• Title/Summary/Keyword: 5'-Modification

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Surface Modification of Iron Oxide Particle by Silica-contained Materials (실리카계 물질에 의한 산화철 입자의 표면개질)

  • Ryu, Beyong-Hwan;Lee, Jung-Min;Koh, Jae-Cheon
    • Applied Chemistry for Engineering
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    • v.8 no.5
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    • pp.830-836
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    • 1997
  • The surface modification of iron oxide particle produced from steel-pickled acid by sodium-contained materials was studied. The molar ratio of $SiO_2$ to $Na_2O$ of sodium silicate was 1, 2, 3.5, respectively. The dispersion stability of iron oxide suspension as functions of amount of silica and pH was evaluated by surface charge and sedimentation velocity of iron oxide particle. Then the amount of sodium silicate was determined to provide a dispersion stability of iron oxide particle above pH 7. Finally, the surface modification of iron oxide particle with sodium silicate as silica-contained materials was done by wet ball milling. In the results of study, the dispersion stability of silica modified iron oxide particle was largely depended on amount of silica and pH together. The untreated iron oxide was unstable at pH 8, i.e. isoelectric point, but, the surface modified iron oxide particle with 0.8wt% silica was stable above pH 5. The dispersion stability was enhanced with 0.2wt% of anionic polyelectrolyte.

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Effect of a 12-week weight management program on the clinical characteristics and dietary intake of the young obese and the contributing factors to the successful weight loss

  • Lee, AeJin;Jeon, Kyeong Jin;Kim, Hye-Kyeong;Han, Sung Nim
    • Nutrition Research and Practice
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    • v.8 no.5
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    • pp.571-579
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    • 2014
  • BACKGROUND/OBJECTIVES: The objectives were to investigate the effect of a 12-wk intervention with behavioral modification on clinical characteristics and dietary intakes of young and otherwise healthy obese and to identify factors for successful weight loss. The goal was to lose 0.5 kg per week by reducing 300-500 kcal/day and by increasing physical activities. SUBJECTS AND METHODS: Forty four obese subjects (BMI > 25) and 19 normal weight subjects (BMI 18.5-23) finished the 12-week intervention. Obese subjects participated in 5 group educations and 6 individual counseling sessions. Normal weight subjects attended 6 individual counseling sessions for evaluations of dietary intake and exercise pattern. Anthropometric and clinical characteristics and 3-day dietary records were evaluated at baseline and week12. RESULTS: Weight and serum triglyceride and free fatty acid concentrations in obese group decreased significantly with intervention. Intakes of energy, fat, and cholesterol decreased significantly in the obese. Active participation, realistic weight loss goal setting, and weight gain after high school graduation not during childhood were identified as key factors for successful weight loss. CONCLUSIONS: The 12-week intervention with behavioral modification resulted in reduced energy and fat intakes and led to significant weight loss and improvements of clinical characteristics in the obese. The finding that those who became obese during childhood lost less weight indicates the importance of 'early' intervention.

Modification of Starch using Dextransucrase and Characterization of the Modified Starch. (덱스트란수크라제를 이용한 전분의 변형 및 특성 조사)

  • ;;;;;John E. Robyt
    • Microbiology and Biotechnology Letters
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    • v.26 no.2
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    • pp.143-150
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    • 1998
  • Many enzymes catalyze a primary reaction and/or secondary reaction. Dextransucrase usually synthesize dextran from sucrose as a primary reaction. The secondary reaction of dextransucrase is the transfer of glucose from sucrose to carbohydrate accepters. We have reacted dextransucrase from Leuconostoc mesenteroides B-742CB with sucrose and starches; granule or gelatinized starches, and Small or Potato starches. The yield of modified starch was ranged from 46% to 72%(s.d.<${pm}$5%) of theoretical depends on various reaction conditions. Modified products were more resistant against the hydrolysis of ${alpha}$-amylase, isoamylase, pullulanase and endo-dextranase than those of native starch. Based on the reactions from enzyme hydrolysis and methylation followed by acid hydrolysis modification of granule starch was more efficient than the modification of gelatinized starch. After modification of granule starch with dextransucrase, there produced a soluble modified starch. After modification the starch granules were fractionated to small size. The positions of glucose substitution of the modified products were determined by methylation followed by acid hydrolysis and analyzed by TLC. The products were modified by the addition of glucose to the position of C3, C4 and C6 free hydroxyl group of glucose residues in the starch.

