• Title/Summary/Keyword: 2,4-TDI

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Impact of anthropogenic activities on the accumulation of heavy metals in water, sediments and some commercially important fish of the Padma River, Bangladesh

  • M Golam Mortuza
    • Fisheries and Aquatic Sciences
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    • v.27 no.2
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    • pp.66-75
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    • 2024
  • Heavy metals are naturally found in the ecosystem, and their presence in the freshwater river is increasing through anthropogenic activities which pose a threat to living beings. In this study, heavy metal concentrations (Zn, Mn, Cu, Cd, Cu, Cr, Pb, and Ni) in different organs (muscle, skin, and gill) of fish from the Padma River were evaluated to quantify, and compare the contamination levels and related human health risks. The results revealed that the heavy metal concentrations in the water, surface sediments, and fish taken from the Padma River were far below the WHO/USEPA's permitted limits. The estimated daily intake (EDI) value in muscle was less than the tolerable daily intake (TDI). The target hazard quotient (THQ) and hazard indexes (HI) were less than 1, showing that consumers face no non-carcinogenic risk (CR). CR values of Cu, Cd, Cr, Pb, and Ni ranged from 4.00 × 10-8 to 6.35 × 10-6, less than 10-4, and total carcinogenic risk (CRt) values ranged from 9.85 × 10-6 to 1.10 × 10-5, indicating some pose a CR from consumption of those fish from the Padma River. To establish a more accurate risk assessment, numerous exposure routes, including inhalation and cutaneous exposure, should be explored.

Variation of Water Quality and Periphytic Algae in Multi-layer and Porous Structure for River-bed Protection using Bio-polymer materials: A Case Study of Daecheong-stream in Gimhae-Si (Bio-polymer 소재를 활용한 다층다공성 하상보호공 적용에 따른 수질 및 부착조류의 변화량: 김해시 대청천을 중심으로)

  • Lee, Sang-Hoon;Ahn, Hong-Kyu;Che, Soo-Kwon
    • Ecology and Resilient Infrastructure
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    • v.6 no.4
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    • pp.227-235
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    • 2019
  • This study monitored Daecheong 1-bo, Daecheong-stream, which carried out the project in 2014, from 2015 to 2016. The technology applied to the stream was evaluated using Periphytic Algae to check contamination indicators and ecological health of the area with an integral river-bed protection using non-toxic materials. The water quality of the monitoring section was confirmed to be above the river environment standard (II), and it was confirmed that the Saproxenic taxa of the river bed protection were higher than the upper and downstream sections. The TDI, which is an index of attachment algae, was shown in the average 51.03 and 52.15 for the pilot project sections in 2015 and 2016, confirming that the index is of the "normal" grade. This is the other sections in the upstream and downstream sections showed higher than "bad", which is thought to have a positive effect on the habitat of the river ecosystem components, especially the microbial population in river bed protection.

The Design of MSC(Multi-Spectral Camera) Calibration Operation

  • Yong Sang-Soon;Kang Geum-Sil;Jang Young-Jun;Kim Jong-Ah;Kang Song-Doug;Paik Hong-Yul
    • Proceedings of the KSRS Conference
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    • 2004.10a
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    • pp.601-603
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    • 2004
  • Multi-Spectral Camera(MSC) is a payload on the KOMPSAT -2 satellite to perform the earth remote sensing. The instrument images the earth using a push-broom motion with a swath width of 15 km and a ground sample distance (GSD) of 1 m over the entire field of view (FOV) at altitude 685 Km. The instrument is designed to have an on-orbit operation duty cycle of $20\%$ over the mission lifetime of 3 years with the functions of programmable gain! offset and onboard image data compression/storage. MSC instrument has one(1) channel for panchromatic Imaging and four(4) channel for multi-spectral Imaging covering the spectral range from 450nm to 900nm using TDI CCD Focal Plane Array (FPA). In this paper, the configuration, the interface of MSC hardware and the MSC operation concept are described. And the method of the MSC calibration are described and the design of MSC calibration operation to measure the change of MSC after Launch & Early Operation(LEOP) and normal mission operations are discussed and analyzed.

