• Transactions of the Korean Society of Mechanical Engineers A
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• v.24 no.3 s.174
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• pp.603-612
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• 2000

Corrosion characteristics on the 12Cr alloy steel of turbine blade was electro-chemically investigated in 3.5wt% NaCI and 12.7wt% Na2S04 solution, respectively. Electro-chemical polarization test, Huey test and Oxalic acid etching test were previously conducted to estimate corrosion susceptibility of the material. And, using the horizontal corrosion fatigue tester, corrosion fatigue characteristics of 12Cr alloy steel in distilled water, 3.5wt% NaCI solution, and 12.7wt%(1M) Na2S04 solution were also fracture-mechanically estimated and compared their results. Parameter considered was room temperature, 60'C and 90'C. Corrosion fatigue crack length was measured by DC potential difference method.Obtained results are as follows,1) 12Cr alloy steel showed high corrosion rate in 3.5wt% NaCI solution and Na2S04 solution at high tempratue.2) Intergranular corrosion sensitivity of 12 Cr alloy was smaller than austenitic stainless steel.3) Corrosion fatigue crack growth rate in 3.5wt% NaCI and 12.7wt%(IM) Na2S04 solution is entirely higher than in the distilled water, and also increased with the temperature increase.

• Proceedings of the KSME Conference
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• 2001.06a
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• pp.223-230
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• 2001

The Monkman-Grant (M-G) and its modified parameters were estimated for modified type 316LN and $9{\sim}12Cr-1Mo$ steels with chemical variations. Several sets of creep data were obtained by constant-load creep tests in $550-650^{\circ}C$ ranges. The relation parameters, m, $m^*$, C and $C^*$ were proposed and discussed for two alloy systems. In creep fracture mode, type 316LN steel showed domination of the intergranular fracture caused by growth and coalescence of cavities. On the other hand, the Cr-Mo steel showed transgranular fracture of the ductile type caused from softening at high temperature. In spite of the basic differences in creep fracture modes as well as creep properties, the M-G and its modified relations demonstrated linearity within the $2{\sigma}$ standard deviation. The value of the m parameter of the M-G relation was 0.90 in the 316LN steel and 0.84 in the Cr-Mo steel. The value of the $m^*$ parameter of the modified relation was 0.94 in the 316LN steel and 0.89 in Cr-Mo steel. The modified relation was superior to the M-G relation because the $m^*$ slopes almost overlapped regardless of creep testing conditions and chemical variations to the two alloy systems.

• Transactions of the Korean Society of Mechanical Engineers
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• v.17 no.6
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• pp.1321-1329
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• 1993

Long time creep strength and life prediction of 1% Cr-Mo-V and 12% Cr rotor steel were performed by using round-bar type specimens under static load at 500-600.deg. C TTP (time temperature parameter), MCM (minimum commitment method) and ISM (initial strain method newly devised) as life prediction methods were investigated, and the results could be summarized as follows. (1) The minimum parameter of SEE (standard error) by TTP was proved as LMP (larson-miller parameter), and the minimum parameter of RMS (root mean squares), by data less than 10$^{3}$hrs was MHP (manson-haferd parameter). (2) The parameters of the minimum and the maximum strength values predicted in $10^{5}$hrs creep life of 1% Cr-Mo-V steel by TTP were LMP and MSP, respectively. In case of 12% Cr steel above $550^{\circ}C$ OSDP (orr-sherby-dorn parameter) was minimum and MSP (manson-succop parameter) was maximum, but below $550^{\circ}C$, the inverse phenomena was observed. On the other hand the creep strengths before $10^{3}hrs$ life by MCM were similar to those by TTP, but the strengths after $10^{3}hrs$ life were 10-25% lower than those by TTP. (3) Creep strengths by ISM were maximum 5% lower than those by TTP. Because $10^{5}hrs$ strengths were similar to those of the lower band by TTP, the ISM was safer than the TTP.

• Journal of Power System Engineering
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• v.16 no.1
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• pp.58-64
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• 2012

Power plant boiler is one of the most important utilities providing steam to turbine in thermal power plant. It is composed of thousands of boiler tubes for high efficient heat transfer. Boiler tube material is used in such high temperature and pressure as $540^{\circ}C$, $170kg/mm^2$. The boiler tube material is needed to resist corrosion damage, creep damage and fatigue damage. 2.25%Cr-1Mo steel is used for conventional boiler tubes. In these days steam temperature and pressure of the power plant became higher for high plant efficiency. So, the material property of boiler tube must be upgraded to meet the plant property. Several boiler tube material was developed to meet such condition. X20CrMoV12.1 steel is also developed in early 1980's and used for superheater and reheater tubes in supercritical boilers. The material has martensitic structure, which is difficult to evaluate the material degradation. Boiler tube material at severe condition was tested to evaluate long term and short term degradation and creep. Through long term and high temperature degradation test, lath structure was decreased and recrystallization has been proceeded by sub-crystal. And in this research the effect of temperature and stress on boiler tube characteristic,for example, deformation by creep was changed rapidly at relatively high temperature and stress because creep was affected easily by temperature and stress.

