• Title/Summary/Keyword: 1.5 generation

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Synthesis, Characterization, and Electrochemical Behavior of Viologen-Functionalized Poly(Amidoamine) Dendrimers

  • Oh, Mi-Kyung;Bae, Sang-Eun;Yoon, Jung-Hyun;Roberts, Mary F.;Cha, Eun-Hee;J. Lee, Chi-Woo
    • Bulletin of the Korean Chemical Society
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    • v.25 no.5
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    • pp.715-720
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    • 2004
  • Amineterminated, ethylenediamine core polyamidoamine starburst dendrimers of generation 2 (G2), generation 4 (G4) and generation 6 (G6) have been successfully surface-modified via an amide coupling reaction with 4-ethyl, 4'-(3-propionic) bipyridinium cation and the electrochemical behavior of the resulting dendrimers were investigated in aqueous potassium chloride electrolyte solutions. The 1-[3-(dimethylamino)propyl]-3-ethylcarbodiimide hydrochloride/N-hydroxysuccinimide-mediated reaction resulted in 25-39% end-group functionalization. The water-soluble 4-ethyl, 4'-(3-propylamide) bipyridinium dibromide dendrimers (G2-V2+, G4-V2+ and G6-V2+) were characterized by $^1H$ NMR and UV-Vis spectroscopic methods. The cyclic voltammetric and chronoamperometric experiments were performed to determine the diffusion coefficient and the number of electrons transferred in the process of the first reduction of the viologen-functionalized dendrimers. Adsorption of viologen-functionalized dendrimers at electrode surface was evidenced in the voltammograms. Experimentally determined diffusion coefficients were in good agreement with the values expected from the Stokes-Einstein relation, while the number of electrons transferred concurred with the extent of functionalization determined by $^1H$ NMR and UV-Vis spectra.

High Power Characteristics of $Pb(Y_{2/3}W_{1/3})O_3-Pb(Zr,Ti)O_3$Ceramics ($Pb(Y_{2/3}W_{1/3})O_3-Pb(Zr,Ti)O_3$계 세라믹스의 고출력 특성)

  • ;Kenji Uchino
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.5
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    • pp.394-399
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    • 1998
  • High power characteristics with vibration velocity were studied in $Pb(Y_{2/3}W_{1/3})O_3-Pb(Zr,Ti)O_3$(PYW-PZT) ceramics by using the constant current method. Young s modulus $Y_0^E$ and mechanical quality factor $Q_m$ are a function of the square of effective vibration velocity \upsilon_0$. The nonlinear proportional constants of the above functions indicate the degree of stability under the vibration level change. The stability of PYW-PZT ceramics estimated by these constants coincides with the results obtained through the heat generation. It was found that $Q_m$ was markedly decreased with increasing the vibration velocity, accompanying a lot of heat generation. The vibration hysteresis and dielectric loss according to the vibration velocity was reduced by doping $Fe_2O_3$to the ceramics. On the contrary, these losses was increased by doping $Nb_2O_5$.

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Studies on the Antioxidant Effects of Mori Folium Extract (상엽(桑葉)추출물의 항산화효과에 대한 연구)

