• 제목/요약/키워드: 2,4-dichlorophenol

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Mono-와 Di-Chlorophenol에 적응시킨 혐기성 저질의 탈염소 특성 (Regiospecificity of Reductive Dechlorination of Chlorophenols in Mono- and Di-Chlorophenol Adapted Anoxic Sediments)

  • 공인철;이석모
    • 한국환경과학회지
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    • 제3권1호
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    • pp.65-76
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    • 1994
  • 자연호소의 혐기성 저질을 특정한 chlorophenol(CP)에 적응시킨 후 다른 구조물 가진 CP에 대한 탈염소 특성을 검토하였다. CP에 노출되지 않는 혐기성 저질에서는 mono-CP의 경우 ortho > meta > para-염소의 손으로 di-CP의 경우는 ortho > par > meta- 염소의 순서로 짧은 지체기를 거친 후 탈염소가 발생하였다. Mono-CP 중 2-CP에 적응된 저질은 4-CP와 3,4DCP를 제외하고, 3-CP에 적응시킨 저질은 4-CP를 제외한 모든 시험물질에 대하여 지체기 없이 탈염소 특성을 나타내었다. DCP에 적응된 모든 저질은 2-CP, 2,3,-, 2,4-, and 3,4-DCP를 지체기 없이 탈염소가 발생하지 않았다. 이 결과에서 볼 때 mono-와 di-CP를 탈염소시키는 혐기성 미생물의 종류가 다양함을 알 수 있다.

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기체 크로마토그래피/질량분석기를 이용한 종이류 중 알킬페놀류, 클로로페놀류 및 비스페놀 A 정량 (Sensitive Determination of Alkylphenols, Chlorophenols, and Bisphenol A using GC/MS-SIM in Paper Materials)

  • 김협;김진호
    • Environmental Analysis Health and Toxicology
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    • 제18권1호
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    • pp.45-55
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    • 2003
  • The alkylphenols, chlorophenols and bisphenol A were determined by gas chromatography/mass spectrom-etry-selected ion monitoring (GC/MS-SIM) mode followed by two work-up methods for comparison; isoBOC derivatization method and TBDMS derivatization method. Eleven phenols in paper samples were extracted with acetonitrile. Also, solid -phase extraction (SPE) with XAD -4 and subsequent conversion to isobutoxycarbonyl derivatives or tert.-butyldimethylsilyl derivatives for sensitive analysis with the selected ion-monitoring (SIM) mode. The SIM responses were linear with the correlation coefficient varying 0.9717 ∼ 0.9995 (isoBOC derivatization), and 0.9842 ∼ 0.9980 (TBDMS derivatization). The recoveries were 82.4 ∼ 108.8%) by area ratio of phenanthrene -d$\_$10/ vs bisphenol A-d$\^$l6/. (isoBOC derivatization and TBDMS derivatization) The range of concentrations was respectively, 0.95 ∼ 1.44 ng/g in 2,4-dichlorophenol, 1.01 ∼ 1.17 ng/g in t-butylphenol,2.17 ∼ 5.84 ng/g in pentachlorophenol, 12.68 ∼ 14.88 ng/g in nonylphenol and 30.84 ∼ 153.72 ng/g in bisphenol A.

Termicidal Activity and Chemical Components of Wood Vinegar from Nipah Fruit against Coptotermes curvignathus

  • ORAMAHI, Hasan Ashari;TINDAON, Mika Jessika;NURHAIDA, Nurhaida;DIBA, Farah;YANT, Hikma
    • Journal of the Korean Wood Science and Technology
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    • 제50권5호
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    • pp.315-324
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    • 2022
  • The termicidal activity and chemical components of wood vinegar from two sources of biomass, nipah fruit shells (NFS) and a mixture of shells and fiber (MSF), were evaluated against Coptotermes curvignathus. A no-choice test was carried out to evaluate their termicidal activity using filter paper samples treated with 2.5%, 5.0%, 7.5%, 10.0%, and 12.5% NFS or MSF vinegar. Both wood vinegars exhibited antitermitic activity against C. curvignathus. The results show that increased concentrations of NFS and MSF vinegar significantly increased termite mortality. In particular, the NFS vinegar caused complete mortality and the lowest filter paper mass losses at 2.18% when treated with 12.5% wood vinegar. The most abundant chemical compounds of NFS vinegar were cyclopropanecarbonyl chloride, 2,5-dichlorophenol, 2-propanone, acetic acid, propanoic acid, benzenesulfonic acid, 3,7-dimethyl-6-octenal, and trans-geraniol. Meanwhile, the main compounds in the MSF vinegar were 1,2-ethanediol, formic acid, acetic acid, ethanoic acid, 2-furancarboxaldehyde, phenol, 2-methoxy phenol, and 4-methyl phenol.

