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High capacity polymer for nickel determination in environmental samples

  • Panahi, Homayon Ahmad;Feizbakhsh, Alireza;Dadjoo, Fatemeh;Moniri, Elham
    • Advances in environmental research
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    • v.2 no.4
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    • pp.309-321
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    • 2013
  • High AA new high capacity sorbent for preconcentration and determination of nickel in environmental samples was synthesized. The sorbent was synthesized by copolymerization of allyl glaycidyl ether / imminodiacetic acid with N,N-dimethylacrylamide as functional monomers in the presence of N,N-bismethylenacryl amid as cross linker and characterized by Fourier transform infra red spectroscopy, elemental analysis, thermogravimetric analysis and scanning electron microscopy. A recovery of 93.6% was obtained for the metal ion with 0.1 M, sulfuric acid as the eluting agent. The sorption capacity of the functionalized sorbent was 55.9 $mgg^{-1}$. The equilibrium sorption data of Ni(II) on polymeric sorbent were analyzed using Langmuir, Freundlich, Temkin and Redlich.Peterson models. Based on equilibrium adsorption data the Langmuir, Freundlich and Temkin constants were determined 0.87 (L mg-1), 25.87 ($mgg^{-1}$) $(Lmg^{-1})^{1/n}$ and 171.4 ($Jmol^{-1}$) respectively at pH 4.5 and $20^{\circ}C$.

Optimization Design of Stainless Steel Stamping Multistage Pump Based on Orthogonal Test

  • Weidong, Shi;Chuan, Wang;Weigang, Lu;Ling, Zhou;Li, Zhang
    • International Journal of Fluid Machinery and Systems
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    • v.3 no.4
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    • pp.309-314
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    • 2010
  • Stainless steel stamping multistage pump has become the mainstream of civil multi-stage pump. Combined with the technological features of stamping and welding pump, the studies of design for hydraulic parts of pump were come out. An $L_{18}$$3^7$)orthogonal experiment was designed with seven factors and three values including blade inlet angle, impeller outer diameter, guide vane blade number, etc. 18 plans were designed. The two stage of whole flow field on stainless steel stamping multistage pump at design point for design was simulated by CFD. According to the test result and optimization design with experimental research, the trends of main parameters which affect hydraulic performance were got. After being manufactured and tested, the efficiency of the optimal model pump reaches 61.36% and the single head is more than 4.8 m. Compared with the standard efficiency of 53%, the design of the stainless steel stamping pump is successful. The result would be instructive to the design of Stainless steel stamping multistage pump designed by the impeller head maximum approach.

Dielectric Properties of Complex Microstructure for High Strength LTCC Material (고강도 LTCC 소재을 위한 복합구조의 유전특성)

  • Kim, Jin-Ho;Hwang, Seong-Jin;Sung, Woo-Kyung;Kim, Hyung-Sun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.309-309
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    • 2007
  • The LTCCs (low-temperature co-fired ceramics) are very important for electronic industry to build smaller RF modules and to fulfill the necessity for miniaturization of devices in wireless communication industry. The dielectric materials with sintering temperature $T_{sint}$<$900^{\circ}C$ are required. In this study, we investigated with glass-ceramic composition, which was crystallized with two crystals. The microstructure, crystal phases, thermal and mechanical properties, and dielectric properties of the composites were investigated using FE-SEM, XRD, TG-DTA, 4-point bending strength test and LCR measurement. The starting temperature for densification of a sintered body was at $779{\sim}844^{\circ}C$ and the glass frits were formatted to the crystal phases, $CaAl_2Si_2O_8$(anorthite) and $CaMgSi_O_6$(diopside), at sintering temperature. The sintered bodies exhibited applicable dielectric properties, namely 6-9 for ${\varepsilon}_r$. The results suggest that the glass-ceramic composite would be potentially possible to application of low dielectric L TCC materials.

