• Title/Summary/Keyword: 4-decanol

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Antimutagenic effects of 4-decanol identified from mustard leaf (갓으로부터 분리, 동정된 4-decanol의 항돌연변이 효과)

  • Kim, Jeong-Ok;Kim, Mu-Nam;Park, Kun-Young;Moon, Suk-Hee;Ha, Yeong-Lae;Rhee, Suk-Hee
    • Applied Biological Chemistry
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    • v.36 no.6
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    • pp.424-427
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    • 1993
  • The chloroform extract of mustard leaves (Brassica juncea Cosson) reduced mutagenicity of $AFB_1$ in bacterial assay (Salmonella typhimurium TA100). 4-Decanol was one of major compounds in the chloroform extract when analyzed by GC-MS on HP-5 capillary column. The authentic compound of 4-decanol dissolved in DMSO (0.5%) inhibited mutagenic activities of $AFB_1$ and MNNG in Salmonella typhimurium TA100 at a rate of 99% and 93%, respectively. This result indicates that 4-decanol is an antimutagenic compound present in chloroform extract of mustard leaves.

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Separation of Molybdenum and Tungsten from Sulfuric acid Solution by Solvent Extraction with Alamine 336 (황산용액에서 Alamine 336에 의한 용매추출로 몰리브덴과 텅스텐의 분리)

  • Nguyen, Thi Hong;Lee, Man Seung
    • Resources Recycling
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    • v.25 no.1
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    • pp.16-23
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    • 2016
  • The separation behaviour of Mo and W from sulfuric acid solution by solvent extraction with Alamine 336 was investigated as a function of solution pH and extractant concentration. Selective extraction of Mo over W by Alamine 336 was obtained in the pH range of 3-5 with low amine concentration. The mixture of Alamine 336 and acidic extractants improved the separation factor between Mo and W and was in the following order: D2EPHA > PC88A > Decanol > Versatic acid. The stripping efficiency of Mo and W from the loaded mixture of Alamine 336 and D2EHPA was very poor, while complete stripping of Mo and W was possible from the mixture of Alamine 336 and Decanol by using a mixture of $NH_4OH$ and $NH_4Cl$.

Extraction Characteristics of $Cr^{6+}$ from Aqueous Solutions with PC-88A, Alamine 336 and Aliquat 336 (PC-88A, Alamine 336 및 Aliquat 336에 의한 수용액중$Cr^{6+}$의 추출특성)

  • Kim Sung Gyu;Lee Hwa Young;Oh Jong Kee
    • Resources Recycling
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    • v.11 no.6
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    • pp.18-23
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    • 2002
  • A study on the solvent extraction of hexavalent chromium from aqueous solutions has been investigated. The results showed that the extraction efficiency of chromium increased in proportion to extractant concentration. Aliquat 336 of quarternary amine effectively extracted hexavalent chromium and was superior to Alamine 336. And the stabilizers like polyhydric alcohols of octanol, decanol and dodecanol showed the similar effect fur prevention of third phase and a little promotion of extraction efficiency in comparison with non-use of polyhydric alcohols. On the other hand, in solvent extraction of hexavalent chromium from aqueous solutions, the hexavalent chromium was completely extracted at pH range lower than 7 with 1% Aliquat 336 as extractant and 5% decanol as stabilizer and the hexavalent chromium in extractant was completely stripped with 1M sodium hydroxide solution in the stripping step.

The Penetration of n-Alkanols into Model Membranes of Cholesterol Plus Phospholipids Extracted from Brain Membranes (n-Alkanols가 Cholesterol과 인지질들로서 제제한 인공세포막에서의 침투정도)

