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Analysis of Long-term Stability of Direct Methanol Fuel Cell and Investigation of the Methods to Improve its Performance (직접메탄올 연료전지의 장기운전 특성 분석 및 성능향상 연구)

  • Lee, Hyun-Sook;Bae, Byung-Chan;Lee, Jae-Young;Im, Tae-Hun;Ha, Heung-Yong;Hong, Seong-Ahn
    • Transactions of the Korean hydrogen and new energy society
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    • v.16 no.1
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    • pp.31-39
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    • 2005
  • Direct methanol fuel cell (DMFC) is considered as a candidate for portable power sources, that could overcome the disadvantages of lithium battery. But in order to attain commercial viability the long term stability of the DMFC should be achieved. Understanding the long-term behavior of membrane-electrode assembly (MEA) is a prerequisite to this purpose and the optimization of the MEA is also needed. In this study we have investigated the changes in performance and electrochemical properties of the MEA during extended operation and the effects of heat treatment of MEA on the long-term performance. The MEAs have been treated in an autoclave with saturated water vapor at 120$^{\circ}C$, vacuum oven at 140$^{\circ}C$ and boiling in organic solvents. The autoclaved MEA was found to be have the best long term performance. The on-off operation mode also increased the performance probably due to effective removal of products from the electrodes. Physical and electrochemical analyses using a scanning electron microscope, impedance analyser and half-cell technique have been done to characterize the MEAs.

Photolysis Improvement of Toluene in 50%TiO2/6%WO3 Sol Solutions Sensitized by Acetone (50%TiO2/6%WO3 졸 용액에서의 톨루엔 처리에 대한 아세톤의 광활성 증가효과)

  • Shin, Hye-Seung;Kim, Jae-Hyoun
    • Journal of Environmental Health Sciences
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    • v.38 no.3
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    • pp.261-268
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    • 2012
  • Objectives: The photocatalytic degradation of toluene in a batch mode photoreactor for the purpose of the hazardous waste treatment was investigated. Methods: Kinetic experiments using a low pressure mercury lamp (Lambda Scientific Pty Ltd, 50 Watt) emitting both UV and visible light were performed at $31^{\circ}C$ over toluene concentrations ranging from 10 to 50 mg/l in water with $50%TiO_2/6%WO_3$ (TW) concentration of 1 g/l at a pH of 6. Results: Kinetic studies showed that $50%TiO_2/6%WO_3$ (TW) photocatalyst was highly active in toluene degradation; we observed that 99% of the pollutant was degraded after six hours under visible irradiation; furthermore, we observed that adsorption onto TW catalyst was responsible for the decrease of toluene with pseudo-first order kinetics. It was also found that oxygen as a radical source in the sol medium played a significant role in affecting the photodegradation of toluene, especially with a two-fold elevation. This increase was achieved by a more than four-fold elevation of the photodegradation of toluene in the presence of acetone than without, presumably via an energy transfer mechanism. Conclusions: We concluded that photodegradation in acetone and oxygen molecules along with TW was an effective method for the removal of toluene from wastewater.

A 100MHz DC-DC Converter Using Integrated Inductor and Capacitor as a Power Module for SoC Power Management (SoC 전원 관리를 위한 인덕터와 커패시터 내장형 100MHz DC-DC 부스트 변환기)

  • Lee, Min-Woo;Kim, Hyoung-Joong;Roh, Jeong-Jin
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.46 no.8
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    • pp.31-40
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    • 2009
  • This paper presents a design of a high performance DC-DC boost converter as a power module for SOC designs. It applied to this chip that reduced inductor and capacitor for integrating on a chip, and it operates with a switching frequency of 100MHz. It has reliability and stability in high switching frequency. The controller of DC-DC boost converter is designed by voltage-mode control method and compensated properly. The designed DC-DC converter is fabricated with the 0.18${\mu}m$ standard CMOS technology with a thick-gate oxide option. The overall die size is 8.14$mm^2$, and controller size is 1.15$mm^2$. The converter has the maximum efficiency over 76% for the output voltage of 4V and load current larger 300mA. The load regulation is 0.012% (0.5mV) for the load current change of 100mA.

