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A Study on the Electrical Conductivity of $Na_2O-Fe2O_3-B_2O_3-P_2O_5$ System Glass ($Na_2O-Fe2O_3-B_2O_3-P_2O_5$ 계 유리의 도전성에 관한 연구)

  • 박용원;이경태
    • Journal of the Korean Ceramic Society
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    • v.22 no.3
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    • pp.35-40
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    • 1985
  • The composition of the base glass was determined to be $Na_2O$ 15, $Fe_2O_3$ 35, $B_2O_3$ 0~20, $P_2O_5$ 30~50 by mole percent. The heating temperature for nucleation was determined by means of thermal expansion curve. Crystalline phases were investigated by X-ray diffraction method and I.R Spectra. Electrical conductivities of glass spec-imens were observed in the temperature range 25~20$0^{\circ}C$ The activation energies of these specimens were caculated. The results obtained were as follows : 1) The limit composition of the melts 15mol% $Na_2O$ 35mole% $Fe_2O_5$ 20mole% $B_2O_3$ 30mole% $P_2O_5$ was able to be formed into desired shapes during cooling, . 2) In the measurement of d. c conductivity($\delta$) on the glasses in the system $15Na_2O-35Fe_2O_3$-$B_2O_3$-(50-x) $P_2O_5$ the values decreased by replacing 5 mole% $P_2O_5$ with $B_2O_3$ 3) The d. c conducties of heat treated samples were increased by replacing $P_2O_5$ with $B_2O_3$ 4) $B_2O_3$ contributed to precipitate crystals such as${\gamma}$-$Fe_2O_3$ $Fe_3O_4$ which had the advantage of electronic conduction in heat treated samples. 5) The slope plotted Log($\delta$) versus 1/T in this glass system was linear in the measured temperature range.

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Effects of B and Si Additions on the $DO_3{\rightleftharpoons}B2$ Transition Temperature, Microstructure and Corrosion Behavior of Fe-25at%Al Alloys (Fe-25at%Al합금의 $DO_3{\rightleftharpoons}B2$ 천이온도, 미세조직 및 부식거동에 미치는 B, Si의 영향)

  • Choi, Dap-Chun;Hwang, Keum-Yeon
    • Journal of Korea Foundry Society
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    • v.12 no.2
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    • pp.131-138
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    • 1992
  • The effects of B additions, alone or in combination with Si, on the microstructure, $DO_3{\rightleftharpoons}B2$ transition temperature($T_c$) and corrosion behavior of Fe-25at%Al alloys were investigated. The raw materials were arc-melted in vacuum and then subjected to the following heat treatments to maximize the $DO_3$ order : homogenized at $1000^{\circ}C$ for 48hrs, slowly cooled to $500^{\circ}C$, and held at that temperature for 24hours. Results showed that the B addition to Fe-25at%Al alloys does indeed refine the grain and change from intergranular to transgranular fracture mode at room temperature, indicating a strengthening of grain boundaries. The Fe-25at% Al-1at% B-3at% Si alloy showed the highest $T_c$(${\Delta}T_c=150^{\circ}C$) in this work. However, the effectiveness of Si in raising $T_c$ decreased with more than 5at% Si additions combined with B. Since the preferential corrosion occurs at the precipitates, the corrosion resistance decreased due to the increased amount of precipitates with alloying additions.

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Effect of Operating Parameters on Electrochemical Degradation of Rhodamine B by Three-dimensional Electrode (3차원 전극을 사용한 Rhodamine B의 전기분해에 미치는 운전인자의 영향)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Health Sciences
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    • v.35 no.4
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    • pp.295-303
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    • 2009
  • A simulated wastewater containing the dye Rhodamine B (RhB) was electrolytically treated using a three-dimensional electrode reactor equipped with granular activated carbon (GAC) as particle electrode. The effect of type of packing material (GAC, ACF, Nonwoven fabric fiber coated with activated carbon), amounts of GAC packing (25-100 g), current (0.5-3 A) and electrolyte concentration (0.5-3 g/l) was evaluated. Experimental results showed that performance for RhB decolorization of the 3 three-dimensional electrodes lie in: GAC > Nonwoven fabric fiber > ACF. When considered RhB decolorization, oxidants concentration and electric power, optimum GAC dosage was 50 g. Generated concentration of 3 oxidants ($ClO_2$, free Cl, $H_2O_2$) was increased with increase of applied current, however optimum current for RhB degradation was 2.5 A. The oxidants concentration was increased with increase of NaCl concentration and optimum NaCl dosage for RhB degradation was 1.5 g/l.