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A Study on the Modification Value for Estimation of Traveling Speed During Rainfall in Interrupted Traffic Flow (단속교통류에서 강우시 평균통행속도 산정을 위한 보정계수에 관한 연구)

  • Mo, Moo Ki;Lee, Seung Joo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.37 no.5
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    • pp.837-844
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    • 2017
  • Generally, V/C ratio in uninterrupted traffic flow and average travel speed in interrupted traffic flow are utilized as measure of effect for assessing operational situation of roads. The set of road conditions and traffic conditions are considered to be major variables for assessing operational situation in the traffic flow. However, weather conditions such as rainfall also affect the operational situation of roads. The studies reflected by the rainy situation are conducted in the uninterrupted flow, but the related studies are insufficient in the interrupted flow. In this study, the modification factors during rainfall in the interrupted flow were suggested, and the factors could be used when calculating the average travel speed during rainfall in the interrupted flow. By utilizing the data that were investigated in the same road and traffic conditions and the different weather conditions (rainy day or clear day), the modification factors were founded on regression analysis of the travel speed during rainfall as a dependent variable. Modification factors was suggested in dividing peak time, non-peak time, and whole period. Based on this study, the modification factors can be used to complementing the average travel speed model for assessing the operational situation of urban streets during rainfall.

Development and Case Study of Unmanned Aerial Vehicles (UAVs) for Weather Modification Experiments (기상조절 실험용 드론의 설계·제작과 활용에 관한 연구)

  • Hae-Jung Koo;Miloslav Belorid;Hyun Jun Hwang;Min-Hoo Kim;Bu-Yo Kim;Joo Wan Cha;Yong Hee Lee;Jeongeun Baek;Jae-Won Jung;Seong-Kyu Seo
    • Atmosphere
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    • v.34 no.1
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    • pp.35-53
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    • 2024
  • Under the leadership of the National Institute of Meteorological Sciences (NIMS), the first domestic autonomous flight-type weather modification experimental drone for fog and lower-level cloud seeding was developed in 2021. This drone is designed based on a multi-copter configuration with a maximum takeoff weight of approximately 25 kg, enabling the installation of up to four burning flares for seeding materials and facilitating weather observations (temperature, pressure, humidity, and wind) as well as aerosol (PM10, PM2.5, and PM1.0) particle measurements. This research aims to introduce the construction of the drone and its recent applications over the past two years, providing insights into the experimental procedures, effectiveness verification, and improvement directions of the weather modification drone-based rain enhancement. In particular, partial confirmation of the experimental effects was obtained through the fog dissipation experiment on December 10, 2021, and the lower-level cloud seeding case study on October 5, 2022. To enhance the scope and rainfall amount of weather modification experiments using drones, various technological approaches, including adjustments to experimental altitude, seeding lines, seeding amount, and verification methods are necessary. Through this research, we aim to propose the development direction for weather modification drone technology, which will serve as foundational technology for practical application of domestic rain enhancement technology.

A Study on the Removal of Refractory Organic Matter in Leachate sampled at Kimpo Landfill by means of Fenton Oxidation Process (Fenton 산화를 이용한 김포매립지 침출수내 난분해성)