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Synthesis and characterization of polyamide thin-film nanocomposite membrane containing ZnO nanoparticles

  • AL-Hobaib, A.S.;El Ghoul, Jaber;El Mir, Lassaad
    • Membrane and Water Treatment
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    • v.6 no.4
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    • pp.309-321
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    • 2015
  • We report in this study the synthesis of mixed matrix reverse osmosis membranes by interfacial polymerization (IP) of thin film nanocomposite (TFNC) on porous polysulfone supports (PS). This paper investigates the synthesis of ZnO nanoparticles (NPs) using the sol-gel processing technique and evaluates the performance of mixed matrix membranes reached by these aerogel NPs. Aqueous m-phenyl diamine (MPD) and organic trimesoyl chloride (TMC)-NPs mixture solutions were used in the IP process. The reaction of MPD and TMC at the interface of PS substrates resulted in the formation of the thin film composite (TFC). NPs of ZnO with a size of about 25 nm were used for the fabrication of the TFNC membranes. These membranes were characterized and evaluated in comparison with neat TFC ones. Their performances were evaluated based on the water permeability and salt rejection. Experimental results indicated that the NPs improved membrane performance under optimal concentration of NPs. By changing the content of the filler, better hydrophilicity was obtained; the contact angle was decreased from $74^{\circ}$ to $32^{\circ}$. Also, the permeate water flux was increased from 26 to 49 L/m2.h when the content of NPs is 0.1 (wt.%) with the maintaining of lower salt passage of 1%.

Mechanical Properties and Cross-sectional Surface Evaluation of Dental Ceramic Abutment (치과용 세라믹 임플란트 지대주의 기계적 특성 및 절단면 평가)

  • Hwang, Jun Ho;Kwon, Sung-Min;Choi, Sung Gi;Sung, Mi Ae;Lee, Kyu-Bok
    • Journal of the Korean institute of surface engineering
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    • v.51 no.5
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    • pp.309-315
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    • 2018
  • The purpose of this study is to assess the mechanical properties of the ceramic abutment with washer. In this study, ceramic abutment were used, tested with $30^{\circ}$ compression load, shear fatigue, adaptation accuracy test(rotation angle, contact interval), removal torque force test, torsional breaking force test. The $30^{\circ}$ compression load was 729 N, the shear fatigue load was 275 N, adaptation accuracy test of rotation angle was within $3^{\circ}$, contact interval within $10{\mu}m$, and removal torque force test value is $18.88N{\cdot}cm$, torsional breaking force test value is $35.52N{\cdot}cm$. Ceramic abutment with a washer fitted have sufficient mechanical strength and may be substituted for titanium abutment.

Comparison of Antioxidant and yield Properties of of Adzuki Bean (Vigna angularis L.) Cultivars Under Different Air Temperatures and Sunshine Hours

  • Jisun Jang;Seon-Min Oh;Kwonseo Park;Youngsik Kang;Jeom-Sig Lee;Suk-Bo Song;Tugsang Yun;Jae Yoon Kim
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2022.10a
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    • pp.309-309
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    • 2022
  • This study investigated the antioxidant and yield properties of eight adzuki bean (Vigna angularis) cultivars under different mean temperature and sunshine hours in 2020 and 2021. The mean temperature in 2020 compared to 2021, which was normal, were lower during the pod extension and grain filling period. In addition, due to frequent rainfall during the vegetative perio d in 2020, there were fewer hours of sunshine compared to 2021. The Adzuki Bean yield in 2020 was about 13% lower than that in 2021 due to the decreased number of pods per plant and 100 seeds weight. The stability of yields was higher in 'Hongda' and 'Hongjin' than in 'Arari', which is the most cultivated in Korea. Also, the yields of these varieties were all higher than those of 'Arari' varieties for two years. Compared to 2021, in 2020, when weather conditions were not favorable, both antioxidant components and activity were higher. The cultivar 'Hongda' was a higher antioxidant component and activity than others for two years. The results suggested that the antioxidant component and activity were good in 2020 with about 13% decrease in yield compared to a normal year in 2021 due to mean temperature and sunshine hours.

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Radiographic Parameters of Segmental Instability in Lumbar Spine Using Kinetic MRI

  • Jang, Se-Youn;Kong, Min-Ho;Hymanson, Henry J.;Jin, Tae-Kyung;Song, Kwan-Young;Wang, Jeffrey C.
    • Journal of Korean Neurosurgical Society
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    • v.45 no.1
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    • pp.24-31
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    • 2009
  • Objective : To investigate the effectiveness of radiographic parameters on segmental instability in the lumbar spine using Kinetic magnetic resonance imaging (MRI). Methods : Segmental motion, defined as excessive (more than 3 mm) translational motion from flexion to extension, was investigated in 309 subjects (927 segments) using Kinetic MRI. Radiographic parameters which can help indicate segmental instability include disc degeneration (DD), facet joint osteoarthritis (FJO), and ligament flavum hypertrophy (LFH). These three radiographic parameters were simultaneously evaluated, and the combinations corresponding to significant segmental instability at each level were determined. Results : The overall incidence of segmental instability was 10.5% at L3-L4, 16.5% at L4-L5, and 7.3% at L5-S1. DD and LFH at L3-L4 and FJO and LFH at L4-L5 were individually associated with segmental instability (p<0.05). At L4-L5, the following combinations had a higher incidence of segmental instability (p<0.05) when compared to other segments : (1) Grade IV DD with grade 3 FJO, (2) Grade 2 or 3 FJO with the presence of LFH, and (3) Grade IV DD with the presence of LFH. At L5-S1, the group with Grade III disc and Grade 3 FJO had a higher incidence of segmental instability than the group with Grade I or II DD and Grade 1 FJO. Conclusion : This study showed that the presences of either Grade IV DD or grade 3 FJO with LFH at L4-L5 were good indicators for segmental instability. Therefore, using these parameters simultaneously in patients with segmental instability would be useful for determining candidacy for surgical treatment.

