• Title/Summary/Keyword: 210Pb

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Chemical Characteristics and Deposition of Aerosols in the Cheju-Korea Straits (제주-대한해협 해역에서 에어로졸의 화학적 특성과 침적)

  • Suk Hyun, Kim;Hyunmi, Lee;Deok-Soo, Moon
    • Ocean and Polar Research
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    • v.44 no.4
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    • pp.297-310
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    • 2022
  • To understand the chemical composition of aerosols in the Cheju-Korea Straits and their contribution to the ocean by deposition, aerosol samples were collected on board R/V Eardo from November 1997 to May 1999. The average concentrations of Al, NO3-, non-sea-salt (nss)-SO42-, and NH4+ in aerosols were 2.19, 5.59, 6.16 and 2.08 ㎍ m-3, respectively. The Al concentration in the high yellow dust period was about 100 times higher than that in the non-yellow dust period. The concentration ratio of NO3-/nss-SO42- ranged between 0.47 and 1.5, indicating that the aerosols in the Cheju-Korea Straits are under the effects of NOx and SOx emitted from China, Korea and Japan. The equivalent concentration ratio of [NH4+]/[nss-SO42-+ NO3-] with the average of 0.58±0.29 indicates that nss-SO42- and NO3- are not neutralized by NH4+. A high activity concentration of 210Pb with 1.13-1.23 mBq m-3 was observed during the high yellow dust period, indicating that 210Pb is easily adsorbed in the yellow dust originating from the continent of Asia. The distribution of 7Be and NH4+ concentrations showed a strong negative linear correlation during the low yellow dust period, April 1998. The total mineral dust flux in the Cheju-Korea Straits was estimated to be 1.21×106 tons yr-1, accounting for about 12% of the annual sediment discharge via the Nakdong River. The combined annual deposition of NH4+ and NO3- was 0.103 mole N m-2 yr-1 was estimated to support 4% of the annual primary productivity in the East China Sea.

A Study on the Valve Regulated Lead-Acid Battery using Sulfuric Acid Gel Electrolyte for New Generation Substitution Energy (황산 겔 전해질을 사용한 차세대 대체에너지용 밀폐형 납축전지에 관한 연구)

  • Park, Keun-Ho;Ju, Chan-Hong
    • Journal of the Korean Applied Science and Technology
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    • v.21 no.2
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    • pp.164-173
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    • 2004
  • The capacity and long life of gel electrolyte batteries is connected with gas recombination producting $PbO_2$ and Pb electrode. We prepared with sulfuric acid gel electrolyte to know gel characteristics per density to assemble valve regulated lead-acid (VRLA) batteries. We studied on actions of sulphuric acid gel electrolyte by measuring electrolyte dispersion using Brewster-angle microscope (BAM), charge-discharge cycle, and electrode structure using scanning election microscope (SEM). Sulphuric acid density 1.210 showed excellent gel dispersion in sol condition, electrode condition after fifty cycles in this study.

A Study on the Valve Regulated Lead-Acid Battery using Phosphoric Acid Gel Electrolyte (인산 겔 전해질을 사용한 밀폐형 납축전지에 관한 연구)

  • Ju, Chan-Hong;Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.4
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    • pp.296-308
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    • 2003
  • The capacity and long life of gel electrolyte batteries is connected with gas recombination producting $PbO_2$ and Pb electrode. We were prepared with phosphoric acid gel electrolyte to know gel characteristics per density to assemble VRLA batteries. We studied by measuring electrolyte dispersion using Brewster-angle microscope(BAM), charge-discharge cycle and electrode structure using scanning election microscope(SEM) per electrolyte density. As a results, phosphoric acid density 1.210 was excellent gel dispersion in sol condition, electrode condition after fifty cycles in this study.

Flux Loss and Neutron Diffraction Measurement Ag-sheathed Bi-2223 Tapes in terms of Flux Creep

  • Jang Mi-Hye
    • KIEE International Transactions on Electrophysics and Applications
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    • v.5C no.5
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    • pp.204-210
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    • 2005
  • Alternating current (AC) losses of two Bi-2223 ([Bi, Pb]: Sr: Ca: Cu: O = 2:2:2:3) tapes [(Tape I, un-twist-pitch) and the other with a twist-pitch of 10 mm (Tape II)] were measured and compared. These samples, produced by the powder-in-(Ag) tube (PIT) method, are multi-filamentary. Also, it's produced by non-twist and different twist pitch (8, 10, 13, 30, 50 and 70 mm). The critical current measurement was carried out under the environment in liquid Nitrogen and in zero-field by 4-probe method. Susceptibility measurements were conducted while cooling in a magnetic field. Flux loss measurements were conducted as a function of ramping rate, frequency and field direction. The AC flux loss increases as the twist-pitch of the tapes decreased, in agreement with the Norris Equation. Neutron-diffraction measurements have been carried out investigate the crystal structure, magnetic structures, and magnetic phase transitions in Bi-2223([Bi, Pb]:Sr:Ca:Cu:O)