Tyrphostin ErbB2 Inhibitors AG825 and AG879 Have Non-specific Suppressive Effects on gp130/ STAT3 Signaling

  • Lee, Hyun-Kyoung;Seo, In-Ae;Lee, Sang-Hwa;Seo, Su-Young;Kim, Kyung-Sup;Park, Hwan-Tae
    • The Korean Journal of Physiology and Pharmacology
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    • v.12 no.5
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    • pp.281-286
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    • 2008
  • Although the interaction between gp130 and the ErbB family has frequently been shown in cancer cells, the mechanism of this interaction remains unclear and controversial. In the present study, we found that specific tyrphostin inhibitors of ErbB2 (AG825 and AG879), but not ErbB1 inhibitor (AG1478), suppressed IL-6-induced tyrosine phosphorylation of STAT3 in schwannoma cells. However, biochemical evidence for transactivation of ErbB2 by IL-6 was not observed. Additionally, the inhibition of ErbB2 expression, with either a specific RNAi or transfection of an ErbB2 mutant lacking the intracellular domain did not inhibit the IL-6-induced tyrosine phosphorylation of STAT3. Thus, it seems that tyrphostins, which are known as specific inhibitors of the ErbB2 kinase, may have non-specific suppressive effects on the IL-6/STAT3 pathway.

Magnetic Properties of $\alpha$-Fe Based Nd-Fe-B Nanocrystalline with High Remanence (고잔류자화 $\alpha$-Fe기 Nd-Fe-B 초미세결정립 합금의 자기특성)

  • 조용수;김윤배;박우식;김창석;김택기
    • Journal of the Korean Magnetics Society
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    • v.5 no.1
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    • pp.38-41
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    • 1995
  • The effects of Nb and Cu additives as will as substitutional Co into $Nd_{4}Fe_{85.5}B_{10.5}$ melt-spun alloy were studied aiming for finding a $\alpha$-Fe based Nd-Fe-B composite alloys with high energy product. The addition of Nb and Cu to $Nd_{4}Fe_{85.5}B_{10.5}$ decreased the average grain size and increased the coercivity up to 207kA/m(2.6kOe), Further-more, the substitution of Co for Fe in $Nd_{4}Fe_{82}B_{10}Nb_{3}Cu_{1}$ alloy resulted in the decrease of the average grain size (<20nm) and improved the hard magnetic properties. The remanence, coercivity and energy product of optimally annealed $Nd_{4}Fe_{74}Co_{8}B_{10}Nb_{3}Cu_{1}$ alloy were 1.345, 219kA/m(2.75kOe) and $95.5kJ/m^{3}$(12MGOe), respectively.

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Comparison of Iron(Fe) Data of ENDF/B-IV and VI in Yonggwang Nuclear Unit-3/4 Vessel Fluence Calculation (영광 3/4호기 압력용기의 중성자 조사량계산을 통한 ENDF / B-IV와 VI 철(Fe) 자료의 비교)

  • Kim, Tae-Hyeong;Cho, Nam-Zin
    • Nuclear Engineering and Technology
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    • v.27 no.1
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    • pp.74-83
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    • 1995
  • The accurate determination of the fast neutron flux/fluence onto the pressure vessel is an essential part of the reactor pressure vessel surveillance program. It has been reported recently that the iron cross section data in ENDF/B versions III through V might underestimate the flux/fluence of fast neutrons in steel structures such as reactor pressure vessel. In this study, for the comparison of iron data of ENDF/B-IV and VI we produced two 47-group cross section sets, CXFe-IV and CXFe-Ⅵ, which are based on Yonggwang nuclear unit-3/4 model and the iron data of ENDF/B-IV and VI, respectively. A comparison was made of the results obtained from DOT4.3 calculation using CXFe-IV and CXFe-VI. From the results, it was found that the fast flux(E 〉 1.0 MeV), which is important for the pressure vessel embrittlement analysis, increases by about 7.6% at the inner wall and 20% at the outer wall of the vessel, if the iron data are used from ENDF/B-VI instead of ENDF/B-IV.

