• Title/Summary/Keyword: 18650 Li-ion battery

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Studies on Multi-step Addition of NMP in (LiNi0.80Co0.15Al0.05) (NCA) Cathode Slurry Preparation and its Rheological, Mechanical Strength and Electrochemical Properties for Li-ion Cells

  • Vasudevarao Pasala;Satyanarayana Maddukuri;V. Sethuraman;Rekha Lankipalli;Devi Gajula;Venkateswarlu Manne
    • Journal of Electrochemical Science and Technology
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    • v.14 no.3
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    • pp.262-271
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    • 2023
  • For electrode stability and the electrochemical performance of the Li-ion cell, it is essential that the active ingredients and unique additives in the polymer binder be well dispersed with the solvent-based slurry. The efficient procedure used to create the slurry affects the rheological characteristics of the electrode slurry. When successively adding different steps of Nmethyl-2-pyrrolidone (NMP) solvent to the cathode composition, it is evenly disseminated. The electrochemical performance of the Li-ion cells and the electrodes made with slurry formed by single step and multiple steps of addition of NMP solvent are examined. To preform rheological properties of cathode electrode slurry on Ni-rich Lithium Nickel-Cobalt-Aluminum Oxide (LiNi0.80Co0.15Al0.05) (NCA). Also, we investigate different step addition of electrode formation and mechanical strength characterization like peel strength. According to the EIS study, a multi-step electrode slurry has lower internal resistance than a single-step electrode slurry, which results in better electrical characteristics and efficiency. Further, microstructure of electrodes is obtained electrochemical performance in the 18650 cylindrical cells with targeted capacity of 1.5 Ah. The slurry of electrodes prepared by single step and multiple steps of addition of NMP solvent and its effect on the fabrication of 1.5 Ah cells. A three-step solvent addition on slurry has been found to be a lower internal resistance than a single-step electrode slurry as confirmed by the EIS analysis, yielding improved electrical properties and efficiency.

Screening method using the cells deviation for Li-ion battery pack of the high power application (고출력 어플리케이션의 배터리 팩에 적합한 셀간 편차를 이용한 스크리닝 기법)

  • Lee, P.Y.;Lee, D.Y.;Pack, J.H.;Kim, J.H.;Lim, C.W.
    • Proceedings of the KIPE Conference
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    • 2017.11a
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    • pp.157-158
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    • 2017
  • 본 논문에서는 고출력 리튬이온 18650 셀(cell) 200개를 사용하여 고출력 어플리케이션의 운용 범위와 동적 특성을 적용한 스크리닝 방법을 제안하였다. 전기적 특성 실험 기반 배터리 용량과 OCV(open circuit voltage)의 요소를 고려한 16개의 내부 파라미터를 추출하고 표준편차 기반 가중치를 선정하였다. 선정된 가중치를 각각의 요소에 적용하여 단위 셀의 대표 값을 결정하고 셀 스크리닝을 수행하였다. 기존의 스크리닝 기법과 제안된 스크리닝 기법을 200개의 단위 셀에 적용하여 두 기법의 차이를 비교 분석하였다.

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Effect of Fast Charging Mode on the Degradation of Lithium-Ion Battery: Constant Current vs. Constant Power (정전류/정출력 고속충전 방식에 따른 리튬이온전지의 열화 비교 연구)

  • Park, Sun Ho;Oh, Euntaek;Park, Siyoung;Lim, Jihun;Choi, Jin Hyeok;Lee, Yong Min
    • KEPCO Journal on Electric Power and Energy
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    • v.6 no.2
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    • pp.173-179
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    • 2020
  • Electric vehicles (EVs) using lithium secondary batteries (LIBs) with excellent power and long-term cycle performance are gaining interest as the successors of internal combustion engine (ICE) vehicles. However, there are few systematic researches for fast charging to satisfy customers' needs. In this study, we compare the degradation of LIB where its composition is LiNi0.5Co0.2Mn0.3/Graphite with the constant current and constant power-charging method. The charging speed was set to 1C, 2C, 3C and 4C in the constant current mode and the value of constant power was calculated based on the energy at each charging speed. Therefore, by analyzing the battery degradation based on the same charging energy but different charging method; CP charging method can slow down the battery degradation at a high rate of 3C through the voltage curve, capacity retention and DC-IR. However, when the charging rate was increased by 4C or more, the deviation between the LIBs dominated the degradation than the charging method.