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The Dynamic of Phytoplankton Communities and the Biological Water Quality Assessment at Three Artificial Weirs in Downstream of Namhan-river (남한강 3개 인공보의 식물플랑크톤 군집 변동과 생물학적 수질평가)

  • Shin, Hyun-Joo;Lee, Ok-Min
    • Journal of Korean Society on Water Environment
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    • v.30 no.6
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    • pp.612-621
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    • 2014
  • Physicochemical factors and the phytoplankton communities in the downstream area of Namhan-River were investigated from June 2012 to November 2013. We also assessed water quality using biological water quality indices. Total nitrogen was 2.4 mg/L, total phosphorus was 0.04 mg/L, and biological oxygen demand was 1.1 mg/L. This resulted in a level 2 (Ib, good) water quality rating. A total of 259 phytoplankton taxa were classified, consisting of 26 families, two subfamilies, 64 genera, 222 species, 32 varieties, and five formas. Bacillariophyceae dominated during a1l seasons and at all sites. The dominant species were Aulacoseira granulata, Cyclotella meneghiniana, C. stelligera, Melosira varians, Cocconeis placentula var. lineata, Nitzschia palea, N. amphibia, Cymbella minuta, and Achnanthes convergens. The diatom assemblage index for organic pollution values was level A-D, and TDI was level B-D. P-IBI at most sites was at the M (moderate) level, but TSI was at the E (eutrophic) level. Most indices dropped from upstream to downstream.

Analysis and Safety Assessment of Antioxidants Migrated from Polyethylene and Polypropylene Food Packaging Materials into Food Simulants (폴리에틸렌 및 폴리프로필렌 기구·용기·포장 유래 산화방지제 분석 및 안전성평가)

  • Choi, Heeju;Choi, Jae Chun;Bae, In-Ae;Park, Se-Jong;Kim, MeeKyung
    • Journal of Food Hygiene and Safety
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    • v.32 no.5
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    • pp.424-433
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    • 2017
  • Antioxidants are used in the manufacturing of commercial food packages made of polyolefin plastic such as polyethylene and polypropylene for the purpose to delay the oxidation reaction of the polymer due to oxygen or traces of ozone in the atmosphere. Additives in plastics may be migrated from the packaging materials into foods, thereby presenting a potential health risk to the consumer. Therefore, it is necessary to determine migration level of antioxidants from food packaging materials to foodstuffs in order to take proactive management. In this study, we have developed a method for the analysis of 10 antioxidants, which are butylated hydroxyanisole (BHA), butylated hydroxytoluene (BHT), Cyanox 2246, 425 and 1790, Irgafos 168, and Irganox 1010, 1330, 3114 and 1076, migrated from the food packaging materials into four food simulants for aqueous, acidic, alcoholic and fatty foods. The antioxidants were determined by reversed-phase high-performance liquid chromatograph-ultraviolet detector with 276 nm after solid-phase extraction with a hydrophilic-lipophilic balance (HLB) cartridge or dilution with isopropanol. The analytical method showed a good linearity of coefficient ($R^2{\geq}0.99$), limits of detection (0.11~0.41 mg/L), and limits of quantification (0.34~1.24 mg/L). The recoveries of antioxidants spiked to four food simulants ranged from 71.3% to 109.4%. The migrated antioxidants in this study were within the safety levels that resulted from the safety assessment by the estimated daily intake to the tolerable daily intake.