The comparative effectiveness and evaluation study of user groups of the various web search tools (다양한 형태의 웹 탐색도구의 이용자집단간 비교효용성 및 평가에 관한 연구)

  • 박일종;윤명순
    • Journal of Korean Library and Information Science Society
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    • v.31 no.1
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    • pp.87-114
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    • 2000
  • The purpose of this study is offering appropriate system and training program to helf the system designer and the trainer in addition to analyze information use behavior about the web search tools and evaluate the estimated system by user groups. The results of the study are as follows $\circledS1$ It is desirable to consider age than other demographic variables in the case of web search tool. $\circledS2$ It is desirable to design Directory Search Tool in the case of web search tool which serves the student user group. $\circledS3$ An Intelligent Search Tool is more appropriate for the students who are using keyword search tool than any other tools. $\circledS4$ A discussion about standard classification of the web information should be accomplished soon because users feel confused in using web search tools due t o absence of standard mode of classification about classified item. $\circledS5$ Librarians need the cognition about data on internet s a source of information and need positive service and user training program about these information because student users hardly get help from librarians or library orientation for learning method to use web search tool. $\circledS6$ Internet use experience and years of computer use had effect on their use ability when using web search tool, whereas computer use experience, library use experience and Online Public Access Catalogs (OPAC) use experience had no effect on it. Especially, OPAC use experience had no effect on use ability of web search tool of student user group because student user groups had no information about internet and web search tool and they did not recognized the difference about search method between web search tool and OPAC. $\circledS7$In the case of web search tool, it si important to index the increasing web resource automatically by a searching robot. But in the case of student users, web search tool is much more needed to index by index expert due to the absence of ability about selecting and combining keyword.

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Time series analysis of patients seeking orthodontic treatment at Seoul National University Dental Hospital over the past decade

  • Lim, Hyun-Woo;Park, Ji-Hoon;Park, Hyun-Hee;Lee, Shin-Jae
    • The korean journal of orthodontics
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    • v.47 no.5
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    • pp.298-305
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    • 2017
  • Objective: This paper describes changes in the characteristics of patients seeking orthodontic treatment over the past decade and the treatment they received, to identify any seasonal variations or trends. Methods: This single-center retrospective cohort study included all patients who presented to Seoul National University Dental Hospital for orthodontic diagnosis and treatment between January 1, 2005 and December 31, 2015. The study analyzed a set of heterogeneous variables grouped into the following categories: demographic (age, gender, and address), clinical (Angle Classification, anomaly, mode of orthodontic treatment, removable appliances for Phase 1 treatment, fixed appliances for Phase 2 treatment, orthognathic surgery, extraction, mini-plate, mini-implant, and patient transfer) and time-related variables (date of first visit and orthodontic treatment time). Time series analysis was applied to each variable. Results: The sample included 14,510 patients with a median age of 19.5 years. The number of patients and their ages demonstrated a clear seasonal variation, which peaked in the summer and winter. Increasing trends were observed for the proportion of male patients, use of non-extraction treatment modality, use of ceramic brackets, patients from provinces outside the Seoul region at large, patients transferred from private practitioners, and patients who underwent orthognathic surgery performed by university surgeons. Decreasing trends included the use of metal brackets and orthodontic treatment time. Conclusions: Time series analysis revealed a seasonal variation in some characteristics, and several variables showed changing trends over the past decade.

Fermentative Hydrogen Production from the Pretreated Food-Processing Waste and Sewage Sludge using Chemical/Ultra-Sonication (두부제조폐기물과 하수슬러지의 화학/초음파 전처리에 의한 가용화 및 혐기발효 수소생산)

  • Kim, Mi-Sun;Lee, Dong-Yeol;Kim, Dong-Hun;Kim, Ok-Sun;Lim, So-Yung
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.6
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    • pp.580-586
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    • 2010
  • Acid and alkali pretreatments were applied to tofu processing waste (TPW) to increase the solubility of ingredients in TPW. Pretreatment at 1.0% of HCl and 2.5% of NaOH condition resulted in the increase of SCOD concentration from 3.2 g COD/L to 27 g COD/L and 33 g COD/L, respectively. The acid and alkali-pretreated TPW was studied for its fermentative $H_2$ production capacity in batch mode using a thermophillic mixed culture. Alkali pretreatment on presence of 2.5% NaOH exhibited more soluble portion released compared to acid pretreatment using HCl, however the $H_2$ production from acid pretreated TPW was better than alkali-pretreated TPW probably due to the sodium inhibition on microbial activity. In addition, sewage sludge was externally added to the acid-pretreated (1.0% HCl) TPW by 20% (on volume basis). Average H2 production rate was increased from 31 to 78 ml/L-broth/hr, and it was attributed to the high buffer capacity and abundant nutrients especially divalent cation in sewage sludge.

