.2 k/${\mu}\ell$, 3.5${\pm}$0.4 k/${\mu}\ell$, respectively. In conculsion, this study could be overemphasized the importance of control program the heartworm in eastern Chungnam province

인간-침팬지간 대량의 지놈서열 비교분석 (Comparative Analysis of Large Genome in Human-Chimpanzee)

  • Kim, Tae-Hyung;Kim, Dae-Soo;Jeon, Yeo-Jin;Cho, Hwan-Gue;Kim, Heui-Soo
    • 한국생물정보학회:학술대회논문집
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    • 한국생물정보시스템생물학회 2003년도 제2차 연례학술대회 발표논문집
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    • pp.183-192
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    • 2003
  • With the availability of complete whole-genomes such as the human, mouse, fugu and chimpanzee chromosome 22, comparative analysis of large genomes from cross-species at varying evolutionary distances is considered one of a powerful approach for identifying coding and functional non-coding sequences. Here we describe a fast and efficient global alignment method especially for large genomic regions over mega bases pair. We used an approach for identifying all similarity regions by HSP (Highest Segment Pair) regions using local alignments and then large syntenic genome based on the both extension of anchors at HSP regions in two species and global conservation map. Using this alignment approach, we examined rearrangement loci in human chromosome 21 and chimpanzee chromosome 22. Finally, we extracted syntenic genome 30 Mb of human chromosome 21 with chimpanzee chromosome 22, and then identified genomic rearrangements (deletions and insertions ranging h size from 0.3 to 200 kb). Our experiment shows that all jnsertion/deletion (indel) events in excess of 300 bp within chimpanzee chromosome 22 and human chromosome 21 alignments in order to identify new insertions that had occurred over the last 7 million years of evolution. Finally we also discussed evolutionary features throughout comparative analyses of Ka/ks (non-synonymous / synonymous substitutions) rate in orthologous 119 genes of chromosome 21 and 53 genes of MHC-I class in human and chimpanzee genome.

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당뇨병 환자의 인플루엔자 예방접종률과 관련 요인 (The Estimated Proportion for Influenza Vaccination and Related Factors in Korean Diabetics)

  • 변경향;김재용;최보영;최보율
    • 보건행정학회지
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    • 제28권2호
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    • pp.107-118
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    • 2018
  • Background: The purpose of this study was to investigate the estimated proportion for influenza vaccination and to identify factors associated with influenza vaccination in Korean diabetic patients. Methods: Data from the fourth, fifth, and sixth (except for 2013) Korea National Health and Nutrition Examination Survey (n=3,726) was used. A chi-square test was performed to investigate the estimated proportion for influenza vaccination, and a multiple logistic regression analysis was used to identify the factors associated with self-reported influenza vaccination. Results: In men, 28.8% of diabetes patients 30-64 years of age, and 76.1% of elderly (over 65 years of age) diabetes patients received influenza vaccination. In women, 37.7% of diabetes patients 30-64 years of age, and 78.4% of elderly diabetes patients received influenza vaccination (p<0.0001). The determinants of influenza vaccination were marriage, hypertension (odds ratio [OR], 1.55; 95% confidence interval [CI], 1.07-2.24), residence within a mega city, unemployment (OR, 3.94; 95% CI, 1.24-12.54), and exercise via (weekly) walking for diabetic men; and hypertension (OR, 1.71; 95% CI, 1.16-2.52), chronic disease (OR, 1.81; 95% CI, 1.08-3.02), and exercise via walking (OR, 2.65; 95% CI, 1.49-4.73) for diabetic women. Conclusion: Influenza vaccination remains relatively low in young diabetic patients. It is necessary to recommend vaccination to young diabetic patients, and to devise other strategies to improve vaccination.