  • 정동환;조일형;김익수;한인규;정문호
    • Journal of Environmental Health Sciences
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    • v.26 no.4
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    • pp.49-57
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    • 2000
  • This study was carried out to find the optimal condition to treat refractory organic matter which can’t treat clearly with biological treatment and to find the optimal division dosage and division dose timing in the modification of Fenton oxidation which is used resolve the problem that hydrogen peroxide is too expensive. The results are following; 1. The highest TOC removal efficiency was 41% and color removal efficiency was 64% when the dilution magnitude of leachate is fold. This suggests that dilution is efficiency when high concentration of leachate is treated. 2. The removal efficiency of TOC and color increased up to the molar ratio between ferrate and hydrogen peroxide was 1:1. However above that ratio, removal efficiency hardly increased. The highest removal efficiency of TOC and color were 38% and 71% when the mole ratio of ferrate to hydrogen peroxide was 1.5:1. 3. When the mole ratio between ferrate and hydrogen peroxide was fixed, the removal efficiency of TOC and color increased as the dosage of hydrogen peroxide increased. 4. pH of samples were adjusted at pH 3, 5, 7, 9, 11. After oxidation reaction, pH of samples were dropped to 2.59, 2.54, 5.34, 6.36 and 9.68. The highest color removal efficiency was 75.7% when initial pH was at pH 7. 5. The removal of TOC and color was ended within 10. min. and the removal efficiency increased logarithmically within 10min. However after 10 min., the removal efficiency of hardly increased. 6. The color removal efficiency was higher with modification of fentone oxidation than that with fentone oxidation by 5%. Optimal division dosage ratio was 1:1 and optimal dose timing ratio was 2:1. However the TOC removal efficiency was not higher with modification of Fenton oxidation than that with Fenton oxidation.7. The CO $D_{Mn}$ /BO $D_{5}$ Ratio decreased with the time went by. It meant bioresolution increased as time went by. However, after 15 min., the CO $D_{Mn}$ /BO $D_{5}$ Ratio did not decrease any more. 8. In the case of $H_2O$$_2$ Divisiom Dose experiment, the increase of bioresolution was highest at the $H_2O$$_2$ Division dosage Ratio of 3:7.3:7.

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Hydrophilic surface formation of polumer treated by ion assisted reaction and its applications (이온빔보조 반응법을 이용한 고분자 표면의 친수성처리와 그 응용)

  • Cho, J.;Choi, S. C.;Yun, K.H.;Koh, S. K.
    • Journal of the Korean Vacuum Society
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    • v.8 no.3B
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    • pp.262-268
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    • 1999
  • Polycarbonate (PC) and Polymethylmethacrylate (PMMA) surface was modified by ion assisted reaction (IAR) technique to obtain the hydrophilic functional groups and improve the wettability. In conditions of ion assisted reaction, ion beam energy was changed from 500 to 1500eV, and ion dose and oxygen gas blown rate were fixed $1\times10^{16}$ ions/$\textrm{cm}^2$ and 4ml/min, respectively. Wetting angle of water on PC and PMMA surface modified by $Ar^+$ ion without blowing oxygen at 4ml/mon showed $5^{\circ}$ and $10^{\circ}$. Changes of wetting angle with oxygen gas and $Ar^+$ ion irradiation were explained by considering formation of hydrophilic group due to a reaction between irradiated polymer chain by energetic ion irradiation and blown oxygen gas. X-ray photoelectron spectroscopy analysis shows that hydrophilic groups such as -C-O, -(C=O)- and -(C=O)-O- are formed on the surface of polymer by chemical interaction. The polymer surface modification using ion assisted reaction only changed the surface physical properties and sept the bulk properties. In comparison with other modification methods, the surface modification by IAR treatment was chemically stable and enhanced the adhesion between metal and polymer surface. The applications of various kinds of polymer surface modification methods, metal and polymer surface. The applications of various kinds of polymer surface modification could be appled to the new materials about hydrophilic surface properties by IAR treatment. The adhesion between metal film and polymer measured by Scotch tape test whether the hydrophilic surfaces could improve the adhesion strength or not.

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Inverse effect of Nickel modification on photoelectrochemical performance of TiNT/Ti photoanode (TiNT/Ti 광아노드의 광전기화학 특성에 미치는 Ni 금속의 영향)

