• Corrosion Science and Technology
• /
• v.21 no.1
• /
• pp.32-40
• /
• 2022

The o-Vanillin - Glutamine Schiff base [2-Hydroxy-3-Methoxy BenzylidineCarbomyl) -2-Butanoic Acid] was examined for low carbon steel corrosion inhibition in acid media. Weight loss studies were carried out at three different temperatures to determine the inhibition efficiency (IE). Electrochemical impedance spectroscopy revealed that the charge transfer resistance controlled the corrosion reaction and Tafel polarization indicated that the Schiff base acts as mixed mode of inhibitor. SEM images were recorded for the surface morphology of the low carbon steel surface. DFT studies revealed corrosion control mechanisms using quantum chemical parameters such as E_HOMO, E_LUMO, energy gap (∆E), chemical Hardness (η), chemical Softness (σ), Electronegativity (χ), and the fraction of electron transferred (∆N), which is calculated using Gaussian software 09. The gas-phase geometry was fully optimized in the Density Functional Theory (DFT/B3LYP-6-31G (d)).The DFT results are in good agreement with the experimental results. All the results proved that the Schiff Base (2-Hydroxy-3-Metoxy BenzylidineCarbomyl) -2-Butanoic is a suitable alternative for corrosion inhibition of low carbon steel in acid media.

• Earthquakes and Structures
• /
• v.23 no.3
• /
• pp.283-295
• /
• 2022

Seismic design codes permit the use of Equivalent Static Analysis of buildings considering torsional eccentricity e with dynamic amplification factors on structural eccentricity and some accidental eccentricity. Estimation of e in buildings is not addressed in codes. This paper presents a simple approximate method to estimate e in RC Moment Frame and RC Structural Wall buildings, which required no detailed structural analysis. The method is validated by 3D analysis (using commercial structural analysis software) of a spectrum of building. Results show that dynamic amplification factor should be applied on torsional eccentricity when performing Response Spectrum Analysis also. Also, irregular or mixed modes of oscillation arise in torsionally unsymmetrical buildings owing to poor geometric distribution of mass and stiffness in plan, which is captured by the mass participation ratio. These irregular modes can be avoided in buildings of any plan geometry by limiting the two critical parameters (normalised torsional eccentricity e/B and Natural Period Ratio 𝜏 =T_𝜃/T, where B is building lateral dimension, T_𝜃 uncoupled torsional natural period and T uncoupled translational natural period). Suggestions are made for new building code provisions.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.22 no.2
• /
• pp.91-99
• /
• 2014

The common-rail injectors are the most critical component of the CRDI diesel engines that dominantly affect engine performances through high pressure injection with exact control. Thus, from now on the advanced combustion technologies for common-rail diesel injection engine require high performance fuel injectors. Accordingly, the previous studies on the numerical and experimental analysis of the diesel injector have focused on a optimum geometry to induce proper injection rate. In this study, computational predictions of performance of the diesel injector have been performed to evaluate internal flow characteristics for various needle lift and the spray pattern at the nozzle exit. To our knowledge, three-dimensional computational fluid dynamics (CFD) model of the internal flow passage of an entire injector duct including injection and return routes has never been studied. In this study, major design parameters concerning internal routes in the injector are optimized by using a CFD analysis and Response Surface Method (RSM). The computational prediction of the internal flow characteristics of the common-rail diesel injector was carried out by using STAR-CCM+7.06 code. In this work, computations were carried out under the assumption that the internal flow passage is a steady-state condition at the maximum needle lift. The design parameters are optimized by using the L16 orthogonal array and polynomial regression, local-approximation characteristics of RSM. Meanwhile, the optimum values are confirmed to be valid in 95% confidence and 5% significance level through analysis of variance (ANOVA). In addition, optimal design and prototype design were confirmed by calculating the injection quantities, resulting in the improvement of the injection performance by more than 54%.