  • Lee, Ji-Eun;Lim, Hyung-Ho;Song, Yun-Kyung
    • The Journal of Korean Medicine
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    • v.28 no.1 s.69
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    • pp.148-158
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    • 2007
  • Objective : The objective of this study was to investigate the antioxidant effects of Mori Folium extract. Methods Total antioxidant status was examined by total antioxidant capacity(TAC) and total antioxidant response(TAR) against potent free radical reactions. The effect of Mori Folium extract was examined by measuring total phenolic content, concentration at which 1,1-dipheny1-2-picrylhydrazyl(DPPH) radical scavenging activity was inhibited, inhibitory effect on lipid peroxidation, and the effect on reactive oxygen species(ROS) generation. Results : 1. TAC and TAR of Mori Folium extract at the concentration of 5 mg/ml were 1.61 and 1.24 mM Trolox equivalents, respectively. 2. Total phenolic content of Mori Folium extract at the concentration of 5 mg/Ml was 1.70 mM gallic acid equivalent. 3. Concentration of Mori Folium extract at which DPPH radical scavenging activity was inhibited by 50% was 2.29 m9/m4 as compared to 100% by Pyrogallol solution as a reference. 4. The inhibitory effect of the extract on lipid peroxidation was examined using rat liver mitochondria induced by FeSO$_4$/ascorbic acid. Mori Folium extract at the concentration of 10 mg/ml significantly decreased thiobarbituric acid reactive substances(TBARS) concentration. The extract prevented lipid peroxidation in a dose-dependent 5. The effect of Mori Folium extract on reactive oxygen species(ROS) generation was examined using a celt-free system induced by hydrogen peroxide FeSO$_4$. Addition of 1 mg/ml of Mori Folium extract significantly reduced dichlorofluorescein(DCf) fluorescence. The extract caused concentration-dependent attenuation of the increase in DCF fluorescence, indicating that the extract significantly prevented ROS generation in vitro. Conclusion ; The antioxidant effects of Mori Folium extract seem to be due, at least in part, to the prevention offree radical-induced oxidation, fllowed by inhibition of lipid peroxidation.

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Analysis for the Economic efficiency of District Heating and Gas Engine Co-generation System comparing with Central Heating System (중앙난방방식을 지역난방.소형열병합난방방식으로 전환시의 경제성 비교 분석)

  • Kim, Kyu-Saeng;Lee, Sang-Hyeok;Hong, Kyung-Pyo;Won, Young-Jae
    • Proceedings of the SAREK Conference
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    • 2007.11a
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    • pp.459-465
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    • 2007
  • This study was conducted to calculate the LCC of a apartment complex with a type of heating system, district heating and cogeneration system. For the purpose of analyzing LCC according to size of apartment complex, 500, 1,500 and 4,000 houses of model apartment selected. This research performs design of heating system and the life cycle cost analysis including an initial cost, energy cost, maintenance and operation cost, replacement cost and renovation cost during the project period(15years). According to the calculated results, 1) Initial cost of cogeneration system with 500, 1500 and 4000 houses is higher than district heating system each of 20%, 13%, 12%. 2) In case of cogeneration system, the payback period by electric generation is 5.21, 4.92 and 4.47 years and saving cost was calculated 29 billion won, 94 billion won and 262 billion won after payback period. 3) Cogeneration system LCC was 1.12, 1.07 and 1.06 times larger than district system with the size of apartment complex. According to the case of this study district heating system is more efficient than cogeneration system in terms of the reduction of LCC. 4) Gas Engine Co-generation System is more efficient than other systems because it can collect progressive part from electric charge progressive stage system. However, the efficiency is decreasing because of raising of fuel bills(LNG) and lowering of power rate for house use. Especially the engine is foreign-made so the cost of maintenance and repair is high and the technical expert is short. 5) District heating is also affected by fuel bills so we should improve energy efficiency through recovering of waste heat(incineration heat, etc.). Also, we should supply district cooling on the pattern of heat using of let the temperature high in winter and low in summer.

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The Variable Acquisition of Discourse Marker Use in Korean American Speakers of English

  • Lee, Hi-Kyoung
    • English Language & Literature Teaching
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    • v.11 no.2
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    • pp.1-18
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    • 2005
  • This study is a preliminary investigation of the nature of discourse marker acquisition in Korean American speakers of English. Discourse markers are of interest because they are not an aspect of language taught through formal instruction either to native or non-native speakers. Therefore, discourse marker use serves as indirect evidence of face-to-face interaction with native speakers and an indicator of integration. In this light, the present study examines the presence of discourse markers in Korean Americans. The markers chosen for analysis were you know, like, and I mean. The data consist of spontaneous speech elicited from interviews. Sociolinguistic variables such as age, sex, and generation (i.e., $1^{st}$, 1.5, $2^{nd}$) were examined. Results show that there appears to be interaction between the variables and discourse marker use. While all speakers showed variable acquisition of markers, younger, female, and 1.5 generation speakers were found to use discourse markers more than other speakers. Although discourse marker use is optional and thus not a linguistic feature that must be necessarily acquired, it is clear that use is pervasive and acquired differentially by English speakers irrespective of whether they are native or not.