  • Lee, JeongRan;Choi, HaeYoung;Shinde, Pravin S.;Go, GeunHo;Lee, WonJae
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.100-100
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    • 2011
  • Nanomaterial architecture with highly ordered, vertically oriented $TiO_2$ nanotube arrays shows a good promise for diverse technological applications. As inspired from the literature reports that Nickel modification can improve the photocatalytic activity of $TiO_2$, it was planned to coat Ni into the $TiO_2$ matrix. In this study, first $TiO_2$ nanotubes(TiNTs) were prepared by anodization (60V,3min) in HF-free aqueous electrolyte on ultrasonically cleaned polished titanium sheet substrates ($1{\times}7cm^2$). The typical thickness of the sintered TiNT ($500^{\circ}C$for10min) was ~1 micronas confirmed from the FESEM study. In the next part, as-anodized and sintered TiNT/Ti photoanodes were used to coat Ni by AC electrodeposition from aqueous 0.1M nickel sulphate solution. During AC electrodeposition, conditions such as 1V DC offset voltage, 9V amplitude (peak-to-peak) and 750 Hz frequency were fixed constant and the deposition time was varied as 0.5 min, 1 min, 2 min and 10 min. The photoelectrochemical performance of pristine and Ni modified TiNT/Ti photoanodes was measured in 1N NaOH electrolyte under 1 SUN illumination in the potential range of -1V and 1.2V versus Ag/AgCl reference electrode. The photocurrent performance of TiNT/Ti photoanode decreased upon Ni modification and the results were confirmed after repeated experiments. This suggests us that Ni modification inhibits the photoelectrochemical performance of $TiO_2$ nanotubes.

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The Effect of Behavior Modification on Enhancing Patient Adherence to Tuberculosis Treatment Regimens (Video프로그램을 통한 환자교육이 결핵환자 치료이행행위에 미치는 영향)

  • 정은리
    • Journal of Korean Academy of Nursing
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    • v.26 no.3
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    • pp.697-708
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    • 1996
  • Most efforts to improve tuberculosis treatment adherence target the patient and his or her behavior. This study examined the effects of behavioral modification training for these patients. Based on Bandura's behavioral principles of modeling, intervention strategies using a video program were devised to elicit specific patient target behaviors considered to improve patients' adherence to tuberculosis treatment regimens. A random assignment, two-group(experimental group and control group) research design including 81 subjects was used. The main outcomes measured were pill taking measured with the Medication Event Monitoring System(MEMS) Medication Cap, patients' self-efficacy, and their knowledge of tuberculosis. The findings are as follows : 1) There was a significant difference between the experimental group and the control group in patients' feelings of self-efficacy. That is, the patients who received the behavior modification program showed greater feeling of self-efficacy to initiate and change their behavior for the tuberculosis treatment regimen than the patients who did not receive the program(t=3.51, p=0.01). 2) There was a significant difference between the experimental group and the control group in patients' knowledge of tuberculosis. That is, the patients who received the behavior modification program showed higher level of knowledge of tuberculosis than the patients who did not receive the program(t=2.15, p=0.03) 3) There was a significant difference between the experimental group and the control group in patients' adherence to tuberculosis treatment regimens. That is, the patients who received the behavior modification program showed greater adherence to the treatment regimens than the patients who did not receive the program(t=5.11, p=0.00). The study findings provided useful insights into nursing practice, particularly in planning intervention strategies aimed at enhancing patients' adherence in tuberculosis that may also be relevant to other chronic diseases with patient adherence problems.

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A Study on Applet Control on the Internet Communication using Java Bytecode (자바 바이트 코드를 이용한 인터넷 통신의 애플릿 제어)

  • 김문환;나상동
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.28 no.5C
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    • pp.523-531
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    • 2003
  • Java applets are downloaded from web server through internet and executed in Java Virtual Machine of clients'browser. Before execution of java applets, JVM checks bytecode program with bytecode verifier and performs runtime tests with interpreter. However, these tests will not protect against undesirable runtime behavior of java applets, such as denial of service attack, email forging attack, URL spoofing attack, or annoying sound attack. In order to protect malicious applets, a technique used in this paper is java bytecode modification. This technique is used to restrict applet behavior or insert code appropriate to profiling or other monitoring efforts. Java byte modification is divided into two general forms, class-level modification involving subclassing non-final classes and method-level modification used when control over objects from final classes or interface. This paper showed that malicious applets are controlled by java bytecode modification using proxy server. This implementation does not require any changes in the web sever, JVM or web browser.