• 제목/요약/키워드: 3b

검색결과 43,790건 처리시간 0.068초

$Na_2O-Fe2O_3-B_2O_3-P_2O_5$ 계 유리의 도전성에 관한 연구 (A Study on the Electrical Conductivity of $Na_2O-Fe2O_3-B_2O_3-P_2O_5$ System Glass)

  • 박용원;이경태
    • 한국세라믹학회지
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    • 제22권3호
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    • pp.35-40
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    • 1985
  • The composition of the base glass was determined to be $Na_2O$ 15, $Fe_2O_3$ 35, $B_2O_3$ 0~20, $P_2O_5$ 30~50 by mole percent. The heating temperature for nucleation was determined by means of thermal expansion curve. Crystalline phases were investigated by X-ray diffraction method and I.R Spectra. Electrical conductivities of glass spec-imens were observed in the temperature range 25~20$0^{\circ}C$ The activation energies of these specimens were caculated. The results obtained were as follows : 1) The limit composition of the melts 15mol% $Na_2O$ 35mole% $Fe_2O_5$ 20mole% $B_2O_3$ 30mole% $P_2O_5$ was able to be formed into desired shapes during cooling, . 2) In the measurement of d. c conductivity($\delta$) on the glasses in the system $15Na_2O-35Fe_2O_3$-$B_2O_3$-(50-x) $P_2O_5$ the values decreased by replacing 5 mole% $P_2O_5$ with $B_2O_3$ 3) The d. c conducties of heat treated samples were increased by replacing $P_2O_5$ with $B_2O_3$ 4) $B_2O_3$ contributed to precipitate crystals such as${\gamma}$-$Fe_2O_3$ $Fe_3O_4$ which had the advantage of electronic conduction in heat treated samples. 5) The slope plotted Log($\delta$) versus 1/T in this glass system was linear in the measured temperature range.

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Fe-25at%Al합금의 $DO_3{\rightleftharpoons}B2$ 천이온도, 미세조직 및 부식거동에 미치는 B, Si의 영향 (Effects of B and Si Additions on the $DO_3{\rightleftharpoons}B2$ Transition Temperature, Microstructure and Corrosion Behavior of Fe-25at%Al Alloys)

  • 최답천;황금연
    • 한국주조공학회지
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    • 제12권2호
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    • pp.131-138
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    • 1992
  • The effects of B additions, alone or in combination with Si, on the microstructure, $DO_3{\rightleftharpoons}B2$ transition temperature($T_c$) and corrosion behavior of Fe-25at%Al alloys were investigated. The raw materials were arc-melted in vacuum and then subjected to the following heat treatments to maximize the $DO_3$ order : homogenized at $1000^{\circ}C$ for 48hrs, slowly cooled to $500^{\circ}C$, and held at that temperature for 24hours. Results showed that the B addition to Fe-25at%Al alloys does indeed refine the grain and change from intergranular to transgranular fracture mode at room temperature, indicating a strengthening of grain boundaries. The Fe-25at% Al-1at% B-3at% Si alloy showed the highest $T_c$(${\Delta}T_c=150^{\circ}C$) in this work. However, the effectiveness of Si in raising $T_c$ decreased with more than 5at% Si additions combined with B. Since the preferential corrosion occurs at the precipitates, the corrosion resistance decreased due to the increased amount of precipitates with alloying additions.

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3차원 전극을 사용한 Rhodamine B의 전기분해에 미치는 운전인자의 영향 (Effect of Operating Parameters on Electrochemical Degradation of Rhodamine B by Three-dimensional Electrode)

  • 김동석;박영식
    • 한국환경보건학회지
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    • 제35권4호
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    • pp.295-303
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    • 2009
  • A simulated wastewater containing the dye Rhodamine B (RhB) was electrolytically treated using a three-dimensional electrode reactor equipped with granular activated carbon (GAC) as particle electrode. The effect of type of packing material (GAC, ACF, Nonwoven fabric fiber coated with activated carbon), amounts of GAC packing (25-100 g), current (0.5-3 A) and electrolyte concentration (0.5-3 g/l) was evaluated. Experimental results showed that performance for RhB decolorization of the 3 three-dimensional electrodes lie in: GAC > Nonwoven fabric fiber > ACF. When considered RhB decolorization, oxidants concentration and electric power, optimum GAC dosage was 50 g. Generated concentration of 3 oxidants ($ClO_2$, free Cl, $H_2O_2$) was increased with increase of applied current, however optimum current for RhB degradation was 2.5 A. The oxidants concentration was increased with increase of NaCl concentration and optimum NaCl dosage for RhB degradation was 1.5 g/l.