Clinical features of macrocephaly at birth in Korea

  • Jeong, Goun;Kim, Minkyun;Han, Byoung Hee
    • Clinical and Experimental Pediatrics
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    • 제57권2호
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    • pp.75-78
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    • 2014
  • Purpose: This study aimed to investigate the clinical features of macrocephaly at birth in Korea using ultrasonography. Methods: We retrospectively investigated the medical records of full-term birth neonates in Cheil General Hospital & Women's Healthcare Center from January 2000 to June 2012. The following parameters were recorded and analyzed: gestational age, sex, birth weight, height, occipitofrontal circumference (OFC), physical examination, perinatal problems, and ultrasonography results. Macrocephaly was diagnosed when the OFC was greater than two standard deviations, based on the 2007 Korean National Growth Charts. Results: There were 75 neonates with macrocephaly at birth (52 boys and 23 girls), with a mean OFC of $38.1{\pm}0.49cm$. A comparison of the birth weight and height with the OFC value showed that height was correlated with OFC (r=0.35) but birth weight was not correlated with OFC (r=0.06). There were no remarkable findings in 56 cases (75%). Germinal matrix hemorrhage was identified in 10 cases (13%). An enlarged cerebrospinal fluid space was found in 5 cases (6.7%). There were 3 cases of mega-cisterna magna (4%), 1 case of ventriculomegaly, and 1 case of an enlarged interhemispheric space (6 mm) among these patients. In addition, a choroid plexus cyst was seen in 1 case. Mineralizing vasculopathy in both basal ganglia with no evidence of congenital infection was found in 2 cases and an asymptomatic subarachnoid hemorrhage was found in 1 case. Conclusion: Our results indicate that macrocephaly at birth has benign ultrasonography findings and shows a pattern of male dominance.

Elasto-plastic time history analysis of a 117-story high structure

  • Wu, Xiaohan;Li, Yimiao;Zhang, Yunlei
    • Computers and Concrete
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    • 제19권1호
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    • pp.7-17
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    • 2017
  • In Chinese Design Codes, for super high-rise buildings with complex structural distribution, which are regarded as code-exceeding buildings, elasto-plastic time history analysis is needed to validate the requirement of "no collapse under rare earthquake". In this paper, a 117-story super high-rise building is discussed. It has a height of 597 m and a height-width ratio of 9.5, which have both exceeded the limitations stipulated by the Chinese Design Codes. Mega columns adopted in this structure have cross section area of about $45m^2$ at the bottom, which is infrequent in practical projects. NosaCAD and Perform-3D, both widely used in nonlinear analyses, were chosen in this study, with which two model were established and analyzed, respectively. Elasto-plastic time history analysis was conducted to look into its seismic behavior, emphasizing on the stress state and deformation abilities under intensive seismic excitation.From the comparisons on the results under rare earthquake obtained from NosaCAD and Perform-3D, the overall responses such as roof displacement, inter story drift, base shear and damage pattern of the whole structure from each software show agreement to an extent. Besides, the deformation of the structure is below the limitation of the Chinese Codes, the time sequence and distribution of damages on core tubes are reasonable, and can dissipate certain inputted energy, which indicates that the structure can meet the requirement of "no collapse under rare earthquake".

글로벌 스포츠 산업 트렌드 예측 (Market Trends Prediction of the Sports Industry)

  • 김헌일
    • 한국산학기술학회논문지
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    • 제15권11호
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    • pp.6536-6546
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    • 2014
  • 본 연구는 스포츠 산업 경쟁력 강화와 생존 전략 마련을 위하여 글로벌 스포츠 시장 트렌드의 미래 변화를 예측하기 위한 것이다. 연구를 위하여 3차에 걸친 델파이 조사에 12개국 21명의 전문가가 참여하여 51개의 미래 예측 의견을 제시하였고, 의견에 대한 참여자들의 수렴을 거쳐 다음과 같은 결론을 얻었다. 첫째, 도핑, 사행 산업 등 윤리적 이슈가 글로벌 시장에 중요한 영향을 미칠 것이다. 둘째, 유소년 스포츠 시장은 지속적으로 성장할 것이다. 셋째, 스포츠는 건강 산업으로서의 중요성이 부각 될 것인데, 특히 저비용 건강 서비스 시장과, 고령인구 대상의 건강 기능 시장이 성장 할 것이다. 넷째, 스포츠 산업의 첨단 기술 /문화 등과의 융 복합은 더욱 가속화 할 것이다. 다섯째, 메가스포츠 이벤트는 다양한 비판적 논란으로 인하여 미래가 불투명해질 것이다. 여섯째, 소셜 미디어 등 신 미디어와 구 미디어의 스포츠에 대한 영향력은 더욱 증대될 것이다. 마지막으로 문화현상으로서의 스포츠시장 글로벌화는 더욱 가속화 될 것이다.

