• Journal of Ocean Engineering and Technology
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• v.5 no.2
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• pp.207-207
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• 1991

The crack length measurements by electrical potential(EP) method for 1% Cr-Mo-V and 12%Cr steel of 0.5T-CT specimen were performed at $500^{\circ}C, 600^{\circ}C 700^{\circ}C$, and an applicability of stress intensity factor($K_I$), net section stress($\sigma_{net}$), $C^*$-ingegral and $C_t$ parameter was studied to measure creep crack growth rate(da/dt) with side groove and without side groove under static and cyclic loading condition. The experimental result could be summarized as follows: 1) Crack measurement by EP method was available and coincided with the Johnson,s analytical equation. 2) da/dt by $K_I$ and $\sigma_{net}$ was not adequate because of the wide scatter band according to load and temperature, but $C^*$-integral, except for transition region, was adequate. 3) $C_t$ parameter showed the best fitted line through total creep region without relating with both temperature and load condition. 4) Under the cyclic loading condition, $C_t$ parameter was proper to extimate da/dt. And it was shown that da/dt for 1% Cr-Mo V steel under the static condition(R=1) was 1.16 times faster than the case under cyclic loading(R=0), and for 12% Cr steel, 1.43 times.

• Journal of Ocean Engineering and Technology
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• v.5 no.2
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• pp.67-75
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• 1991

The crack length measurements by electrical potential(EP) method for 1% Cr-Mo-V and 12%Cr steel of 0.5T-CT specimen were performed at $500^{\circ}C, 600^{\circ}C 700^{\circ}C$, and an applicability of stress intensity factor($K_I$), net section stress($\sigma_{net}$), $C^*$-ingegral and $C_t$ parameter was studied to measure creep crack growth rate(da/dt) with side groove and without side groove under static and cyclic loading condition. The experimental result could be summarized as follows: 1) Crack measurement by EP method was available and coincided with the Johnson, s analytical equation. 2) da/dt by $K_I$ and $\sigma_{net}$ was not adequate because of the wide scatter band according to load and temperature, but $C^*$-integral, except for transition region, was adequate. 3) $C_t$ parameter showed the best fitted line through total creep region without relating with both temperature and load condition. 4) Under the cyclic loading condition, $C_t$ parameter was proper to extimate da/dt. And it was shown that da/dt for 1% Cr-Mo V steel under the static condition(R=1) was 1.16 times faster than the case under cyclic loading(R=0), and for 12% Cr steel, 1.43 times.

• Korean Journal of Metals and Materials
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• v.47 no.2
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• pp.129-137
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• 2009

Corrosion behaviors of TiN coated dental casting alloys have been researched by using various electrochemical methods. Three casting alloys (Alloy 1: 63Co-27Cr-5.5Mo, Alloy 2: 63Ni-16Cr-5Mo, Alloy 3: 63Co-30Cr-5Mo) were prepared for fabricating partial denture frameworks with various casting methods; centrifugal casting(CF), high frequency induction casting(HFI) and vacuum pressure casting(VP). The specimens were coated with TiN film by RF-magnetron sputtering method. The corrosion behaviors were investigated using potentiostat (EG&G Co, 263A. USA) in 0.9% NaCl solution at $36.5{\pm}1^{\circ}C$. The corrosion morphologies were analyzed using FE-SEM and EDX. Alloy 1 and Alloy 2 showed the ${\alpha}-Co$ and ${\varepsilon}-Co$ phase on the matrix, and it was disappeared in case of TiN coated Alloy 1 and 2. In the Alloy 3, $Ni_2Cr$ second phases were appeared at matrix. Corrosion potentials of TiN coated alloy were higher than that of non-coated alloy, but current density at passive region of TiN coated alloy was lower than that of non-coated alloy. Pitting corrosion resistances were increased in the order of centrifugal casting, high frequency induction casting and vacuum pressure casting method from cyclic potentiodynamic polarization test.

• Journal of Korea Foundry Society
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• v.16 no.2
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• pp.124-131
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• 1996

High temperature properties such as hot hardness and thermal fatigue resistance of high speed steel roll of hot finishing mill have been investigated. Two kinds of roll having compositions, Fe-1.75%C-5.9%Cr-1.74%Mo-4.94%V-2.03%W(A specimen) and Fe-2.27%C-8.86%Cr-2.91%Mo-3.92%V-1.86%W(B specimen)were prepared for investigating the microstructure and crack propagation mode. A specimen has greater amounts of $M_7C_3$ type carbides and less amounts of MC type carbides in comparison with B specimen. Hot hardness showed sudden decrease over $400^{\circ}C$, resulting in the hardness decrease of 50% at the temperature of $600^{\circ}C$, and showed little variation with time at $500^{\circ}C$ and $800^{\circ}C$. Thermal crack was developed at $550^{\circ}C$ in A specimen and $600^{\circ}C$ in B specimen.