Tyrphostin ErbB2 Inhibitors AG825 and AG879 Have Non-specific Suppressive Effects on gp130/ STAT3 Signaling

  • Lee, Hyun-Kyoung;Seo, In-Ae;Lee, Sang-Hwa;Seo, Su-Young;Kim, Kyung-Sup;Park, Hwan-Tae
    • The Korean Journal of Physiology and Pharmacology
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    • 제12권5호
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    • pp.281-286
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    • 2008
  • Although the interaction between gp130 and the ErbB family has frequently been shown in cancer cells, the mechanism of this interaction remains unclear and controversial. In the present study, we found that specific tyrphostin inhibitors of ErbB2 (AG825 and AG879), but not ErbB1 inhibitor (AG1478), suppressed IL-6-induced tyrosine phosphorylation of STAT3 in schwannoma cells. However, biochemical evidence for transactivation of ErbB2 by IL-6 was not observed. Additionally, the inhibition of ErbB2 expression, with either a specific RNAi or transfection of an ErbB2 mutant lacking the intracellular domain did not inhibit the IL-6-induced tyrosine phosphorylation of STAT3. Thus, it seems that tyrphostins, which are known as specific inhibitors of the ErbB2 kinase, may have non-specific suppressive effects on the IL-6/STAT3 pathway.

고잔류자화 $\alpha$-Fe기 Nd-Fe-B 초미세결정립 합금의 자기특성 (Magnetic Properties of $\alpha$-Fe Based Nd-Fe-B Nanocrystalline with High Remanence)

  • 조용수;김윤배;박우식;김창석;김택기
    • 한국자기학회지
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    • 제5권1호
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    • pp.38-41
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    • 1995
  • $\alpha$-Fe를 주상으로 하는 새로운 Nd-Fe-B계 합금을 개발하기 위하여 Nd 함유량을 4at.%로 고정시킨 Nd-Fe-B 초미세결정립합금의 제조 및 자기특성이 조사되었다. 급속응고법으로 제조된 $Nd_{4}Fe_{85.5}B_{10.5}$ 비정질합금은 결정화하여 $\alpha$-Fe 기지상에 $Nd_{2}Fe_{14}B$이 형성되나 자기특성${_{i}H_{c}=95.5kA/m(1.2kOe),\;Br=1.2T}$은 열화된다. Nb 및 Cu를 첨가한 $Nd_{4}Fe_{82}B_{10}Nb_{3}Cu_{1}$ 합금은 $\alpha$-Fe 결정립미세화(<30nm)로 보자력이 207kA/m(2.6 kOe)로 증가하나 잔류자화는 개선되지 않았다. 이 합금조성에 8at.% Co 첨가는 결정립을 더욱 미세화시키며 자기특성을 개선 시킨다. 최적열처리조건에서 $Nd_{4}Fe_{74}Co_{8}B_{10}Nb_{3}Cu_{1}$ 합금의 잔류자화, 보자력 및 최대에너지적이 각각 1.34 T, 219 kA/m (2.75kOe) 및 $95.5kJ/m^{3}$(12MGOe) 이다.

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영광 3/4호기 압력용기의 중성자 조사량계산을 통한 ENDF / B-IV와 VI 철(Fe) 자료의 비교 (Comparison of Iron(Fe) Data of ENDF/B-IV and VI in Yonggwang Nuclear Unit-3/4 Vessel Fluence Calculation)

  • Kim, Tae-Hyeong;Cho, Nam-Zin
    • Nuclear Engineering and Technology
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    • 제27권1호
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    • pp.74-83
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    • 1995
  • 원자로 압력용기에서의 정화한 속중성자 조사량의 계산은 발전소 압력용기 surveillance program의 핵심적인 부문이다. 최근 기존의 ENDF /B-III~V에 있는 철의 핵단면적 자료가 압력용기와 같은 철이 포함된 구조물에서 속중성자속을 낮게 평가하는 것으로 알려지고 있다. 본 논문에서는 ENDF /B-IV와 VI의 철(Fe) 자료의 비교를 위해 영광3/4호기 모델과 2개의 ENDF/B 파일에 있는 각각의 철자료를 이용하여 47-에너지그룹 핵단면적집 (CXFe-IV와 CXFe-VI )을 만들었다. CXFe-IV와 CXFe-VI를 사용하여 수행한 DOT4.3 계산결과에 의하면 압력용기 취화해석에 중요한 속중성자속(E 〉 1.0 MeV) 계산에서 ENDF /B-VI의 철자료를 사용한 경우가 ENDF /B-IV의 철자료를 사용한 경우보다 압력용기 내부표면에서 7.6%, 외부표면에서 20% 높게 나타났다.