• Bulletin of the Korean Chemical Society
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• v.12 no.5
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• pp.520-524
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• 1991

Stainless steel 304 2B and BA are oxidized in 2.5 M $CrO_3/$ 5.0 M $H_2SO_4$ solution, and elemental composition and oxidized state of the surface region is analyzed as a function of the surface depth using X-ray photoelectron spectroscopy. It is found that Fe and Cr are preferentially oxidized and diffuse outward following the oxidation. Element Ni, the third major component of the steel is not oxidized and remains deep under the surface. It is also found that the oxidized Fe dissolves considerably into the solution thereby enriching the gas-oxide interface with Cr.

• Transactions of the Korean Society of Mechanical Engineers
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• v.14 no.5
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• pp.1349-1355
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• 1990

By examining the fatigue deformation properties of 12% Cr rotor steel which has been proved to have high fatigue and creep rupture strength around 600deg. C, authors reviewed major fatigue life prediction models such as Manson, Langer and Morrow equations, and following results were obtained. (1) A simple life prediction model for 12% Cr rotor steel was obtained as follows : DELTA..epsilon.$_{t}$ =2.18+.sigma.$_{u}$ /E+ $N^{-0.065}$+ $e^{0.6}$ $N^{-0.025}$ This equation shows that fatigue life, N, can be easily determined when total strain range, DELTA..epsilon.$_{t}$ and ultimate tensile strength, .sigma.$_{u}$ are known by simple tension test on the given test conditions. (2) Life prediction equation with equivalent maximum stress, DELTA..sigma./2, corresponding maximum strain in one cycle at room temperature is as follows: DELTA..sigma./w=-7.01logN+96.69+96.69

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 1999.05a
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• pp.73-74
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• 1999

• Journal of Welding and Joining
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• v.4 no.2
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• pp.40-46
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• 1986

This investigation is concerned with the toughness and microstructure of manneristically simulated HAZ in 12% Cr steel. Unnotched specimens were subjected to weld thermal cycles a weld simulator. The parameters-peak temperatures, cooling rate, influence of PWHT and plastic deformation were considered. After weld simulation, the specimens were heat-treated, V-notched and impact tested. An optical metallographic examination was performed to correlate the HAZ toughness with microstructure. Also a fractographic examination was done to obtain information on the fracture mode. The toughness of the coarse grained zone and the part of HAZ subjected to a peak temperature range 700-800.deg. C are lower than the other parts. However, they are still high enough. The double PWHT cycle could not improve the HAZ toughness in present study. However, if the first PWHT is conducted before the work piece is cooled below $M_f$, it is expected that the double PWHA may be beneficial to the toughness of the HAZ. It is also expected that martensitic welding can be used on production welds.

• Journal of the Korean Society for Precision Engineering
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• v.19 no.8
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• pp.71-76
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• 2002

In this study low cycle fatigue (LCF) behavior of 12Cr steel at high temperature are described. Secondly, comparisons between predicted lives and experimental lives are made for the several sample life prediction models. Two minute hold period in either tension or compression reduce the number of cycles to failure by about a factor of two. Twenty minute hold periods in compression lead to shorter lives than 2 minute hold periods in compression. Experiments showed that life predictions from classical phenomenological models have limitations. More LCF experiments should be pursued to gain understanding of the physical damage mechanisms and to allow the development of physically-based models which can enhance the accuracy of the predictions of components. From a design point-of-view, life prediction has been judged acceptable for these particular loading conditions but extrapolations to thermo-mechanical fatigue loading, for example, require more sophisticated models including physical damage mechanisms.

• Journal of Power System Engineering
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• v.14 no.2
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• pp.78-83
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• 2010

This study was carried out to investigate the effect of microstructure on the damping capacity of 12Cr martensite heat-resisting steels, in case of the specimen with martensite phase contained the volume faction of ferrite phases, under 5%. The damping capacity was decreased with the increase of solution treatment temperature and time. While it was increased with the increase of tempering temperature and time. The damping capacity was higher in case of specimen with martensite single phase structure than the specimen with martensite phase contained of ferrite phases.