• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제49권1호
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• pp.8-12
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• 2000

The properties variation by deterioration of the 600V grade heat-resistant polyvinyl chloride insulated wire(HIV) was analyzed. The weight variation of the thermal deteriorated HIV was about 42% at 80$0^{\circ}C$ and over. From the analysis result of the metallurgical microscope photographs it shows that the sorface of normal wire showed the elongated structures. However the elongated structures did not appear at $900^{\circ} and over and we could observe that particles were grown. The grown oxidized substances in the thermally deteriorated electric wire were observed by SEM. The CuL, CuK, $CuK_b$, OK and CIK spectra of the thermally deteriorated HIV at $300^{\circ}C$ were uniform regardless of the scanning length, but the spectra of CIK could not found at above $700^{\circ}. At the DTA analysis, the endothermic reactions were occurred around $3006{\circ}C\; and\; 400^{\circ}C$ and the exothermic reactions were occurred around $470^{\circ}, respectively.

• 한국화재소방학회논문지
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• 제15권1호
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• pp.108-115
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• 2001

본 연구에서는 600V 비닐절연전선에 열적 스트레스를 인가하였을 때 전선의 특성 변화를 분석하였다. 전선의 구조 분석에서 정상 전선은 표면에 방향성을 갖고 있으나, $400^{\circ}c$ 이상에서 열화된 전선의 경우 탄화물, 크랙, 결정 등이 형성되었다. 정상 전선의 표면 조성은 Cu ; 100%였으나, $800^{\circ}c$에서 열화된 전선의 단면 조성은 Cu : 78.89%, O : 21.11%를 나타냈다. 연동선의 시차주사열량 분석 결과 $700^{\circ}c$ 이상에서 열화된 전선에서 새로운 반응 피크가 관측되었다. 절연물의 시차열 분석에서 $150^{\circ}c$로 열화된 전선의 경우 정상 전선의 반응점보다 낮은 $264^{\circ}c$에서 흡열 반응이 나타났다. 등선의 열화에 따른 산소 점유율은 $500^{\circ}c$에서 약 20%이다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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• pp.53-56
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• 1999

The weight decreases of the thermal deteriorated IV were rapidly increased at 80$0^{\circ}C$ and over. At the results of the analysis of the metallurgical microscope photographs. the surface of the thermal deteriorated IV at 30$0^{\circ}C$ was mixed with the elongated and original structures of Cu. But the elongated structures could not detected at 90$0^{\circ}C$ and over. The surface structures of SEM were detected a lot of small rounded particles between crystallizations. The EDX spectra of the thermal deteriorated IV at 3$0^{\circ}C$ were uniformly detected CuL, CuK, OK, and CIK, regardless of the scanning length, but the spectra of CIK could not found at 90$0^{\circ}C$. At the DTA curves, the endothermic reactions were occurred at about 25$0^{\circ}C$ to 30$0^{\circ}C$ and 43$0^{\circ}C$, and the exothermic reactions were occurred at about 48$0^{\circ}C$ respectively.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2002년도 하계학술대회 논문집 C
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• pp.1416-1418
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• 2002

In order to examine the thermal properties of the wire materials, we analyzed the shrinkage, the expansion and the form transformation, the surface structure according to the thermal deterioration temperature through the testing method for a heating shrinkage of Korean Industrial Standard(KS C 3004). For IV(600V grade polyvinyl chloride insulated wires), we measured the shrinkage and the expansion rate, analyzed the surface structure using SEM(Scanning Electron Microscope). In the result of this experiment, the shrinkage rate of IV 2.0mm covering was high in comparison with other wires. As the deterioration temperature rises gradually, the covering is molten and harden.