• Journal of Power Electronics
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• v.2 no.3
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• pp.171-180
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• 2002

New 42-volt automotive electrical systems can provide significant improvements in vehicle performance and fuel economy. It is crucial to provide protection against load dump and other overvoltage transients in 42-volt systems. While advanced active control techniques are generally considered capable of providing such protection, the use of passive transient voltage suppression (TVS) devices as a secondary or supplementary protection means can significantly improve design flexibility and reduce system costs. This paper examines the needs and options for passive TVS devices for 42-volt applications. The limitations of the commonly available automotive TVS devices, such as Zener diodes and metal oxide varistors (MOV), are analyzed and reviewed. A new TVS device concept, based on power MOSFET and thin-film polycrystalline silicon back-to-back diode technology, is proposed to provide a better control on the clamp voltage and meet the new 42-volt specification. Both experimental and modeling results are presented. Issues related to the temperature dependence and energy absorbing capability of the new TVS device are discussed in detail. It is concluded that the proposed TVS device provides a cost-effective solution for load dump protection in 42-volt systems.

• Journal of the Korean Chemical Society
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• v.10 no.1
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• pp.32-42
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• 1966

The electrolysis of tungstic oxide dissolved in the bath of calcium chloride and calcium oxide was studied to produce metallic tungsten using carbon as anode and iron as cathode in the temperature range of 900^{\circ}$ to $1200^{\circ}C$. The binary phase diagrams $CaCl_2$-CaO and $CaCl_2-CaWO_4$ systems were constructed to determine the suitability of bath composition and the range of temperatures for the electrolysis. As $WO_3$ reacted with $CaCl_2$ to form oxychloride in the fused salt, the addition of the proper amount of CaO was necessary to avoid the loss of $WO_3$. The optimum compositions of fused bath were $CaCl_2$ 100 parts, CaO and $WO_3$ each 10 to 20 parts, with the CaO, $WO_3$ ratio greater than unity, to keep freezing point low and to prevent the vaporization of $CaCl_2$. The observed decomposition voltage at which $WO_3$ decomposes to W and CO was-0.1 volt, whereas the calculated was -0.3 volt. Metallic tungsten deposited at the cathode reacted easily with CO formed secondarily at the anode surface, to form WC below $1050^{\circ}C$, so that the cell temperature should be above $1050^{\circ}C$. The effects of cathode current densities on current efficiency were minor in the range of 1 to 5 $amp/cm^2$.