Correlationship with Wedding Dress Image Preference and Self Image of Female University Students (여대생들의 웨딩드레스 이미지 선호도와 자아이미지)

  • 신은정;권혜숙
    • Journal of the Korean Society of Costume
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    • v.52 no.5
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    • pp.31-45
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    • 2002
  • In this paper. the focus is laid on identifying preferred wedding dress image and its co-relationship with self image of female university students. the biggest potential customer group in the industry. As for the research method. it conducted both review of literature and empirical research method. Through the former approach, four main research questions were derived : 1) What is the preferred wedding dress image of female university students\ulcorner 2) What is the relationship between real self-image and preferred wedding dress image\ulcorner and 3) that between ideal self-image and preferred wedding dress image\ulcorner 4)What is the relationship between the consistency level of the two self-images and preferred wedding dress image\ulcorner In the empirical mode of research, 404 surveys were counted in the final analysis among 450 questionnaires completed by female undergraduate students in Seoul and Chun-an city. Collected data analyzed using factor analysis. frequency analysis. descriptive analysis. scheffe test. multiple-regression analysis and t-test. Results are as follows: first, the sophisticated image was most preferred among female students, followed by elegant splendor. lovable and chaste, feminine and decorative, and characteristic and sexy image. This result indicates how wedding dress trend has a keen sensibility to general fashion trend just like the trend of outfits for everyday life. Secondly, the research results indicated consistent level of co-relationship among the real and ideal self-image and the preference of wedding dress image. And the last the level of consistence between the ideal self-image and the real self-image directly related to the preference level of wedding dress image, showing almost no significance.

Integrity Evaluation of Railway Bogie Using Infrared Thermography Technique (적외선 열화상 기술을 이용한 철도차량 대차 건전성 평가)

  • Kim, Jeong-Guk
    • Journal of the Korean Society for Nondestructive Testing
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    • v.31 no.2
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    • pp.144-149
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    • 2011
  • The lock-in thermography was employed to evaluate the integrity of railway bogies. Prior to the actual application on railway bogies, in order to assess the detectability of known flaws, the calibration reference panel was prepared with various dimensions of artificial flaws. The panel was composed of structural steel, which was the same material with actual bogies. Through lock-in thermography evaluation, the optimal frequency of heat source was determined for the best flaw detection. Based on the defects information, the actual defect assessments on railway bogie were conducted with different types of railway bogies, which were used for the current operation. In summary, the defect assessment results with thermography method showed a good agreement as compared with the conventional inspection techniques. Moreover, it was found that the novel infrared thermography technique could be an effective way for the inspection and the detection of surface defects on bogies since the infrared thermography method provided rapid and non-contact mode for the investigation of railway bogies.

DLC Structure Layer for Piezoelectric MEMS Switch (압전 MEMS 스위치 구현을 위한 DLC 구조층에 관한 연구)

  • Hwang, Hyun-Suk;Lee, Kyong-Gun;Yu, Young-Sik;Lim, Yun-Sik;Song, Woo-Chang
    • Journal of Satellite, Information and Communications
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    • v.6 no.1
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    • pp.28-31
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    • 2011
  • In this paper, a new set of structural and sacrificial material that is diamond like carbon (DLC)/photoresist for high performance piezoelectric RF-MEMS switches which are actuated in d33 mode is suggested. To avoid curing problem of photoresist sacrificial layer, DLC structure layer is deposited at room temperature by radio frequency plasma enhanced chemical vapor deposition (RF-PECVD) method. And lead zirconate titanate (PZT) piezoelectric layer is deposited on structure layer directly at room temperature by rf magnetron sputtering system and crystallized by rapid thermal annealing (RTA) equipment. Particular attention is paid to the annealing of PZT film in order to crystallize into perovskite and the variation of mechanical properties of DLC layer as a function of annealing temperature. The DLC layer shows good performance for structure layer in aspect to Young's modulus and hardness. The fabrication becomes much simpler and cheaper with use of a photoresist.

Elliptical Clustering with Incremental Growth and its Application to Skin Color Region Segmentation (점증적으로 증가하는 타원형 군집화 : 피부색 영역 검출에의 적용)

  • Lee Kyoung-Mi
    • Journal of KIISE:Software and Applications
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    • v.31 no.9
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    • pp.1161-1170
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    • 2004
  • This paper proposes to segment skin color areas using a clustering algorithm. Most of previously proposed clustering algorithms have some difficulties, since they generally detect hyperspherical clusters, run in a batch mode, and predefine a number of clusters. In this paper, we use a well-known elliptical clustering algorithm, an EM algorithm, and modify it to learn on-line and find automatically the number of clusters, called to an EAM algorithm. The effectiveness of the EAM algorithm is demonstrated on a task of skin color region segmentation. Experimental results present the EAM algorithm automatically finds a right number of clusters in a given image without any information on the number. Comparing with the EM algorithm, we achieved better segmentation results with the EAM algorithm. Successful results were achieved to detect and segment skin color regions using a conditional probability on a region. Also, we applied to classify images with persons and got good classification results.