• Transactions of the Korean Society of Mechanical Engineers
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• v.8 no.2
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• pp.97-103
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• 1984

Post weld heat treatment(PWHT) of weldment of the low alloy steel is carried out to remove residual stress existing in weldment and to improve fracture toughness, but it is often observed that there occurs grain boundary failure and that fracture toughness decreases in weld heat affected zone(HAZ)because of PWHT. In this paper, the effect of heating rate and holding time of PWHT on fracture toughness were evaluated by crack opening displacement (CDD)test and micro-hardness test under the constant stress simulated residual stress in HAZ of Cr-Mo steel. The experimental results are as follow; (1)Transition temperature of weld HAZ after PWHT was dependent upon heating rate greater than holding time, and fracture toughness was decreased with an increase of the heating rate. (2)Softening ration of the notch tip was increased with holding time within one hour and saturated after one hour, but under applied stress it was increasing continuously. (3)The average hardness value in weld HAZ was increased with heating rate of PWHT.

• Bulletin of the Korean Chemical Society
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• v.18 no.10
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• pp.1061-1066
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• 1997

The complexes M(CO)4-1,2-(PPh2)2-1,2-C2B10H10 (M=Cr 2a, Mo 2b, W 2c) have been prepared in good yields from readily available bis-diphenylphosphino-o-carboranyl ligand, closo-1,2-(PPh2)2-1,2-C2B10H10 (1), by direct reaction with Group Ⅵ metal carbonyls. The infrared spectra of the complexes indicate that there is an octahedral disposition of chelate bis-diphenylphosphino-o-carboranyl ligand around the metal atom. The crystal structure of 2a was determined by X-ray diffraction. Complex 2a crystallizes in the monoclinic space group P21/n with cell parameters a = 12.2360(7), b = 17.156(1), c = 16.2040(6) Å, V = 3354.1(3) Å3, and Z =4. Of the reflections measured a total of 2514 unique reflections with F2 > 3σ(F2) was used during subsequent structure refinement. Refinement converged to R1 = 0.066 and R2 = 0.071. Structural studies showed that the chromium atom had a slightly distorted pseudo-octahedral configuration about the metal center with two phosphine groups of o-carborane occupying the equatorial plane cis-orientation to each other. These metal carbonyl complexes are rapidly converted to the corresponding metal carbene complexes, [(CO)3M=C(OCH3)(CH3)]-1,2-(PPh2)2-1,2-C2B10H10 (M= Cr 3a, Mo 3b, W 3c), via alkylation with methyllithium followed by O-methylation with CF3SO3CH3.

• Corrosion Science and Technology
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• v.10 no.2
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• pp.60-64
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• 2011

Lean duplex stainless steels have been developed in Korea for the purpose of being used in the seawater systems of industry. There are also many important seawater systems in nuclear power plants. These systems supply seawater to cooling water condenser tubes, heat exchanger tubes, related pipes and chlorine injection systems. The flow velocity of some part of seawater systems in nuclear power plants is high and damages of components from corrosion are severe. The considered lean duplex stainless steels are STS329LD (20.3Cr-2.2Ni-1.4Mo) and STS329J3L (22.4Cr-5.7Ni-3Mo) and PRENs of them are 29.4 and 37.3 respectively. Physical, mechanical and micro-structural properties of them are evaluated, and electrochemical corrosion resistance is measured quantitatively in NaCl solution. Critical Pitting Temperatures (CPT)s are measured on these alloys and pit depths are evaluated using laser microscope. Long period field tests on these alloys are now being performed, and some results are going to be presented in the following study.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.24 no.3 s.174
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• pp.794-802
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• 2000

Since the examination of CTOD problem revealed that the discrepancy among CTOD's was a matte., of definition, the relationships among parameters based on different definitions have been studied Particularly, the relationship between $\sigma$BS R-curve based on BS 7448 and R-curve based on the recently introduced $\sigma$5 parameter was investigated in this research. For the comparison, compact tension specimens of used 1Cr-0.5Mo steel, heat treated 1Cr-0.5Mo steel to mimic the new one, A12024-T6, and A12024-T351 were prepared and tested. Consequently, the relationship between $\sigma$5 and $\sigma$BS R-curves for tested materials were established by shifting the rotational center which could determined by rotation factor and ligament size.

• Korean Journal of Crystallography
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• v.6 no.2
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• pp.75-79
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• 1995

The crystal structure of Tris(ethylenediamine)nickel(II)Chromate has been determined by X-ray crystallography. Crystal data : a=9.027(2)Å, c=9.751(5)Å이며, Z=2, V=687.9(2)Å3, Dc=1.714gcm-3, μ=21.635-1. The intensity were collected with Mo-Kα radiation (λ=0.7107Å) on an automatic four-circle diffractometer with a graphite monochromator. The structure was solved by Patterson method and refined by full matrix least-square methods using unit weights. The final R and S values were R=0.029, Rw=032, Rall=0.049 andS=0.018 for 342 observed reflections. The chromate ions are located at position of point of point symmetry 32 and their oxygens are sixfold disodered in an unusual way. Extensive strong hydrogen bonds between complex cations and chromatic anions are found in axial and equatorial directions.

• Transactions of the Korean Society of Mechanical Engineers
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• v.13 no.5
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• pp.921-927
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• 1989

One of the most important problems in recent life prediction is to introduce the degradation effects into life prediction procedure. In the present paper, the effect of the material degradation on the fatigue surface crack growth and fatigue life prediction in a 2 1/4 Cr-1Mo steel were investigated. The 2 1/4 Cr-1Mo steel has been used in a plant having operated for over 60000hours and subjected to material degradation due to temper-embitterment. A Monte-Carlo simulation was made on the basis of the data obtained in the experiment in order to determine the P-S-N diagrams of surface crack growth for the degraded and recovered steels.