TIB로 처리된 시금치의 엽록체에서 산소발생계의 광재활성화 (Photoreactivation of the Oxygen Evolving Center in TIB-treated Chloroplasts of Spinach)

  • 정화숙
    • Journal of Plant Biology
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    • 제36권3호
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    • pp.259-266
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    • 1993
  • In Tris-iso-butanol (TIB; Tris buffer pH 8.8 and 1% iso-butanol)-treated chloroplasts, oxygen evolving activity was more inhibited than Tris-treated chloroplasts, but restored highly by 2,6-dichlorophenol-indophenol (DCPIP) and photoreactivation. To understand the mechanism of this results of TIB in photosynthetic electron transport, system, oxygen consumption and evolution of PS I and PS II were measured and protein of the chloroplasts was analysed. In Tris- and TIB-treated chloroplasts, oxygen evolving activity was increased according to the light intensity. Under 48 W·m-2 light intensity, the oxygen evolving activity in both chloroplasts were similar but as the light intensity was increased, TIB-treated chloroplasts showed higher activity. Under 240 W·m-2 light intensity, TIB-treated chloroplasts showed about 25% higher oxygen evolving activity than Tris-treated chloroplasts. Oxygen evolving activity was increased after photoreactivation in both Tris-treated and TIB-treated chloroplasts. Addition of NH4Cl increased the activity in both chloroplasts but in TIB-treated chloroplasts the increase was 30% higher than that in Tris-treated chloroplasts. In PS I, oxygen evolving activity was not inhibited by both treatments whereas in PS II, significant difference was observed between two treatments. Addition of Mn2+ and Ca2+ enhanced oxygen evolution in both Tris- and TIB-treated chloroplasts. Though enhancement was higher in TIB-treated chloroplasts. No difference was observed n protein analysis of the two thylakoid membrane.

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염화페놀류 화합물의 HDTMA-montmorillonite에 대한 수착 동력학에 미치는 ph의 영향 (Effect of pH on the sorption kinetics of chlorophenols onto HDTMA-montmorillonite)

  • Mun Yong, Gwak;Dong Ik, Song
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2004년도 총회 및 춘계학술발표회
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    • pp.186-191
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    • 2004
  • Sorption kinetics of 2-chlorophenol(2-ChP), 2,4-dichlorophenol(2,4-DChP) and 2,4,5-trichlorophenol (2,4,5-TChP), onto montmorillonite modified with hexadecyltrimethyl ammonium cations(HDTMA-mont) were investigated. One-site mass transfer model(OSMTM) and two compartment first-order kinetic model(TCFOKM) were used to analyze kinetics. As expected from the number of model parameters involved, the three-parameter TCFOKM was better than the two-parameter OSMTM in describing sorption and desorption kinetics of chlorophenols in HDTMA-mont. For all chlorophenols, the results of OSMTM analysis indicate that the predominant deprotonated speciation(at pH 9.15) exhibited higher mass transfer coefficient( $k_{s}$ ) than the protonated speciation(at pH 4.85). This is because the deprotonated speciation has stronger hydrophobic interaction than protonated speciation. Most sorption completes in three hours. The fraction of the fast sorption and the first-order sorption rate constants for the fast and slow compartments in TCFOKM were determined by fitting experimental data to the TCFOKM. The results of kinetics reveal that the fraction of the fast sorption( $f_1$) and the sorption rate constants in the fast compartments( $k_1$) were in the order 2,4,5-TChP > 2,4-DChP > 2-ChP, which agrees with the magnitude of the $K_{ow}$ . The first-order sorption rate constants in the fast compartment(10$^{0.8}$ - 10$^{1.22}$ h $r^{-1}$ ) were much larger than those in the slow compartment(10$^{-1}$.74/ - 10$^{-2}$.622/ h $r^{-1}$ ).> ).).