Preparation and Application of Polyurethane-urea Microcapsules Containing Phase Change Materials

  • Kwon Ji-Yun;Kim Han-Do
    • Fibers and Polymers
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    • v.7 no.1
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    • pp.12-19
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    • 2006
  • For thermal adaptable fabrics, the polyurethane-urea microcapsules containing phase-change materials (PCMs: hexadecane, octadecane and eicosane) were successfully synthesized by interfacial polycondensation using 2,4-toluene diisocyanate (TDI)/poly(ethylene glycol) (PEG400)/ethylene diamine (EDA) as shell monomers and nonionic surfactant NP-12 in an emulsion system under stirring rates of $3,000{\sim}13,000$ rpm. The mean particle size of microcapsule decreased significantly with increasing the stirring rate up to 11,000 rpm, and then leveled off. The mean particle size increased with increasing the content and molecular weight (eicosane > octadecane > hexadecane) of PCMs at the same stirring rate. The mean particle sizes of microcapsules were found to decrease with increasing the NP-12 content up to 1.5 wt%, and thereafter increased a little. It was found that the melting temperature ($T_m$) and crystallization temperature ($T_c$) of three kinds of encapsulated PCMs and their enthalpy changes (${\Delta}H_m,{\Delta}H_c$) increased with increasing PCM contents. The encapsulation efficiencies (Ee) of hexadecane microcapsule linearly increased with increasing the content of hexadecane. It was found that the stable microcapsule containing 50 wt% of hexadecane could be obtained in this study. However, Ee of octadecane and eicosane microcapsules increased with increasing PCM's contents up to 40 wt%, and then decreased a little. By considering the encapsulation efficiency, it was found that the maximum/optimum contents of octadecane and eicosane microcapsules were about 40 wt%. By the dynamic thermal performance test, it was found that the maximum buffering levels of Nylon fabrics coated with hexadecane, octadecane, and eicosane microcapsules were about $-2.4/+2.9^{\circ}C,\;-3.6/+3.6^{\circ}C\;and\;-4.0/+4.7^{\circ}C$, respectively.

Study on the Validity of Selection of Hazardous Substances Requiring Management on Industrial Safety and Health Act (산업안전보건법에 의한 관리대상 유해물질 선정의 타당성 연구)

  • Lee, Kwon Seob;Jo, Jihoon;Choi, Jin Hee;Shin, Hyun Hwa;Yang, Jeong Sun
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.19 no.2
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    • pp.139-152
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    • 2009
  • According to the third study on the distribution of chemical substances carried out by the Department of Environment in 2006, there were a total of 900 chemical substances whose respective annual usage amount exceeded 1,000 tons and, among them, 90 substances belonged to the 168 hazardous substances requiring management(53.6%). The work-related illnesses caused by hazardous substances requiring management in Korea between $1992{\sim}2005$ can be classified into four groups depending on the type of the chemical substances. These four groups are 23 organic substances including benzene, 12 metals including lead, 3 acids and bases including hydrogen chloride, and 6 gaseous substances including carbon monoxide. These hazardous substances requiring management were again classified depending on the threshold limit values. The chemicals whose TLV was lower than or equal to 0.005 ppm included 4 organic substances including methylene bisphenyl isocyanate and toluene-2,4-diisocyanate (TDI). The chemicals whose TLV was larger than 51 ppm included 22 organic substances including diethyl ether and 1,2-dichloroethylene. When we classified these hazardous substances requiring management according to the categories of GHS health hazards, we found that isobutyl acetate and magnesium oxide didn't belong to the 13 health hazard categories. Among the substances whose TLV is set and whose annual usage amount is more than 0.1 million ton, we recommended 12 chemical species including 4,4'-Methylenedianiline as new hazardous substances requiring management. All the recommended substances were found to be hazardous when we classified their health hazards.

