• Interaction and multiscale mechanics
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• v.1 no.2
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• pp.279-301
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• 2008

This paper develops a 3D homogenization based continuum damage mechanics (HCDM) model for fiber reinforced composites undergoing micromechanical damage under monotonic and cyclic loading. Micromechanical damage in a representative volume element (RVE) of the material occurs by fiber-matrix interfacial debonding, which is incorporated in the model through a hysteretic bilinear cohesive zone model. The proposed model expresses a damage evolution surface in the strain space in the principal damage coordinate system or PDCS. PDCS enables the model to account for the effect of non-proportional load history. The loading/unloading criterion during cyclic loading is based on the scalar product of the strain increment and the normal to the damage surface in strain space. The material constitutive law involves a fourth order orthotropic tensor with stiffness characterized as a macroscopic internal variable. Three dimensional damage in composites is accounted for through functional forms of the fourth order damage tensor in terms of components of macroscopic strain and elastic stiffness tensors. The HCDM model parameters are calibrated from homogenization of micromechanical solutions of the RVE for a few representative strain histories. The proposed model is validated by comparing results of the HCDM model with pure micromechanical analysis results followed by homogenization. Finally, the potential of HCDM model as a design tool is demonstrated through macro-micro analysis of monotonic and cyclic damage progression in composite structures.

• Carbon letters
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• v.5 no.3
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• pp.127-132
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• 2004

Chop molding composites and 2D carbon/carbon composites were manufactured by hot press molding method. Phenol resin of novolac type was used for matrix precursor and PAN-based carbon, PAN-based graphite and pitch-based carbon fiber were used for reinforcement and boron oxide was used for oxidation retardant. All of the composites were treated by $2000^{\circ}C$ and $2400^{\circ}C$ graphitization process, respectively. After graphitization process, amount of a boron residue in carbon/carbon composites is much according to irregularity of used raw materials. Under the presence of boron in carbon/carbon composites, catalytic effect of boron was a little at $2000^{\circ}C$ graphitization temperature. However, it was quite at $2400^{\circ}C$ graphitization.

• Advances in nano research
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• v.14 no.5
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• pp.443-450
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• 2023

Carbon nanotubes (CNTs) have received increased interest in reinforcing research for polymer matrix composites due to their exceptional mechanical characteristics. Its high surface area/volume ratio and aspect ratio enable polymer-based composites to make the most of its features. This study focuses on the experimental tensile testing and fabrication of carbon nanotube reinforced composite (CNTRC) beams, exploring various micromechanical models. By examining the performance of these models alongside experimental results, the research aims to better understand and optimize the mechanical properties of CNTRC materials. Tensile properties of neat epoxy and 0.3%; 0.4% and 0.5% by CNT reinforced laminated single layer (0°/90°) carbon fiber composite beams were investigated. The composite plates were produced in accordance with ASTM D7264 standard. The tensile test was performed in order to see the mechanical properties of the composite beams. The results showed that the optimum amount of CNT was 0.3% based on the tensile capacity. The capacity was significantly reduced when 0.4% CNT was utilized. Moreover, the experimental results are compared with Finite Element Models using ABAQUS. Hashin Failure Criteria was utilized to predict the tensile capacity. Good conformance was observed between experimental and numerical models. More importantly is that Young' Moduli of the specimens is compared with the prediction Halpin-Tsai and Mixture-Rule. Although Halpin-Tsai can accurately predict the Young's Moduli of the specimens, the accuracy of Mixture-Rule was significantly low.

• Journal of the Korean Society of Hazard Mitigation
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• v.8 no.3
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• pp.1-9
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• 2008

Fiber Reinforced Polymer (FRP) composites are used extensively in aerospace, marine, automotive, infrastructure, chemical processing and sporting good applications. A concern with using FRP composites in some engineering structures is their high flammability and poor fire resistance In this research, material properties of FRP composites at increasingly high temperatures was measured and verified. The obtained mechanical properties of FRP composites were performed according to ASTM D3039/D3039M and tested to a wide range of heat conditions with temperatures from Room-temp. to 300 for times up to 30 min. It is found that the mechanical properties of FRP composites dropped with increasing heat or temperature. The reduction to the properties was due mainly to thermal degradation and combustion of the polymer matrix.

• Journal of Power System Engineering
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• v.10 no.2
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• pp.117-123
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• 2006

Woven fabrics composites are used as primary structural components in many applications because of their superior properties that offer high specific strength and stiffness. However, the complexity of the fabric structure makes understanding of their failure behavior very difficult. Also, laminate woven fabrics CFRP have unique failure mechanisms such as fiber bridging, fiber/matrix crack and so on. In particular, the delamination phenomenon of the composite materials is one of the most frequent failure mechanisms. So, we estimated interlaminar fracture and damage in composites using as ENF specimen by a 3 point bending test. And AE characteristics were examined for crack propagation on plain woven CFRP. We obtained the following conclusions from the results of the evaluation of the 3 point bending fracture test and AE characteristic estimation. AE counts of maximum crack length were obtained as $85.97{\times}10^4\;and\;93{\times}10^3\;for\;a_0/L=0.3$ and 0.6, respectively. Also the maximum amplitudes were over 80dB at both $a_0/L=0.3\;and\;0.6$. $G_{IIc}$ at that's $a_0/L$ ratio were obtained with $1.07kJ/m^2\;and\;3.79kJ/m^2$.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2005.10a
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• pp.248-251
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• 2005