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Sintering and Mechanical Properties of Chromium Boride-chromium Carbide Composites

  • Matsushita, Jun-Ichi;Shimao, Kenji;Machida, Yoshiyuki;Takao, Takumi;Iizumi, Kiyokata;Sawada, Yutaka;Shim, Kwang-Bo
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1104-1105
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    • 2006
  • Several boride sintered bodies such as $TiB_2$, $ZrB_2$, and $SiB_6$ were previously reported. In the present study, the sinterability and physical properties of chromium boride $(CrB_2)$ containing chromium carbide $(Cr_3C_2)$ sintered bodies were investigated in order to determine its new advanced material. The samples were sintered at desired temperature for 1 hour in vacuum under a pressure by hot pressing. The relative density of sintered bodies was measured by Archimedes' method. The relative densities of $CrB_2$ addition of 0, 5, 10, 15 and 20 mass% $Cr_3C_2$ composites were 92 to 95%. The Vickers hardness of the $CrB_2$ with 10 and 15 mass% $Cr_3C_2$ composites were about 14 and 15 GPa at room temperature, respectively. The Vickers hardness at high temperature of the $CrB_2$ addition of 10 mass% $Cr_3C_2$ composite decreased with increasing measurement temperature. The Vickers hardness at 1273 K of the sample was 6 GPa. The Vickers hardness of $CrB_2$ addition of $Cr_3C_2$ composites was higher than monolithic $CrB_2$ sintered body. The powder X-ray diffraction analysis detected CrB and $B_4C$ phases in $CrB_2$ containing $Cr_3C_2$ composites.

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Effect of Epigallocatechin Gallate on Inhibition of Cell Proliferation in MDA-MB-231 Human Breast Cancer Cells (Epigallocatechin Gallate가 인체 유방암 세포인 MDA-MB-231의 세포증식억제에 미치는 영향)

  • Hong, Eun-Jung;Kim, Woo-Kyung
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.36 no.8
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    • pp.983-988
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    • 2007
  • Epigallocatechin gallate (EGCG), a principal antioxidant derived from green tea, is one of the most extensively investigated chemopreventive phytochemicals. However, the effect of EGCG on proliferation in MDA-MB-231 breast cancer cell is not well known. We investigated the effect of EGCG on protein and mRNA expression related to cell proliferation in MDA-MB-231 human breast cancer cell lines. We cultured MDA-MB-231 cells in the presence of 0, 5, 10 and 20 ${\mu}m$ of EGCG. EGCG significantly inhibited the cancer cell proliferation (p<0.05). In MDA-MB-231 huamn breast cancer cell, EGCG lowered $ErbB_2$ and $ErbB_3$ protein as well as mRNA expression. In addition, protein and mRNA expression of phosphorylated Akt and total Akt were significantly decreased (p<0.05). We suggest that EGCG inhibits cell proliferation through $ErbB_2$, $ErbB_3$ and Akt cell signaling.

Structural Studies on Complexes of Substituted B15C5 with Nd(Ⅲ) (Nd(Ⅲ)과 B15C5 치환체와의 착물의 구조에 관한 연구)

  • Kim, Hae-Joong;Shin, Young-Kook;Kim, Si-Joong
    • Journal of the Korean Chemical Society
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    • v.39 no.9
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    • pp.692-697
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    • 1995
  • The chemical compositions and possible structure for the complex of B15C5 with Nd(Ⅲ) have been determined by NMR spectrophotometry in acetone-d6. On the stepwise additions of Nd(Ⅲ) to B15C5 solution of constant concentration, all the resonances shifted to downfield and the mole ratio of B15C5 to Nd(Ⅲ) was found to be 1 : 1. From the line broadening of proton peaks of NMR spectra, it was found that oxygen atoms in B15C5 interact with Nd(Ⅲ) ion. And in IR spectra of Nd(Ⅲ)-B15C5 complex, the band of asymmetric C-C-O stretching vibration shifted to a lower frequency region upon complexation. We have proposed the possible structure of the Nd(Ⅲ)-B15C5 coordinated with the five ether oxygen atoms and with the three bidentate nitrato groups.

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