  • Kim, Inn-Se;Baik, Seong-Wan;Chung, Kyoo-Sub
    • The Korean Journal of Pain
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    • v.6 no.1
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    • pp.74-82
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    • 1993
  • 신선한 소의 대뇌피질로부터 synaptosomal plasma membrane vesicles(SPMV)를 분리하고 이 SPMV로부터 추출한 총지질(cholesterol과 각종 인지질 함유)로서 제제한 인공세포막(SPMVTL)에서의 n-alkanols 침투 정도를 형광 probe를 이용한 형광 소광법을 통하여 검색하였다. n-alkanols는 SPMVTL 외부 단층(outer monolayer)의 표면에 주로 분포하되 그 탄소수에 비례하여 소수성 부위에 분포되는 양이 증가되는 경향을 나타내었다(1-decanol은 예외). Methanol, ethanol, 1-propanol, 1-butanol, 1-pentanol, 1-hexanol, 1-hepatnol, 1-cotanol, 1-nonanol 및 1-decanol은 SPMVTL 외부 단층 표면(친수성 부위)에 분포되는 것이 소수성 부위에 분포되는 것에 비하여 각각 650, 288, 151.6, 69.5, 36.8, 11.9, 4.8, 1.6, 0.74, 2.1배가 된다는 것을 확인하였다. 1-decanol은 $C_{10}$인데도 불구하고 $C_8$인 1-octanol에 비하여 적은 양이 소수성 부위에 침투 분포되는 것이 확인되었다. 또한 n-alkanols는 저자등이 이미 보고한 SPMV에서의 경우보다도 본 연구에서의 SPMVTL의 경우가 현저하게 많은 양이 소수성 부위로 침투 분포된다는 것이 확인되었다.

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Aroma-Active Compounds in Omandungi (Styela plicata)-Doenjang (Soybean Paste) Stew (오만둥이 된장찌개의 Aroma-active 화합물)

  • Jeong, Eun-Jeong;Cho, Woo-Jin;Cha, Yong-Jun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.41 no.6
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    • pp.414-418
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    • 2008
  • Volatile compounds in Omangdungi (Styela plicata)-Doenjang (soybean paste) stew were analyzed using solvent-assisted flavor evaporation/gas chromatography/mass-selective detection/olfactometry (SAFE/GC/MSD/O) and aroma extract dilution analysis (AEDA). The GC/O analysis detected 37 volatile compounds, of which 32 were positively identified, and included 9 aldehydes, 5 alcohols, 4 aromatic hydrocarbons, 4 ketones, 3 esters, 3 N-containing compounds, 2 acids, 1 S-containing compound, and 1 furan. Nine aroma-active odorants ($\log_3FD{\geq}3.0$) in the sample included six compounds derived from Doenjang (3-methyl(thio)propanal, tetramethylpyrazine, 4-vinyl-2-methoxyphenol, 2-acetylpyrrole, butyric acid, and 2-methoxyphenol) and three compounds from Omangdungi (2-acetyl-2-thiazoline, 9-decanol, and 6-decenol). Three compounds derived from Omangdungi (9-decanol, 6-decenol, and 6-nonenol) were thought to enhance the seafood-like flavor of Omangdungi-Doenjang stew.

The Penetration of n-Alkanols into Model Membranes of cholesterol Plus Phospholipids Extracted from Brain Membranes (n-Alkanols가 인지질들로서 제제한 인공세포막에서의 침투정도)

  • Kim, Inn-Se;Baik, Seong-Wan;Chung, Kyoo-Sub
    • The Korean Journal of Pain
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    • v.6 no.1
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    • pp.67-73
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    • 1993
  • 소의 신선한 대뇌피질로부터 synaptosomal plasma membrane vesicles(SPMV)를 분리한 후 이 SPMV로부터 추출한 모든 인지질들로서 제제한 인공세포막(SPMVPL)에서의 n-alkanols 침투 정도를 형광 probe를 이용한 형광 소광법을 통하여 검색하였다. n-alkanols는 SPMVPL 외부 단층(outer monolayer)의 표면에 주로 분포하되 그 탄소수에 비례하여 소수성 부위에 분포되는 양이 증가되는 경향을 나타내었다. methanol, ethanol, 1-propano, 1-butanol, 1-pentanol, 1-hexanol, 1-heptanol, 1-octanol, 1-nonanol 및 1-decanol은 SPMVPL 외부 단층의 표면(친수성 부위)에 분포되는 것이 소수성 부위에 분포되는 것에 비하여 각각 432.4, 208.9. 125.6, 88.2, 19.3, 7.9, 2.6, 1.0, 0.42, 1.36배가 되었다. 1-decanol은 $C_{10}$인데도 불구하고 $C_8$인 1-octanol에 비하여 적은 양이 소수성 부위에 침투 분포된다는 것이 확인되었다. n-alkanols의 침투에 대하여 저자등이 이미 보고한 바 있는 SPMV 및 SPMVTL(cholesterol+phospholipids)의 경우보다도 본 연구에서의 SPMVPL의 경우가 현저하게 많은 양이 소수성 부위로 침투 분포된다는 것도 확인되었다.