To investigate the degeneration process in the intervertebral disc, a three dimensional (3D) poroelastic finite-element (FE) model was developed. Disc was modeled as two different regions, such as annulus modeled with fiber reinforced 20 node poroelastic ground matrix and nucleus having large porosity. Excess Von Mises stress in the disc element assumed to be a possible source of degeneration under compressive loading condition. Recursive calculation was continued until the desired convergence was attained by changing the permeability and porosity of those elements, which could be predicted from the previous iteration. The degenerated disc model showed that relatively small compressive stresses were generated in the nucleus elements compared to normal disc. Its distribution along the sagittal plane was matched well with a previously reported experimental result. Contrasts to this result, pore pressures in the nucleus were higher than those in the normal disc. Total stress indicated similar values for two different models. This new approach using poroelastic modeling could provide the explanation of the interaction between fluid and solid matrix in the disc during the degeneration process.

• Journal of the Korean Ceramic Society
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• v.45 no.9
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• pp.561-566
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• 2008

Carbon fiber fabric-silicon carbide composites were fabricated by liquid silicon infiltration (LSI) process. The porous two-dimensional carbon fiber fabric performs were prepared by 13 plies of 2D-plain-weave fabric in a three laminating method, [0/90], [${\pm}45$], [$0/90/{\pm}45$] lay-up, respectively. Before laminating, a thin pyrolytic carbon (PyC) layer deposited on the surface of 2D-plain weave fabric sheets as interfacial layer with $C_3H_8$ and $N_2$ gas at $900^{\circ}C$. A densification of the preforms for $C_f-Si-SiC$ matrix composite was achieved according to the LSI process at $1650^{\circ}C$ for 30 min. in vacuum atmosphere. The bending strength of the each composite were measured and the microstructural consideration was performed by a FE-SEM.

• Bulletin of the Korean Chemical Society
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• v.34 no.11
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• pp.3444-3450
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• 2013

Three phase hollow fiber-liquid phase microextraction (HF-LPME), which is faster, simpler and uses a more environmentally friendly sample-preparation technique, was developed for the analysis of Non-Steroidal Anti-Inflammatory Drugs (NSAIDs) in human urine. For the effective simultaneous extraction/concentration of NSAIDs by three phase HF-LPME, parameters (such as extraction organic solvent, pH of donor/acceptor phase, stirring speed, salting-out effect, sample temperature, and extraction time) which influence the extraction efficiency were optimized. NSAIDs were extracted and concentrated from 4 mL of aqueous solution at pH 3 (donor phase) into dihexyl ether immobilized in the wall pores of a porous hollow fiber, and then extracted into the acceptor phase at pH 13 located in the lumen of the hollow fiber. After the extraction, 5 ${\mu}L$ of the acceptor phase was directly injected into the HPLC/UV system. Simultaneous chromatographic separation of seven NSAIDs was achieved on an Eclipse XDB-C18 (4.6 mm i.d. ${\times}$ 150 mm length, 5 ${\mu}m$ particle size) column using isocratic elution with 0.1% formic acid and methanol (30:70) at a HPLC-UV/Vis system. Under optimized conditions (extraction solvent, dihexyl ether; $pH_{donor}$, 3; $pH_{acceptor}$, 13; stirring speed, 1500 rpm; NaCl salt, 10%; sample temperature, $60^{\circ}C$; and extraction time, 45 min), enrichment factors (EF) were between 59 and 260. The limit of detection (LOD) and limit of quantitation (LOQ) in the spiked urine matrix were in the concentration range of 5-15 ng/mL and 15-45 ng/mL, respectively. The relative recovery and precision obtained were between 58 and 136% and below 15.7% RSD, respectively. The calibration curve was linear within the range of 0.015-0.96 ng/mL with the square of the correlation coefficient being more than 0.997. The established method can be used to analyse of NSAIDs of low concentration (ng/mL) in urine.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2000.11a
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• pp.177-182
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• 2000

This paper predicted the equivalent stiffness of spatially reinforced composites (SRC) using the volume average of a fiber rod and matrix stiffness, and the strength of SRC using the stiffness reduction and the modified Tsai-Wu composite failure theory. Those equivalent engineering constants are used to analyze the mechanical behavior and the failure of SRC structures. Because the distribution of equivalent engineering constants is varying with the change in SRC shape, we made a program that predicts engineering constants of SRC. Both 3-D and 4-D SRC show the smallest tensile modulus and the largest shear modulus at the maximum rotated direction from each rod. Also the strength properties show the same tendency.

• The Transactions of the Korean Institute of Electrical Engineers D
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• v.52 no.5
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• pp.206-206
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• 2003

It is hard to expect excellent electrical, mechanical and chemical properties from most of the composite materials presently used as insulators due to insufficient wettability property caused by the difference of interfacial properties between the matrix material and the reinforcer. Therefore, various interfacial coupling agents have been developed to improve the interfacial properties of composite materials. But if the wettable coupling agents are used outdoor for a long time, change in quality takes place in the coupling agents themselves, bringing about deterioration of the properties of the composite materials. In this study, glass surface was treated by plasma to examine the effect of dry interface treatment without coupling agent. It was identified that the optimum parameters for the best wettability of the samples at the time of generation of plasma were oxygen atmosphere, 0.1 torr of system pressure, 100 W of discharge power, and 3 minutes of discharge time. Also, the surface resistance rate and dielectric property were improved.