• International Journal of Fluid Machinery and Systems
• /
• v.4 no.1
• /
• pp.191-198
• /
• 2011

Based on the consideration that the cavitation would affect the operation stability of miniature pumps, the 3-D turbulent cavitating flow in a test pump was simulated by using a mixed cavitation model and k-${\omega}$ SST turbulence model. In order to investigate the influence of inlet geometry parameters on the cavitation performance of the miniature pump, two more impellers are designed for comparison. Based on the results, the following conclusions are drawn: 1) Cavitation performance of the double suction shaft-less miniature pump having different impeller is equivalent to the centrifugal pump having ordinary size, though the flow passage at impeller inlet is small; 2) The miniature pump having radial impeller can produce much higher pump head, but lower cavitation performance than that having the impeller based on the conventional design method; 3) It is believed that by applying the double suction design, the miniature pump achieved relatively uniform flow pattern upstream the impeller inlet, which is favorable for improving cavitation performance.

• Bulletin of the Korean Chemical Society
• /
• v.35 no.7
• /
• pp.2086-2092
• /
• 2014

Two novel coordination compounds $[Cu_2(pypya)_3(H_2O)_2]{\cdot}Cl{\cdot}(H_2O)_5$ (1) and $\{[Cd(pypya)(ta)_{1/2}]{\cdot}H_2O\}_n$ (2) (Hpypya=2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)acetic acid, $H_2ta$=terephthalic acid) were synthesized and characterized by single X-ray diffraction. Structure determination reveals that complex 1 and complex 2 crystallize in the triclinic system, with the P-1 space group. The asymmetric unit of 1 contains two Cu(II) ions, and their coordination modes are different. These units of complex 1 are linked together via hydrogen bonds and ${\pi}-{\pi}$ interactions, and the 3D structure of complex 1 was formed. Complex 2, a mononuclear Cd(II) coordination compound, has a 2D structure which was constructed via coordination bonds. TGA and fluorescence spectra analysis of complex 1 and complex 2 have also been studied. In addition, the geometry parameters of complex 1 have been optimized with the B3LYP method of density functional theory (DFT) to explain its coordination behavior. The electronic properties of the complex 1 and ligand Hpypya have been investigated based on the nature bond orbital (NBO) analysis at the B3LYP level of theory. The result verifies that the synergistic effect have occurred in the compound.

• International Journal of Automotive Technology
• /
• v.8 no.3
• /
• pp.269-274
• /
• 2007

A prior fundamental study was executed using a constant volume chamber (CVC) to improve the burning characteristics of lean pre-mixture by the injection of active radicals generated in the sub-chamber of the CVC. The Radical ignition (RI) technique shows remarkable progress in the burning velocity and combustible lean limit compared with the results of the spark ignition (SI) technique. The optimum design value of the sub-chamber geometry is near $0.11cm^{-1}$ for the ratio of the total area of the holes to the sub-chamber volume $(A_h/V_s)$. In this study, based on the former experimental results, the additional works have been performed to examine the effects of the geometry change in the number $(N_h)$, the total section area $(A_h)$, and diameter $(D_h)$ of the passage holes on the combustion characteristics in the CVC. Also ambient conditions such as the initial temperature and the initial pressure of the mixture were selected as experimental parameters and the effects of residual gas at the chamber on the combustion characteristics were investigated. As a result, the correlation between the passage hole number and overall passage hole area was grasped. The effects of the initial temperature were significant, but on the other hand, those of the initial pressure were weak. A more detailed analysis on the residual gas is required in the future.

• Nuclear Engineering and Technology
• /
• v.45 no.3
• /
• pp.323-334
• /
• 2013

During a hypothetical core-disruptive accident (CDA) in a sodium-cooled fast reactor (SFR), degraded core materials can form roughly conically-shaped debris beds over the core-support structure and/or in the lower inlet plenum of the reactor vessel from rapid quenching and fragmentation of the core material pool. However, coolant boiling may ultimately lead to leveling of the debris bed, which is crucial to the relocation of the molten core and heat-removal capability of the debris bed. To clarify the mechanisms underlying this self-leveling behavior, a large number of experiments were performed within a variety of conditions in recent years, under the constructive collaboration between the Japan Atomic Energy Agency (JAEA) and Kyushu University (Japan). The present contribution synthesizes and gives detailed comparative analyses of those experiments. Effects of various experimental parameters that may have potential influence on the leveling process, such as boiling mode, particle size, particle density, particle shape, bubbling rate, water depth and column geometry, were investigated, thus giving a large palette of favorable data for the better understanding of CDAs, and improved verifications of computer models developed in advanced fast reactor safety analysis codes.