시뮬레이션과 1일 급수량 분석을 이용한 갈수기 감압에 의한 제한급수 방법 (Pressure restricted water supply method during drought using a computer simulation and daily water supply analysis)

  • 남영욱;김경수;현인환;김두일
    • 상하수도학회지
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    • 제34권5호
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    • pp.335-344
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    • 2020
  • Due to global climate change, mega-droughts have occurred frequently. Since long-term droughts make it difficult to secure the water resources, water supply needs to be restricted in a reasonable manner. In the event of limited water supply, the waterworks need to develop a restricted water supply strategy. This study showed that analyzing daily water supply could be used to respond to the first stage of a drought. According to an analysis of Korea's major water authorities, there was about 7~21% of room for daily minimum water supply in case of a drought. Restricting the water supply by lowering pressure is a good strategy for local water authorities with high water leakage rate since leakage is inversely dependent with pressure. For this method, it is necessary to quantify water deficiency and pressure at each node using a simulation. Since DDA-based software is not possible to predict changes in demand at nodes with pressure reduction, WaterGEMS, a PDA software, was used to quantitatively predict water shortages and pressures at each node. Locations where water is deficient need to install booster pumps or to be dispatched with water tank truck and bottled water. Without these support, lowering pressure could not be an option for water works. This paper suggests a method for waterworks to plan a drought by lowering pressure to restrict water supply using daily water supply analysis and PDA based simulation.

고령화연구패널조사의 국제비교연구 활용 가능성 (Korean Longitudinal Study of Ageing: Research Design for International Comparative Studies)

  • 부가청;장지연
    • 한국조사연구학회지:조사연구
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    • 제7권2호
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    • pp.97-122
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    • 2006
  • 2006년에 제1차 본조사에 들어간 '고령화연구패널조사(KLoSA)'는 HRS(미국), SHARE(유럽), ELSA(영국) 등과 연구네트워크를 구축하여 데이터베이스 사업과 공동연구를 추진하고 있다. '고령화연구패널조사'는 국가간 비교연구가 가능한 자료를 생산하기 위해서 다음 세 가지 조건을 고려하여 설계되었다. 첫째, 가족, 건강, 고용, 소득, 자산, 주관적 기대감 등 비교대상으로 삼은 조사들의 핵심적인 주제와 주요 조사영역을 일치시켰다. 둘째, 주요영역의 세부 항목은 우리나라의 제도적, 문화적 차이를 반영하도록 설계하였다. 우리나라의 공적연금과 의료보장제도의 특성 등 제도적 특성을 반영하여 설문을 구성하였으며, 고용상의 관행이나 금융상품의 범위도 고려하였다. 또한 문화적 차이에서 발생하는 가족간의 경제적 지원양태의 특징이나 재산관리상의 특성을 반영하도록 설문을 구성하였다. 마지막으로 척도의 선정에 있어서도 우리나라 고령자들에게 정확하게 의미가 전달할 수 있으면서도 국가간 비교연구도 가능한 방식의 척도를 개발하기 위하여 노력하였다.

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세계물류환경변화에 따른 대상항만의 경쟁력평가분석 (The Evaluation Analysis of Competitiveness among Target Ports with Environmental Changes of Global Logistics)

  • 김진구
    • 한국항만경제학회지
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    • 제19권2호
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    • pp.1-32
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    • 2003
  • The purpose of this study is to identify and evaluate the competitiveness of ports in ASEAN(Association of Southeast Asian Nations), which plays a leading role in basing the hub of global logistics strategies as a countermeasure in changes of logistics environments. This region represents most severe competition among Mega Hub ports in the world in terms of container cargo throughput at the onset of the 21st century. The research method in this study accounted for overlapping between attributes, and introduced the HFP method that can perform mathematical operations. The scope of this study was strictly confined to the ports of ASEAN, which cover the top 100 of 350 container ports that were presented in Containerization International Yearbook 2002 with reference to container throughput. The results of this study show Singapore in the number one position. Even when we compare with major ports in Korea (after getting comparative ratings and applying the same data and evaluation structure), the number one position still goes to Singapore and then Busan(2) and Manila(2), followed by Port Klang(4), Tanjung Priok(5), Tanjung Perak(6), Bangkok(7), Inchon(8), Laem Chabang(9) and Penang(9). In terms of the main contributions of this study, it is the first empirical study to apply the combined attributes of detailed and representative attributes into the advanced HFP model which was enhanced by the KJ method to evaluate the port competitiveness in ASEAN. Up-to-now, none has comprehensively conducted researches with sophisticated port methodology that has discussed a variety of changes in port development and terminal transfers of major shipping lines in the region. Moreover, through the comparative evaluation among major ports in Korea and ASEAN, the presentation of comparative competitiveness for Korean ports is a great achievement in this study. In order to reinforce this study, it needs further compensative research, including cost factors which could not be applied to modeling the subject ports by lack of consistently quantified data in ASEAN.

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