• Title/Summary/Keyword: 2D material

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Effect of Processing Parameters on the Microstructure and Band Gap Energy of 1D-Na2Ti6O13 (1D-Na2Ti6O13 합성 변수에 따른 미세구조 및 밴드 갭 에너지 변화)

  • Yun, Kang-Seop;Ku, Hye-Kyung;Kang, Woo-Seung;Kim, Sun-Jae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.8
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    • pp.664-669
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    • 2012
  • Nano-structured one-dimensional $Na_2Ti_6O_{13}$ particles were synthesized by a molten salt process. Effects of processing parameters on the microstructure and band gap energy of the $Na_2Ti_6O_{13}$ powder were studied in this paper. For the synthesis of the $Na_2Ti_6O_{13}$ particles, two different raw materials of tubular shaped Na-titanate (Na-TiNT) and spherical shaped $TiO_2$ were utilized. Synthesizing with the raw material of Na-TiNT, around 70nm thick 1D-$Na_2Ti_6O_{13}$ with the bandgap energy of 3.5 eV was obtained at $810^{\circ}C$. Below $810^{\circ}C$ or without the presence of NaCl, 1D-$Na_2Ti_6O_{13}$ was in a relatively short in length and agglomerated state. With the processing temperature increased, the thickness of the 1D-$Na_2Ti_6O_{13}$ was also observed to be increased. On the other hand, when $TiO_2$ was employed as a raw material, the mixed amount of $Na_2CO_3$ played an important role in transforming the morphology and phase of the raw material, affecting the bandgap energy of the synthesized product. Specific surface area of the synthesized 1D-$Na_2Ti_6O_{13}$ was significantly affected by the raw and mixed materials as well as processing temperature. When Na-TiNT was processed at $810^{\circ}C$ with NaCl, the specific surface area of the 1D-$Na_2Ti_6O_{13}$ showed the best value of 30.63 $m^2/g$.

Fabrication of 2-D photonic crystal with holographic lithography (홀로그램피 리소그래피 방법을 이용한 2차원 포토닉 크리스탈 제작)

  • Ju, Long-Yun;Nam, Ki-Hyun;Kim, Hyun-Koo;Choi, Hyuk;Chung, Hong-Bay
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.162-163
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    • 2007
  • In this paper, we fabrication of 2-D photonic crytal using holographic lithography. We used Ag doped chalcogenide AsGeSeS film and He-Ne (632.8nm) (P:P) Polarized laser beam. The thickness of Ag thin film was varied from 60nm and the thickness of chalcogenide thin film was varied from 2um. Frist, holographic lithography with 1-D photonic crystal on Ag/AsGeSeS film. And than revolved the sample $90^{\circ}$ to fabricate 2-D photonic crystal with holographic lithography.

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Optimization Research of 3D Printer Associated with Properties of Photocurable Resins for Ocular Prosthesis Producing (의안 제작을 위한 광경화 방식 3D 프린터에 적용 가능한 소재 선정 및 장비 최적화를 위한 실험적 연구)

  • Kim, So Hyun;Yoon, Jin Sook;Yoo, Sun Kook
    • Journal of Biomedical Engineering Research
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    • v.40 no.2
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    • pp.55-61
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    • 2019
  • Recently, various researches on materials and equipment have been actively conducted to overcome the limitations of conventional output methods due to the increase of diversity of 3D printing materials and to adopt an output method suitable for the characteristics of each material. As the range applicable to outputable materials is expanded, manufacturing of medical devices applied to patients is in a more rapid growth trend than other fields. In this study, we investigated the suitable materials for fabricating 3D printer using photocurable resin. As a result, one suitable material was selected through biological safety experiment and thermal stability experiment. Next, to optimize the output of the selected materials, we have developed a system that optimizes the equipment according to the characteristics of the material. The results of this study enabled the implementation of personalized medical implants that could not be made from 3D printer dependent materials, thereby overcoming the limitations of existing 3D printer output conditions and dedicated materials.