• Proceedings of the Korean Society of Medical Physics Conference
• /
• 2002.09a
• /
• pp.119-120
• /
• 2002

The aim is to urge the need of elaborate commissioning of 3D RTP system from the firsthand experience. A 3D RTP system requires so much data such as beam data and patient data. Most data of radiation beam are directly transferred from a 3D dose scanning system, and some other data are input by editing. In the process inputting parameters and/or data, no error should occur. For RTP system using algorithm-bas ed-on beam-modeling, careless beam-data processing could also cause the treatment error. Beam data of 3 different qualities of photon from two linear accelerators, patient data and calculated results were commissioned. For PDD, the doses by Clarkson, convolution, superposition and fast superposition methods at 10 cm for 10${\times}$10 cm field, 100 cm SSD were compared with the measured. An error in the SCD for one quality was input by the service engineer. Whole SCD defined by a physicist is SAD plus d$\sub$max/, the value was just SAD. That resulted in increase of MU by 100${\times}$((1_d$\sub$max//SAD)$^2$-1)%. For 10${\times}$10 cm open field, 1 m SSD and at 10 cm depth in uniform medium of relative electron density (RED) 1, PDDs for 4 algorithms of dose calculation, Clarkson, convolution, superposition and fast-superposition, were compared with the measured. The calculated PDD were similar to the measured. For 10${\times}$10 cm open field, 1 m SSD and at 10 cm depth with 5 cm thick inhomogeneity of RED 0.2 under 2 cm thick RED 1 medium, PDDs for 4 algorithms were compared. PDDs ranged from 72.2% to 77.0% for 4 MV X-ray and from 90.9% to 95.6% for 6 MV X-ray. PDDs were of maximum for convolution and of minimum for superposition. For 15${\times}$15 cm symmetric wedged field, wedge factor was not constant for calculation mode, even though same geometry. The reason is that their wedge factor is considering beam hardness and ray path. Their definition requires their users to change the concept of wedge factor. RTP user should elaborately review beam data and calculation algorithm in commissioning.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
• /
• v.12 no.1
• /
• pp.143-152
• /
• 2001

A method for miniaturization of microstrip patch antenna without degrading its radiation characteristics is investigated in this paper. It involves perforating the patch to form a microstrip square-ring antenna, and it's BW enhancement is investigated numerically and experimentally. A ring geometry introduces additional parameters to the antenna, and those are used to control impedances, resonance frequencies, and bandwidths. For a single square ring antenna, an increase of the size of perforation increases its input impedance, decreases the resonance frequency, and bandwidths. But it affects little on directivity of the antenna. To match the antenna to a transmission line and also enhance its bandwidth, the ring is stacked by a square patch or another square ring. Also numerically simulated results by the IE3D, and experimental data are compared for proof.

• Journal of Electrical Engineering and Technology
• /
• v.10 no.2
• /
• pp.634-640
• /
• 2015

This paper deals with the design of a microstrip line feed toppled T shaped microstrip patch antenna that gives dualband characteristics at 4 GHz and 6.73 GHz respectively. The simulation of proposed antenna geometry has been performed using method of moment based IE3D simulation software. A radial basis function neural network (RBFNN) is used for the estimation of bandwidth for dualband at 4 GHz and 6.73 GHz respectively. In RBFNN model, antenna parameters such as dielectric constant, height of substrate, and width are used as input and bandwidth of first and second band is considered as output of the network. To validate the RBFNN output, an antenna has been physically fabricated on glass epoxy substrate. The fabricated antenna can be utilized in S and C bands applications. RBFNN results are found in close agreement with simulated and experimental results.