The Effect of Piezoelectric Ceramic for Properties Improvement at Electrostriction Ceramic (Actuator용 전왜재료의 특성개선을 위한 압전재료의 첨가효과)

  • 이수호;조현철;김한근;손무현;사공건
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.206-210
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    • 1997
  • In the fields of the optics, precise machine, semiconductors, the micro-positioning actuators are required for the control of position in the submicron range. PNN-P2N-PZT ceramics were fabricated with various mole ratio of the PZT[Pb(Zr$_{1}$2//Ti$_{1}$2)O$_3$]. PNN (Pb(Ni$_{1}$3/Nb$_{2}$3/)O$_3$]and PZN[Pb(Zn$_{1}$3//Nb/sbu 2/3/)O$_3$] powders prepared by double calcination and PZT powders prepared by molten- salt synthesis method. The relative permittivity of specimen with PZT 0.3 mole ratio was shown 5,320 and appeared the relaxor ferroelectric feature. The maximum Piezoelectric coefficient d$_{31}$ to be used for evaluation the displacement of piezoceramics in PNN-PZN-PZT ceramics was 324$\times$10$^{-12}$ (C/V) at the vicinity of morphotropic phase boundary and was larger than that of solid PZT ceramics(120$\times$10$^{-12}$ C/V).

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Contents of Toxic Metals in Fruits Available on Korean Markets (국내유통 과일류 중 유해중금속 함량)

  • Kim, Mee-Hye;Kim, Jung-Soo;Sho, You-Sub;Chung, So-Young;Lee, Jong-Ok
    • Korean Journal of Food Science and Technology
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    • v.36 no.4
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    • pp.523-526
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    • 2004
  • There are few studies on toxic metals in fruits. Therefore, we examined contents of toxic metals in fruits (n=386) available in Korean markets. The samples were digested with acids, then analyzed by inductively coupled plasma spectrometer (ICP) or atomic absorption spectrophotometer (AAS) for lead (Pb), cadmium (Cd), and arsenic (As). The contents of mercury (Hg) were also determined using a mercury analyzer, Contents of toxic metals in fruits were as follows [minimum-maximum (mean), mg/kg]; Hg 0.0001-0.019 (0.001), Pb 0.001-0.410 (0.013), Cd 0.001-0.035 (0.000), and As 0.001-0.210 (0.017). Our results showed that metal contents in fruits in Korean markets were similar to those reported in other countries. Average weekly intakes of Hg, Pb, and Cd from fruits are about 1-2% of Provisional Tolerable Weekly Intakes (PTWI) set by FAO/WHO Joint Food Additive and Contaminants Committee for safety evaluation.

Development of BiPbAgSrCaCuO Superconductor used diffusion of dual layer and The growth mechanism process of superconducting phase (이중층 시료에서 확산을 이용한 BiPbAgSrCaCuO 초전도체 개발 및 초전도상 성장기구)

  • Choi, S.H.;Gang, H.G.;Yu, H.S.;Yu, J.J.;Choi, M.H.;Kim, M.K.;Choi, H.S.;Han, T.H.;Park, S.J.;Hwang, J.S.;Han, B.S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1993.05a
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    • pp.22-27
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    • 1993
  • we prepared 70K new BiPbAgSrCaCuO superconductor used diffusion of dual layer which composed of SrCaCuO and BiPbAgCuO compound. This method is used permeation and diffusion on partial melting point of BiPbAgCuO compound. Samples were analyzed by means of X-ray diffraction analysis, Thermal analysis, critical temperature and scanning electron microscopy. It was found that the best results were obtained for spread volume (A:B=1:0.6) and sintring time 210hours.