The Effects of Velocity and Concentration in the Oxidizer of Heptane Pool Fires on the Flame Stability (헵탄 풀화재 화염안정성에 관한 산화제 유속 및 농도 효과)

  • Jeong, Tae-Hee;Lee, Eui-Ju
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.3
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    • pp.309-314
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    • 2012
  • Flame flickering occurs mainly because of the buoyancy force for pool fires under ambient air. The cup-burner flame was used for experimental investigation of the effect of the oxidizer velocity on the gravitational instability. The results showed that the flickering frequency decreased with increasing oxidizer velocity. The frequency-buoyancy relation with nondimensional variables coincided with that of the buoyant flume and pool fires when the characteristic velocity was defined as the difference between the fuel and oxidizer velocities, which implies that the origin of the gravitational instability is the Kelvin-Helmholtz instability in the shear layer. The effect of the oxidizer composition on the instability was also examined through nitrogen dilution in the oxidizer stream. As the concentration of inert gas increased, the length of the blue flame increased and lift-off behavior was observed. The oscillation frequency was independent of the dilution ratio, but was related to the local flame structure.

The Effect of Asymmetric Lower-Extremity Muscle Force of Elementary Students on Dynamic Balance during Walking (하지 근력의 좌우 비대칭성이 초등학생의 보행 동적안정성에 미치는 영향)

  • Kim, Gun-Soo;Chae, Woen-Sik;Yoon, Chang-Jin;Lee, Haeng-Seob;Kang, Nyeon-Ju;Kim, Dong-Soo
    • Korean Journal of Applied Biomechanics
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    • v.21 no.3
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    • pp.309-315
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    • 2011
  • The purpose of this study was to evaluate the effect of asymmetric muscle force in lower extremity on dynamic balance during walking. Sixteen elementary students(age: 12.3${\pm}$0.7 yrs, height: 149.4${\pm}$9.7 cm, weight 40.6${\pm}$7.8 kg) who have no musculoskeletal disorder were recruited as the subjects. Temporal parameters, M-L inclination angle of XCoM-CoP, M-L and A-P CoP, loading rate, and decay rate were determined for each trial. For each dependent variable, a independent-sample t-test was performed to test if significant difference existed between each conditions(p<.05). The displacement of antero-posterior COP during RTO-LHC1 in SG was siginificantly smaller than corresponding value in AG. In contrast, the displacement of medio-lateral COP during RTO-LHC1 in SG was greater than those of AG. It seems that imbalance of muscle force may result in increasing the medio-lateral stance in order to minimize the instability. We found that the asymmetric muscle force in the lower extremity may be a reason for the awkward control of impact force.

Topology Optimization of Offshore Wind-Power Turbine Substructure Using 3D Solid-Element Model (3 차원 고체요소모델을 활용한 해상풍력터빈 하부구조의 위상최적화)

  • Kim, Won Cheol;Chung, Tae Jin
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.3
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    • pp.309-314
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    • 2014
  • The structural layout of mechanical and civil structures is commonly obtained using conventional methods. For example, the shape of structures such as electric transmission towers and offshore substructures can be generated systematically. However, with rapid advancements in computer graphic technology, advanced structural analyses and optimum design technologies have been implemented. In this study, the structural shape of a jacket substructure for an offshore wind turbine is investigated using a topology optimization technique. The structure is subjected to multiple loads that are intended to simulate the loading conditions during actual operation. The optimization objective function is defined as one that ensures compliance of the structure under the given boundary conditions. Optimization is carried out with constraints on the natural frequency in addition to the volume constraint. The result of a first step model provides quick insights into the optimum layout for the second step structure. Subsequently, a 3D model in the form of the frustum of a quadrilateral pyramid is developed through topology optimization.