Implementation of an USB Camera Interface Based on Embedded Linux System (임베디드 LINUX 시스템 기반 USB 카메라 인터페이스 구현)

  • Song Sung-Hee;Kim Jeong-Hyeon;Kim Tae-Hyo
    • Journal of the Institute of Convergence Signal Processing
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    • v.6 no.4
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    • pp.169-175
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    • 2005
  • In recent, implementation of the embedded system is gradually in the spotlight of world-wide by information technology(IT) engineers. By this time, an implementation of real time system is limited on image acquisition and processing system in practical. In this paper, the USB camera interface system based on the embedded linux OS is implemented using USB 2.0 camera with low cost. This system can obtain image signals into the memory via X-hyper255B processor from USB camera. It is need to initialize USB camera by the Video4Linux for the kernel device driver. From the system image capturing and image processing can be performed. It is confirmed that the image data can be transformed to packet of Network File System(NFS) and connected to the internetwork, then the data can be monitored from the client computer connected to the internetwork.

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Evaluation of short-term cardiac function by tissue Doppler imaging in pre and postoperative period of congenital heart disease (조직 도플러 영상을 이용한 선천성 심장병 수술 전후의 단기 심기능 평가)

  • Lee, Jun-Hwa;Kim, Yeo-Hyang;Hyun, Myung-Chul;Lee, Sang-Bum
    • Clinical and Experimental Pediatrics
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    • v.50 no.5
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    • pp.476-483
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    • 2007
  • Purpose : The objective of this study was to assess ventricular function by tissue Doppler imaging (TDI) in children with congenital heart disease (CHD) who have been undergoing open heart surgery (OHS) using cardiopulmonary bypass. We tried to compare the parameters of tissue Doppler imaging before and after OHS in patients with congenital heart disease. Methods : This study was conducted on 32 patients with CHD after OHS from January 2005 to December 2005 at Kyungpook National University hospital. Patients who underwent 2-D echocardiography before and after their OHS. All patients were divided into three groups, left ventricular volume overloading group (group 1), and right ventricular volume overloading group (group 2), and right ventricular pressure overloading group (group 3). The TDIs were examined before and 1 to 3 months after OHS. Peak early diastolic (E), and peak late diastolic (A) velocity of transmitral flow were measured by pulsed wave Doppler examination. Peak systolic (Sm), peak early diastolic (Em), and peak late diastolic (Am) velocity in apical 4-chamber and 2-chamber views were measured by TDI. The author calculated E/Em ratio. Results : The patients were 14 boys and 18 girls and the average age of patients was 2 years and 3 months. The congenital heart diseases which have to get OHS were ventricular septal defect (13 cases), atrial septal defect (7), atrioventricular septal defect (3), isolated pulmonary stenosis (2) and tetralogy of Fallot (7). There were significant decrease of Sm, Em, Am measured on tricuspid annulus and E/Em measured on mitral annulus in apical 4 chamber view (P<0.05). Conclusion : This study showed significant decrease of Sm, Em, Am measured on tricuspid annulus and E/Em measured on mitral annulus in apical 4 chamber view after OHS. These changes might be due to the effects of cardiopulmonary bypass in OHS and/or hemodynamic changes after correction of congenital heart disease. To clarify these changes, further study on more patients is needed.

Comparison of Correction Coefficients for the Non-uniformity of Pixel Response in Satellite Camera Electronics (위성카메라 전자부의 화소간 응답불균일성 보정계수의 비교검토)

  • Kong, Jong-Pil;Lee, Song-Jae
    • Korean Journal of Remote Sensing
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    • v.27 no.2
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    • pp.89-98
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    • 2011
  • Four kinds of gain and offset correction coefficients that are used to correct the nonuniformity between pixels are discussed. And their correction performance has been compared by performing image correction. using the correction coefficients calculated, on the real image data obtained from a newly fabricated camera electronics system. The performance of the correction coefficients depends in general on the number of the light input levels used to obtain the reference image. The result shows that, as expected obviously, when only two light input levles are used to obtain the reference image, even though its correction coefficients are relatively easily calculated, the correction performance is relatively poor. And with the number of light inputs increased to a value of larger than two, the correction performance is improved. It is noted, however, no Significant performance difference is found between the different correction coefficients employed.