3D reconstruction of two-phase random heterogeneous material from 2D sections: An approach via genetic algorithms

  • Pizzocri, D.;Genoni, R.;Antonello, F.;Barani, T.;Cappia, F.
    • Nuclear Engineering and Technology
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    • v.53 no.9
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    • pp.2968-2976
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    • 2021
  • This paper introduces a method to reconstruct the three-dimensional (3D) microstructure of two-phase materials, e.g., porous materials such as highly irradiated nuclear fuel, from two-dimensional (2D) sections via a multi-objective optimization genetic algorithm. The optimization is based on the comparison between the reference and reconstructed 2D sections on specific target properties, i.e., 2D pore number, and mean value and standard deviation of the pore-size distribution. This represents a multi-objective fitness function subject to weaker hypotheses compared to state-of-the-art methods based on n-points correlations, allowing for a broader range of application. The effectiveness of the proposed method is demonstrated on synthetic data and compared with state-of-the-art methods adopting a fitness based on 2D correlations. The method here developed can be used as a cost-effective tool to reconstruct the pore structure in highly irradiated materials using 2D experimental data.

Fabrication and Properties of D-Glass Fiber with Low Dielectric Constant (저유전율을 가지는 D-Glass Fiber의 제조 및 특성)

  • Jeong, Bora;Lee, Ji-Sun;Lee, MiJai;Lim, Tae-Young;Lee, Youngjin;Jeon, Dae-Woo;Shin, Dongwook;Kim, Jin-Ho
    • Korean Journal of Materials Research
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    • v.28 no.4
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    • pp.254-259
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    • 2018
  • General D-glass(Dielectric glass) fibers are adaptable to PCBs(Printed circuit boards) because they have a low dielectric constant of about 3.5~4.5. However, very few papers have appeared on the physical characteristics of D-glass fibers. D-glass fibers were fabricated via continuous spinning process using bulk D-glass. In order to fabricate the D-glass, raw materials were put into a Pt crucible, melted at $1650^{\circ}C$ for 2 hrs, and then annealed at $521{\pm}10^{\circ}C$ for 2 hrs. We obtained transparent clear glass. The transmittance and adaptable temperature for spinning of the bulk marble glass were characterized using a UV-visible spectrometer and a viscometer. Continuous spinning was carried out using direct melting spinning equipment as a function of the fiberizing temperature in the range of $1368^{\circ}C$ to $1460^{\circ}C$, while the winder speed was between 100 rpm and 200 rpm. We investigated the physical properties of the D-glass fibers. The average diameters of the glass fibers were measured by optical microscope and FE-SEM. The average diameters of the D-glass fibers were 21.36 um at 100 rpm and 34.06 um at 200 rpm. The mechanical properties of the fibers were confirmed using a UTM(Universal materials testing machine). The average tensile strengths of the D-glass fibers were 467.03 MPa at 100 rpm and 522.60 MPa at 200 rpm.

The Hot Forging of Small Size Gas Turbine Disks (소형가스터빈 디스크의 얼간단조)

  • Cha, D.J.;Song, Y.S.;Kim, D.K.;Kim, Y.D.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.10a
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    • pp.370-373
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    • 2008
  • Small size gas turbine disk requires good mechanical strength and creep properties at high temperature. In this study, Waspaloy was used as a superalloy to satisfy these specifications. The control of microstructure was needed to satisfy material properties at high temperature. In order to do this, we studied forging conditions and material analysis. Therefore die and preform design conducted so that hot forged gas turbine disk could have a good microstructure. The die and preform shapes are designed with consideration of the predefined hydraulic press capacity and the microstructure of forging product. Also we carried out the hot compression test for Waspaloy in various test conditions. From these results, we obtained the forging conditions as material temperature, die velocity etc. To verify these forging conditions, we conducted FE simulations by means of the DEFORM 2D-HT. In this study, the hot closed die and preform designs were completed to offer high temperature material properties of a small size gas turbine.

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Novel quasi-3D and 2D shear deformation theories for bending and free vibration analysis of FGM plates

  • Younsi, Abderahman;Tounsi, Abdelouahed;Zaoui, Fatima Zohra;Bousahla, Abdelmoumen Anis;Mahmoud, S.R.
    • Geomechanics and Engineering
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    • v.14 no.6
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    • pp.519-532
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    • 2018
  • In this work, two dimensional (2D) and quasi three-dimensional (quasi-3D) HSDTs are proposed for bending and free vibration investigation of functionally graded (FG) plates using hyperbolic shape function. Unlike the existing HSDT, the proposed theories have a novel displacement field which include undetermined integral terms and contains fewer unknowns. The material properties of the plate is inhomogeneous and are considered to vary continuously in the thickness direction by three different distributions; power-law, exponential and Mori-Tanaka model, in terms of the volume fractions of the constituents. The governing equations which consider the effects of both transverse shear and thickness stretching are determined through the Hamilton's principle. The closed form solutions are deduced by employing Navier method and then fundamental frequencies are obtained by solving the results of eigenvalue problems. In-plane stress components have been determined by the constitutive equations of composite plates. The transverse stress components have been determined by integrating the 3D stress equilibrium equations in the thickness direction of the FG plate. The accuracy of the present formulation is demonstrated by comparisons with the different 2D, 3D and quasi-3D solutions available in the literature.