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An experiment on activation energies of alcohol fuels (알코홀 연료의 활성화 에너지에 관한 실험적 연구)

  • 이정헌;김경오;정석호
    • Journal of the korean Society of Automotive Engineers
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    • v.13 no.3
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    • pp.43-48
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    • 1991
  • Activation energies of alcohol fuels have been determined through droplet combustion and extinction experiments using droplet suspension technique in a low pressure environment to minimize the effect of buoyance. Results show that the activation energies determined are 41.4 kcal/mol for ethanol, 47.6 for 1-propanol, 48.4 for 1-butanol, 40.0 for 2-butanol, 48.0 for 1- pentanol, 50.8 for 1-hexanol and 51.7 for 1-decanol.

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Development of Diagnostic Strip for Determining Paraquat in Urine (뇨중 파라쿼트(paraquat)측정용 진단 시험지의 개발)

  • Park Sang-Bum Park;Won-Cheoul Jang;Jong-Wan Kim
    • Journal of the Korean Chemical Society
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    • v.47 no.4
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    • pp.339-344
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    • 2003
  • Paraquat is an effective and widely used herbicide, but it is also very toxic to humans. It is well-known that urine paraquat concentration is one of the most important prognostic indicator for paraquat-poisoning. Quantitative analysis of paraquat, however, are not generally used in clinical laboratories. In this work, a new test strip to detect paraquat concentration using sodium dithionite in urine was developed. Using these second-derivative method, the test strip prepared in $0.5{\%}$ borate buffer (pH 8.0), 0.25 M $Na_2S_2O_4,\0.1~0.8{\%}$ PVP, and $1{\%}$ decanol showed not only better color reaction but also an excellent application possibility to be used in automatic analyzer.

Analysis of the Aroma Constituents of Korean mandarin (Citrus reticula) and Orange Juices by Capillary GC and GC/MS (한국산 감귤쥬스의 향기성분)

  • Lee, Hyun-Yu;Hawer, Woo-Deck;Shin, Dong-Hwa;Chung, Dong-Hyo
    • Korean Journal of Food Science and Technology
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    • v.19 no.4
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    • pp.346-354
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    • 1987
  • The voflatile fraction from Korean mandarin (Citrus reticula) and valencia orange essence oil were analyzed by capillary gas chromatography and the separated components were identified from their retention time and mass pectrum. The essence oil were extracted with methylene chloride after steam distillation. The major volatile constituents of mandarin and sweet orange was limonene which accounted for 68% of total volatiles in mandarin and 87% in sweet orange. The 31 components identified from mandarin include 11 hydrocarbones, 1 ester, 10 alcohols, 4 aldehydes, 5 miscellaneous. The following 37 components were identified in sweet orange; 12 hydrocarbones, 1 ester, 11 alcohols, 8 aldehydes, 5 misecellaneous. Mandarin contained more octanal, ${\alpha}-terpinene$, terpineol, styrene, dcitronellol, citronellal, citral and farnesol while orange included more sweet orange, myrcene, ${\beta}-pinene$, linallol, decanol, ${\beta}-copaene$, elemene, ${\beta}-cadinene$, valencene.

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Development of Novel Diagnostic Testing Strips for Measuring Leukocyte Levels in Urine (요 중 백혈구를 측정하기 위한 새로운 진단 시험지 개발에 관한 연구)

  • Park, Soo Min;Park, Chung Oh;Jang, Won Cheoul
    • Journal of the Korean Chemical Society
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    • v.43 no.1
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    • pp.104-109
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    • 1999
  • A number of leukocytes increases when infected by a germ or virus. Detection of leukocyte levels can indicate of such medical informations as urogenital tract infection or other dysfunction. In this study, pentyl-3-thiophene-carboxlyate (PTC), pentyl-8-quinolinecarboxylate (PQC), and 2-Phenyl-4(N-tosyl-alanyloxyl)-thiazole (PTT) were synthesized, and the test strips were prepared with these substrates for quantifying leukocytes in urine. Among these substrates, the PTT test strip prepared in 0.5% borate buffer pH 8.0, 0.03% PTT, 0.1-0.8% PVP, and 1% decanol showed not only better color reaction but also an excellent application possibility to be used in automatic urine analyzer.

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