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Sintering and Mechanical Properties of Chromium Boride-chromium Carbide Composites

  • Matsushita, Jun-Ichi;Shimao, Kenji;Machida, Yoshiyuki;Takao, Takumi;Iizumi, Kiyokata;Sawada, Yutaka;Shim, Kwang-Bo
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.1104-1105
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    • 2006
  • Several boride sintered bodies such as $TiB_2$, $ZrB_2$, and $SiB_6$ were previously reported. In the present study, the sinterability and physical properties of chromium boride $(CrB_2)$ containing chromium carbide $(Cr_3C_2)$ sintered bodies were investigated in order to determine its new advanced material. The samples were sintered at desired temperature for 1 hour in vacuum under a pressure by hot pressing. The relative density of sintered bodies was measured by Archimedes' method. The relative densities of $CrB_2$ addition of 0, 5, 10, 15 and 20 mass% $Cr_3C_2$ composites were 92 to 95%. The Vickers hardness of the $CrB_2$ with 10 and 15 mass% $Cr_3C_2$ composites were about 14 and 15 GPa at room temperature, respectively. The Vickers hardness at high temperature of the $CrB_2$ addition of 10 mass% $Cr_3C_2$ composite decreased with increasing measurement temperature. The Vickers hardness at 1273 K of the sample was 6 GPa. The Vickers hardness of $CrB_2$ addition of $Cr_3C_2$ composites was higher than monolithic $CrB_2$ sintered body. The powder X-ray diffraction analysis detected CrB and $B_4C$ phases in $CrB_2$ containing $Cr_3C_2$ composites.

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Epigallocatechin Gallate가 인체 유방암 세포인 MDA-MB-231의 세포증식억제에 미치는 영향 (Effect of Epigallocatechin Gallate on Inhibition of Cell Proliferation in MDA-MB-231 Human Breast Cancer Cells)

  • 홍은정;김우경
    • 한국식품영양과학회지
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    • 제36권8호
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    • pp.983-988
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    • 2007
  • 본 연구는 녹차의 폴리페놀 성분 중에서 항암효과가 가장 크다고 알려진 EGCG가 인체 유방암 세포 MDA-MB-231의 세포증식억제 기전을 알아보고자 실시하였다. EGCG 처리 농도가 증가할수록 48시간 후에 유방암 세포의 증식이 유의적으로 감소되었다. 세포증식 관련 단백질인 $ErbB_2$, $ErbB_3$, Akt의 단백질 발현은 EGCG의 첨가농도 10 ${\mu}m$ 이상일 때부터 유의적으로 발현이 감소하였고, mRNA 발현은 5 ${\mu}m$ 이상부터 유의적으로 감소되었다. Py20, p-Akt 로 단백질의 인산화를 알아본 결과 EGCG 첨가농도가 증가할수록 $ErbB_2$, $ErbB_3$, Akt 의 인산화가 감소함을 확인할 수 있었다. 본 연구 결과를 종합해 보면 인체 유방암 세포 MDA-MB-231에서 EGCG는 암세포에서 과발현되는 $ErbB_2$, $ErbB_3$, Akt의 세포신호 전달과정 억제를 통하여 암세포의 증식을 억제시키는 것을 알 수 있었다.

Nd(Ⅲ)과 B15C5 치환체와의 착물의 구조에 관한 연구 (Structural Studies on Complexes of Substituted B15C5 with Nd(Ⅲ))

  • 김해중;신영국;김시중
    • 대한화학회지
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    • 제39권9호
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    • pp.692-697
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    • 1995
  • 아세톤($Ac-d_6$)에서 B15C5과 ND(3)과의 착물형성에 따른 조성비와 구조를 NMR를 이용하여 연구하였다. 일정한 농도의 B15C5에 Nd(3)의 농도 증가에 따른 공명선이 저자기장 이동되었으며, 착물의 조성비가 1:1임을 알 수 있었다. 수소피크의 띠넓힘 현상은 Nd(3)과 산소원자와의 상호작용에 기인한다고 생각된다. 또한 고체상에서의 치환된 B15C5와 Nd(III)과의 착물의 구조를 적외선스펙트럼으로 연구하였다. 그 결과 착물형성시 니트라토기가 두자리 리간드로 배위되었고, 비대칭 C-C-O 신축 진동의 띠이동이 있었다. 이로부터 Nd(3)-B15C5 착물의 구조는 Nd(3)에 5개의 산소원자와 3개의 두자리 니트라토기가 배위된 형태임을 알 수 있었다.

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