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Development and Performance Test of SOFC Co-generation System for RPG (SOFC를 이용한 가정용 열병합 발전시스템 개발 및 성능시험)

  • Lee, Tae-hee;Choi, Jin-Hyeok;Park, Tae-Sung;Choi, Ho-Yun;Yoo, Young-Sung
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.361-364
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    • 2009
  • KEPRI has studied planar type SOFC stacks using anode-supported single cells and kW class co-generation systems for residential power generation. A 1kW class SOFC system consisted of a hot box part, a cold BOP part and a water reservoir. A hot box part contains a SOFC stack made up of 48 cells with $10{\times}10cm^2$ area and ferritic stainless steel interconnectors, a fuel reformer, a catalytic combustor and heat exchangers. Thermal management and insulation system were especially designed for self-sustainable operation. A cold BOP part was composed of blowers, pumps, a water trap and system control units. When a 1kW class SOFC system was operated at $750^{\circ}C$ with hydrogen, the stack power was 1.2kW at 30 A and 1.6kW at 50A. Turning off an electric furnace, the SOFC system was operated using hydrogen and city gas without any external heat source. Under self-sustainable operation conditions, the stack power was about 1.3kW with hydrogen and 1.2kW with city gas respectively. The system also recuperated heat of about 1.1kW by making hot water. Recently KEPRI developed stacks using $15{\times}15cm^2$ cells and tested them. KEPRI will develop a 5 kW class CHP system using $15{\times}15cm^2$ stacks by 2010.

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Studies on the Immuno Modulating Acitivity of Fermented Artemisiae Argyi Folium Extract (애엽(艾葉) 발효 추출물의 면역활성에 관한 연구)

  • Han, Hyo-Sang;Park, Wan-Su;Lee, Young-Jong
    • The Korea Journal of Herbology
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    • v.23 no.3
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    • pp.103-112
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    • 2008
  • Objectives : This research aimed to study the cytotoxicity and immuno modulating activity of fermented Artemisia argyi Lev. et Vant.(Compositae). Methods : Effect of fermented Artemisiae Argyi Folium extracts, which were fermented by Sacchromyces cerevisiae STV89(AFS), on cell viability, generation of ROS within cells, generation of NO and the level of cytokines($TNF-{\alpha}$ and IL-6) was measured using mouse macrophage RAW 264.7 cell. Results : 1. Result of MTT assay conducted to verify the cytotoxicity of fermented Artemisiae argyi folium extract illustrated that, when fermented Artemisiae argyi folium extract was processed for each concentration, there was no excessive induction of cytoxicity in the RAW 264.7 cell. 2. Fermented Artemisiae Argyi Folium extract increased the generation of H2O2 within RAW 264.7 cell as well as significantly increased inhibition of generation of H2O2 in macrophage induced by LPS. 3. Fermented Artemisiae Argyi Folium extract inhibited generation of NO in RAW 264.7 cell, and significantly inhibited increase in generation of NO of macrophage induced by LPS. 4. Fermented Artemisiae Argyi Folium extract, AFS has significantly reduced the increase in the generation of $TNF-{\alpha}$ above 10 ${\mu}g/mL$. 5. Fermented Artemisiae Argyi Folium extract, AFS has significantly reduced the increase in generation of IL-6 above 50 ${\mu}g/mL$. Conclusions : AFS fermented extract produced from Artemisiae Argyi Flium, have increased generation of ROS and reduced generation of NO in RAW 264.7 cell without excessively inducing cytotoxicity of RAW 264.7 cell. In addition, they displayed significant immuno modulating activities including inhibition of generation of $TNF-{\alpha}$ and IL-6 in macrophage, induced by LPS.