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Effects of $GeO_2$ Addition on the Stabilities of $PbO-Bi_2O_3-Ga_2O_3$ Glasses ($GeO_2$의 첨가가 $PbO-Bi_2O_3-Ga_2O_3$ 유리의 안정화에 미치는 영향)

  • Choi, Yong-Gyu;Heo, Jong;Ryou, Sun-Youn
    • Journal of the Korean Ceramic Society
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    • v.32 no.11
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    • pp.1269-1275
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    • 1995
  • Effects of GeO2 addition on the thermal and structural stabilities of PbO-Bi2O3-Ga2O3 glasses were studied. Thermal stabilities, as assessed by the weighted thermal stability factors [(Tx-Tg)/Tg], increased with GeO2 concentraton from 0.097 to 0.210 with the addition of 20 mol% GeO2. Increasing GeO2 content resulted in the decrease of apparent density, molar volume, refractive index and thermal expansion. On the other hand, IR transmission cut-off (λT=50%) moved from 6.73${\mu}{\textrm}{m}$ for the ternary PbO-Bi2O3-Ga2O3 glass to shorter wavelength side, 5.98${\mu}{\textrm}{m}$ for a glass containing 20mol% GeO2. There were little change with GeO2 content, however, in the activation energies for the viscous flow of approximately 140 kcal/mole within the temperature interval of 300~50$0^{\circ}C$. Addition of GeO2 to PbO-Bi2O3-Ga2O3 glasses enhanced the thermal and structural stabilities significantly at the expense of their infrared transmittance. An appropriate compsomise between these two opposite trends should be made following the specifications of the final applications.

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Occurrence and Geochemistry of Argyrodite, a Germanium-Bearing Mineral(Ag8GeS6), from the Weolyu Ag-Au Hydrothermal Vein Deposits (월류(月留) 은(銀)-금(金) 열수광상(熱水鑛床)에서 산출된 함(含) Ge 광물(鑛物)인 Argyrodite의 산상(産狀)과 지구화학(地球化學))

  • So, Chil-Sup;Yun, Seong-Taek;Choi, Seon-Gyu
    • Economic and Environmental Geology
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    • v.26 no.2
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    • pp.117-127
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    • 1993
  • Ag-Au vein ores from the Weolyu mine, Youngdong district, contain significant germanium (up to 145g/t, average 34.9g/t), in the form of argyrodite ($Ag_8GeS_6$). Mineral chemistries of argyrodite and its associated minerals were determined by electron probe microanalysis. Twenty eight elements in thirteen ore samples were analyzed using an ICP mass spectrometer. Argyrodite occurs in the paragenetically later mineral assemblage consisting of carbonates+quartz+native silver+argentite+Ag-sulfosalts, indicating that the germanium mineralization represents the culmination of a complex mineral sequence which includes early gold and late silver deposition. The mean formula of the argyrodite is $Ag_{7.90}\;(Ge_{0.76}Sn_{0.04})S_6$, with minor amounts of Cu, Fe, Sb, As, Sn, and Zn. The Weolyu argyrodite shows systematic substitutions of Ag by Cu, and of Ge by Sb. Chemical analyses of vein ores indicate that metals were precipitated in the order of $Fe{\rightarrow}Pb$, $Zn{\rightarrow}Cu{\rightarrow}Ag$, Sb, As, Ge. Germanium has a strong geochemical affmity with As and Sb, and Cu, Pb, Zn, Mo, and Sr show weak positive correlations with Ge. Germanium deposition at Weolyu was mainly a result of cooling of hydrothermal fluids (down to $175^{\circ}C{\sim}210^{\circ}C$, due to increasing involvement of cooler meteoric waters in the epithermal system.

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Changes in Sediment Characteristics in the Eastern Tidal Flat of Donggum Island in Ganghwa, west coast of Korea (강화 동검도 동부 갯벌의 퇴적 특성 변화)

  • Woo, Han Jun;Jang, Seok;Kwon, Su Jae
    • Journal of Wetlands Research
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    • v.14 no.3
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    • pp.375-384
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    • 2012
  • The sedimentary processes of the Ganghwa tidal flat has been changed over 20 years because of the large-scale construction projects. The sedimentary environment of the Donggum tidal flat, located in the eastern part of Ganghwa tidal flat and in the lower reaches of Yeomha channel, was affected by changes the tidal current regime and estuarine circulation. These resulted an occurrence of rapid deposition in the tidal flat. The silt-clay laminated silt facies in the upper parts of two core sediments suggested that deposition had been relatively high in the tidal flat. The sedimentation rates from the cores using $^{210}Pb$ analysis were 3.25cm/year(st. 3) and 3.47cm/year(st. 5). However the short-term sediment accumulation rates from 2010 to 2012 were mostly less than 1cm/year, indicated that the sediments deposited relatively low rates. As a result, the sediment in the Donggum tidal flat rapidly accumulated during 2000s due to constructions of man-made structures. Recently, the increase of elevation in the tidal flat resulted to show relatively low sedimentation rate with seasonal variations.