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리그닌과 적니의 공동 열분해를 통한 금속-바이오차 생산 및 수중 오염물질 제거를 위한 활용 (The Production of Metal-biochar through Co-pyrolysis of Lignin and Red Mud and Utilization for the Removal of Contaminants in the Water)

  • 김은지;김나은;박주영;이희연;윤광석
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제29권2호
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    • pp.1-10
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    • 2024
  • With industrial development, the inevitable increase in both organic and inorganic waste necessitates the exploration of waste treatment and utilization methods. This study focuses on co-pyrolyzing lignin and red mud to generate metalbiochar, aiming to demonstrate their potential as effective adsorbents for water pollutant removal. Thermogravimetric analysis revealed mass loss of lignin below 660℃, with additional mass loss occurring (>660℃) due to the phase change of metals (i.e., Fe) in red mud. Characterization of the metal-biochar indicated porous structure embedded with zero-valent iron/magnetite and specific functional groups. The adsorption experiments with 2,4-dichlorophenol and Cd(II) revealed the removal efficiency of the two pollutants reached its maximum at the initial pH of 2.8. These findings suggest that copyrolysis of lignin and red mud can transform waste into valuable materials, serving as effective adsorbents for diverse water pollutants.

A kinetic study of 4-chlorophenol biodegradation by the novel isolated Bacillus subtilis in batch shake flask

  • Sandhibigraha, Sudhansu;Chakraborty, Sagnik;Bandyopadhyay, Tarunkanti;Bhunia, Biswanath
    • Environmental Engineering Research
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    • 제25권1호
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    • pp.62-70
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    • 2020
  • Here in this work, a 4-chlorophenol (4-CP)-degrading bacterial strain Bacillus subtilis (B. subtilis) MF447840.1 was isolated from the drain outside the Hyundai car service center, Agartala, Tripura, India. 16S rDNA technique used carried out for genomic recognition of the bacterial species. Isolated bacterial strain was phylogenetically related with B. subtilis. This strain was capable of breaking down both phenol and 4-CP at the concentration of 1,000 mg/L. Also, the isolated strain can able to metabolize five diverse aromatic molecules such as 2-chlorophenol, 2,4-dichlorophenol, 2,4,6-trichlorophenol, 4-nitrophenol, and pentachlorophenol for their growth. An extensive investigation was performed to portray the kinetics of cell growth along with 4-CP degradation in the batch study utilizing 4-CP as substrate. Various unstructured models were applied to evaluate the intrinsic kinetic factors. Levenspiel's model demonstrates a comparatively enhanced R2 value (0.997) amongst every analyzed model. The data of specific growth rate (μ), saturation constant (KS), and YX/S were 0.11 h-1, 39.88 mg/L, along with 0.53 g/g, correspondingly. The isolated strain degrades 1,000 mg/L of 4-CP within 40 h. Therefore, B. subtilis MF447840.1 was considered a potential candidate for 4-CP degradation.

리그닌의 분해가 우수한 Streptomyces halstedii ssp. scabies SA1-27과 Streptomyces violaceusinger C1-6에서 생성되는 효소들에 관한 연구 (The Study of Enzymes Produced by Streptomyces halstedii ssp. scabies SA1-27 and Streptomyces violaceusinger C1-6 Which Have Good Lignolytic Activity)