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A Construction of the Multiplier and Inverse Element Generator over $GF(3^m)$ ($GF(3^m)$ 상의 승산기 및 역원생성기 구성)

  • 박춘명;김태한;김흥수
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.27 no.5
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    • pp.747-755
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    • 1990
  • In this paper, we presented a method of constructing a multiplier and an inverse element generator over finite field GF(3**m). We proposed the multiplication method using a descending order arithmetics of mod F(X) to perform the multiplication and mod F(X) arithmetics at the same time. The proposed multiplier is composed of following parts. 1) multiplication part, 2) data assortment generation part and 5) multiplication processing part. Also the inverse element generator is constructed with following parts. 1) multiplier, 2) group of output registers Rs, 3) multiplication and cube selection gate Gl, 4) Ri term sequential selection part. 5) cube processing part and 6) descending order mod F(X) generation part. Especially, the proposed multiplier and inverse element generator give regularity, expansibility and modularity of circuit design.

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Synthesis and Properties of Novel T-type Nonlinear Optical Polyurethane Containing Tricyanovinylthienyl Group with Enhanced Thermal Stability of Dipole Alignment

  • Cho, You-Jin;Kim, Mi-Sung;Lee, Ju-Yeon
    • Bulletin of the Korean Chemical Society
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    • v.32 no.2
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    • pp.424-430
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    • 2011
  • A novel T-type polyurethane 7 containing 1-(2,5-dioxyphenyl)-2-(5-(1,2,2-tricyanovinyl)-2-thienyl)ethenes as NLO chromophores, which constitute part of the polymer backbone, was prepared. Polyurethane 7 is soluble in common organic solvents such as DMF and DMSO. It shows a thermal stability up to $270^{\circ}C$ from TGA thermogram with $T_g$ value obtained from DSC thermogram near $155^{\circ}C$. The second harmonic generation (SHG) coefficient ($d_{33}$) of poled polymer film at 1560 nm fundamental wavelength is $3.56{\times}10^{-9}$ esu. Polymer 7 exhibits a thermal stability even at $5^{\circ}C$ higher than $T_g$, and no significant SHG decay is observed below $160^{\circ}C$, which is acceptable for nonlinear optical device applications.

Evaluation of NOx Reduction Efficiency and Emission Factor from Large Combustion Facilities in Seoul (서울지역 대형연소시설에서의 질소산화물 제거효율과 배출계수 산정)

  • 신진호;오석률;김정영;전재식;신정식
    • Journal of environmental and Sanitary engineering
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    • v.18 no.2
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    • pp.27-33
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    • 2003
  • This survey was performed to investigate the NOx emission factors at 3 Municipal Solid Waste Incinerators(MSWI) and 5 Power generation boilers in Seoul. The NOx concentrations were measured before and after control systems. The results were as follows. 1) The NOx reduction efficiencies of Selective Catalytic Reduction (SCR) using ammonia as reducing agent ranged from 53.7% to 89.9%. The NOx reduction efficiencies of SCR using methanol as reducing agent, Non- Selective Catalytic Reduction (NSCR) using ethanol as reducing agent and low-NOx burner were 20.8%, 29.1% and 24.7%, respectively. 2) The NOx emission factors at A-1, A-2 and A-3 facilities of MSWI were 0.786, 0.127 and 0.594 kg Nox/ton fuel, respectively. The factors of A-1 and A-3 facilities were higher than the average value of Korea. 3) The NOx emission factors at B-1, B-2, B-3, B-4 and B-5 facilities of Power generation boiler were 2.109, 0.726, 4.106, 8.378 and 5.168 kg Nox/ton fuel, respectively. The factors of B-4 and B-5 facilities were higher than the average value of Korea.