Settling Characteristics of Phosphorus in Nakdong Estuary Barrage (낙동강 하구호에서의 인의 침강특성)

  • YANG Jin-Woo;LEE Suk-Mo;PARK Chung-Kil
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.23 no.3
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    • pp.185-191
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    • 1990
  • A study on the characteristics of phosphorus sedimentation in Nakdong Estuary Barrage was conducted in June and July, 1989. Cylindric type sediment trap was designed for collecting of downward material. Downward flux and settling velocity of downward material were $296g/m^2/d$, 1.25m/hr in mid-layer and $955g/m^2/d$, 3.31m/hr in bottom-layer, respectively Downward flux and settling velocity of phosphorus were $0.64g/m^2/d$, 0.85m/hr in mid-layer and $1.97g/m^2/d$, 1.89m/hr in bottom-layer, respectively. Fractional composition of organic phophorus in downward material was $51.9\%$ in mid-layer water and $48.3\%$ in bottom-layer water. According to the result of this study, sedimentation of phosphorus plays an important role as a sinking effect in Nakdong Estuary Barrage.

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Preparation and Dielectric Behavior of D-Glass with Different Boron Contents (보론함량에 따른 D-glass의 유전율 특성)

  • Jeong, Bora;Lee, Ji-Sun;Lee, MiJai;Lim, Tae-Young;Lee, Youngjin;Jeon, Dae-Woo;Shin, Dongwook;Kim, Jin-Ho
    • Korean Journal of Materials Research
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    • v.27 no.1
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    • pp.39-42
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    • 2017
  • E-glass (electrical glass) fiber is the widely used as a reinforced composite material of PCBs (printed circuit boards). However, E-glass fiber is not stable because it has a dielectric constant of 6~7. On the other hand, D-glass (dielectric glass) fiber has a low dielectric constant of 3~4.5. Thus, it is adaptable for use as a reinforcing material of PCBs. In this study, we fabricated D-glass compositions with low dielectric constant, and measured the electrical and optical properties. In the glass composition, the boron content was changed from 9 to 31 wt%. To confirm the dependence of the dielectric constant on melting properties, D-glass with 22 wt% boron was melted at $1550^{\circ}C$ and $1650^{\circ}C$ for 2hrs. The glass melted at $1650^{\circ}C$ had a lower dielectric constant than the glass melted at $1550^{\circ}C$. Therefore, the D-glass with boron of 9~31 wt% was fabricated by melting at $1650^{\circ}C$ for 2hrs, and transparent clear glass was obtained. We identified the non-crystalline nature of the glass using an XRD (x-ray diffractometer) graph. The visible light transmittance values depending on the boron contents were measured and found to be 88.6 % ~ 82.5 %. Finally, the dielectric constant of the D-glass with 31 wt% boron was found to have decreased from 4.18 to 3.93.

A Study on Silane Crosslinking Process of Polypropylene for Enhanced Impact Strength (실란 가교 반응을 이용한 폴리프로필렌의 충격강도 향상에 관한 연구)

  • Kang, Min-Soo;Park, Sung-Ho;Kim, Ki-Sung;Bae, Jong-Rak;Jeon, Oh-Hwan
    • Transactions of the Korean Society of Automotive Engineers
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    • v.18 no.3
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    • pp.69-73
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    • 2010
  • The melt grafting of unsaturated silanes onto polypropylene (PP) in a twin-screw extruder and crosslinking in hot water were studied to enhance impact strength of polypropylene. The influence of grafting formulations on the melt flow rates of grafted PP and the gel percentages of crosslinked PP was investigated. 3-methacryloylpropyltrimethoxysilane (VMMS) unsaturated silane monomer was used. Benzoyl peroxide, (BPO) and Dicumyl peroxide (DCP) were used as an initiator. When benzoyl peroxide (BPO) was used as an initiator, higher gel percentage and impact strength than those of DCP has been observed. The maximum impact strength was obtained with 0.7 phr of BPO and 2phr of VMMS. The value is 8.7 kgf-cm/cm and it is on a parity with the value of with 20 phr of EOR mixed to PP.