  • 김태전
    • 대한임상검사과학회지
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    • 제38권2호
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    • pp.87-93
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    • 2006
  • This study was done to know a kind and change (transition) of enzymes produceed by Streptomyces halstedii ssp. scabies SA1-27 and Streptomyces violaceusinger C1-6 which showed good lignolytic activity and a good decolorization ratio of remazol brilliant blue R(RBBR) dye. These strains were isolated from soil and identified by the author. The basal medium containg 0.2% glucose was used to measure enzyme activity, Lignin peroxidase 1 (Lip 1) was measured by the methods of Choi, and Bourbonnais and Paice. Lignin peroxidase 2 (Lip 2) was measured by the methods of Ishida et al and Ramachandra et al using 2.4-dichlorophenol(2.4 DCP), manganese peroxidase(Mnp), veratryl alcohol oxidase (VAO), and laccase. They were measured by each of the methods of Choi and Paszczynski et al, and Bourbonnais and Paice, and De Jong et al. In the results, the kind of enzymes produced by Streptomyces halstedii ssp. scabies SA1-27 were Lip 1, Lip 2, VAO, and laccase, and their activities indicated the highest value as each 4.95 nmol/mg protein, $8.45({\times}100^{-3})unit$, 10.25 nmol/mg protein, 9.20 nmol/mg protein on the sixth day of the culture and decreased gradually over time. The kind of enzymes produced by Streptomyces violaceusinger C1-6 were Lip 1, Lip 2, Mnp, VAO, and laccase, and their activities indicated the highest value as each 4.90 nmol/mg protein, $13.85({\times}100^{-3})unit$, 3.10 nmol/mg protein, 11.30 nmol/mg protein, 4.45 nmol/mg protein on the sixth day of the culture and decreased gradually over time. Consequently, the author knew the fact that there were few differences in the kind and quantity of enzymes produced by the two Streptomyces strains, but all enzyme activities indicated the highest value on the sixth day of the culture and decreased gradually over time.

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Experimental Investigation and Quantum Chemical Calculations of Some (Chlorophenyl Isoxazol-5-yl) Methanol Derivatives as Inhibitors for Corrosion of Mild Steel in 1 M HCl Solution

  • Sadeghzadeh, Rogayeh;Ejlali, Ladan;Eshaghi, Moosa;Basharnavaz, Hadi;Seyyedi, Kambiz
    • Corrosion Science and Technology
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    • 제18권5호
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    • pp.155-167
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    • 2019
  • In this study, two novel Schiff base compounds including (3-(4-Chlorophenyl isoxazole-5-yl) methanol and (3-(2,4 dichlorophenol isoxazole-5-yl) methanol as corrosion inhibitors for mild steel in 1 M hydrochloric acid solution were investigated by potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and density functional theory (DFT) computations. The results showed that the corrosion inhibition efficiency (IE) is remarkably enhanced with the growing concentration of the Schiff base inhibitors. The results from Tafel polarization and EIS methods showed that IE decreases with gradual increments of temperature. This process can be attributed to the displacement of the adsorption/desorption balance and hence to the diminution of the level of a surface coating. Also, the adsorption of two inhibitors over mild steel followed the Langmuir adsorption isotherm. Too, the results of the scanning electron microscope (SEM) images showed that the Schiff base inhibitors form an excellent protective film over mild steel and verified the results by electrochemical techniques. Additionally, the results from the experimental and those from DFT computations are in excellent accordance.

무흡광 색소생물의 감광수용체 개발 연구(IV) -표고버섯 중의 광감응성 Mitochondrial ATP synthase의 유기물 및 금속이온 유입효과- (Studies on the Development of Photoreceptor in the Nonchromatophore Organisms (IV) -Effect of organic compound and metal ion influx of light-induced Mitochondrial ATP synthase in Lentinus edodes (Berk.) Sing-)

  • 민태진;이완기;김재웅;민태익
    • 한국균학회지
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    • 제17권2호
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    • pp.99-104
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    • 1989
  • 1. 최적광조사 조건, 470 nm에서 15초 동안 빛을 조사한 미토콘드리아성 ATP synthase는 1mmole DCPI에 의하여 그 활성이 85% 증가되었다. 2. 1mmole DNP, $10\;{\mu}mole$ HHQNO 및 $100\;{\mu}g/ml$의 oligomycin은 이 효소의 활성을 각각 61, 41% 및 12% 억제시켰다. 3. 최적 조건의 빛에 의한 $Fe^{3+}$$Fe^{2+}$ 이온의 유입효과에서, 5mmole $Fe^{3+}$ 및 0.5mmole $Fe^{2+}$ 이온에 의하여 이 효소 활성이 각각 14% 및 12% 증가되었다. 4. 광증감제인 phenazine methosulfate의 존재하에서 470nm의 빛을 조사한 후의 효소의 활성도가 크게 증가되는 것으로 보아, 미토콘드리아성 ATP synthase내에 미지의 흡광물질이 존재함을 추정할 수 있었다.

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