• Title/Summary/Keyword: 1-Q mode correlation coefficient

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Elemental Correlations of Chemical Compositions in Co-rich Mn-crusts of the Republic of Marshall Islands (마샬공화국 고코발트망간각 화학조성의 원소 상관관계)

  • 황의덕;장세원;김두영
    • Journal of the Mineralogical Society of Korea
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    • v.12 no.2
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    • pp.77-90
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    • 1999
  • Characteristics and variations of chemical compositions in Co-rich crusts occurred in the EEZ of the Republic of Marshall Islands were reviewed. Correlation coefficient analysis, hierarchical cluster analysis, and Q-mode factor analysis for 62 samples were done in this study. All data were selected and gathered from the open file report of the cooperative cruise done by United States Geological Survey with Scripps Institute of Oceanography, University of Hawaii or Korea Ocean Research Development Institute. The average of crust thickness. Co content, and Ni content of 62 samples from the 21 seamounts were 30mm, 0.58 wt% and 0.40%, respectively. The mineral phases and associated elements assigned by correlation coefficients, cluster analysis and Q-mode factor analysis are following four. 1) CFA: P, Ca, CO2, Y, Sr: 2) Mn-oxide mineral: As, Mn, Co, Na: 3) Al-silicate mineral: Pd,Si, Al, Cu, Fe: 4) PGE-bearing mineral: Rh, Pt, Ir.

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Oxygen Transfer Characteristics & Pure Oxygen Application Study on Circulation Flow Rate of the JLB (Jet Loop Bioreactor) (Jet 폭기 시스템의 순환유량에 따른 산소전달 특성 및 순산소 적용성 검토)

  • Park, Noh-Back;Song, Yong-Hyo;Pack, June-Gue;Jun, Hang-Bae
    • Journal of Korean Society on Water Environment
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    • v.25 no.6
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    • pp.896-901
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    • 2009
  • In this study, in order to apply the air and pure oxygen in the Jet Loop Reactor (JLB) in which the oxygen transfer rate is high, differentiate the operation mode according to each air flowrate and liquid flowrate and investigate the oxygen transfer characteristic, an experiment was carried out. The oxygen concentration with the air flowrate ($Q_g$) and liquid flowrate ($Q_L$) was identical but the oxygen transfer coefficient ($K_L{\cdot}a$) is linear depending on degree of two factors. The width of an increase is small in $0.1min^{-1}$ when the air flowrate is 0.2 L/min with increasing the liquid flowrate. Whereas, the increment was exposed to be very high for $1.5min^{-1}$ when the air flowrate was 5 L/min. In the experiments using the pure oxygen, it was 30 mg/L of oxygen concentration finally and it was 3.5 times than using the air. But the time reached the saturated concentration was similar to using the air, and $K_L{\cdot}a$ was similar to using the air too. Analysis between two independent variable and oxygen transfer of the correlation is the same model like $K_L{\cdot}a={0.0161Q_L}^{1.5371}{Q_g}^{0.5433}$ using with coefficient non linear regression analysis. It was resulted that the liquid flowrate were approximately three times than air flowrate on effect to oxygen transfer rate.

Performance Analysis of an Earth Tube Heat Exchanger(I) -Temperature Variation Characteristics and Heat Exchange Performance on the Mode of Continuous Operation (지중매설관 열교환장치의 성능분석(I) -연속운전실험에서의 온도특성 및 열교환성능-)

  • Kim, Y.B.;Paek, Y.
    • Journal of Biosystems Engineering
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    • v.21 no.4
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    • pp.436-448
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    • 1996
  • An earth tube soil air heat exchange system was designed, installed and operated as a single pass heat exchanger to utilize the geothermal energy as an natural energy source. This study was undertaken to investigate the potential of the heating and cooling, energy gain, heat exchange efficiency and coefficient of performance of the system. The system consisted of 30m in length and 30cm in diameter polyethylene pipes buried 2m deep in soil. Maximum heating and cooling performance were 2.51㎾ and 1.26㎾ at the air mass rate of 21cmm. Energy gain and coefficient of performance were the function of temperature difference between outside air and soil temperature. They were expressed as Q=0.33$ imes$$Delta T_{max}$+0.134(㎾) for energy gain and COP=0.44$ imes$$Delta T_{max}$+0.178 for coefficient of performance with correlation factor of 0.95. The mean of heat exchange efficiencies was 85.6%.

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Quantitative Analysis of Lysophosphatidic Acid in Human Plasma by Tandem Mass Spectrometry

  • Kim, Ho-Hyun;Yoon, Hye-Ran;Pyo, Dong-Jin
    • Bulletin of the Korean Chemical Society
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    • v.23 no.8
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    • pp.1139-1143
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    • 2002
  • Analysis of lysophosphatidic acids (LPAs) is of clinical importance as they can serve a potential marker for ovarian and other gynecological cancers and obesity. It is critically important to develop a highly sensitive and specific method for the early detection of gynecological cancers to improve the overall outcome of this disease. We have established a novel quantification method of LPAs in human plasma by negative ionization tandem mass spectrometry (MS-MS) using multiple reaction monitoring (MRM) mode without the conventional TLC step. Protein-bound lipids, LPAs in plasma were extracted with methanol : chloroform (2:1) containing LPA C14:0 as an internal standard under acidic condition. Following back extraction with chloroform and water, the centrifuged lower phase was evaporated and reconstituted in methanol. The reconstituted solution was directly injected into electrospray source of MS/MS. For MRM mode, Q1 ions selected were m/z 409, 433, 435, 437 and 457 which corresponds to molecular mass [M-H]- of C16:0, C18:2, C18:1, C18:0 and C20:4 LPA, respectively. Q2 ions selected for MRM were m/z 79, phosphoryl product. Using MS/MS with MRM mode, all the species of LPAs were completely separated from plasma matrix without severe interferences. This method allowed simultaneous detection and quantification of different species of LPAs in a plasma over a linear dynamic range of 0.01-25 ㎛olL-1 . The detection limit of the method was 0.3 pmol/mL, with a correlation coefficient of 0.9983 in most LPAs analyzed. When applied to the plasmas of normal and gynecological cancer patients, this new method differentiated two different groups by way of total LPA level.

Weed Emergence in Orchard and Comparison of Weeding Performance of Some Orchard-Herbicides (Single and Mixture Products) (과수원(果樹園)의 잡초발생(雜草發生)과 제초제유형(除草劑類型) (단제(單劑) 및 혼제(混劑))별(別) 살초특성(殺草特性)의 비교연구(比較硏究))

  • Guh, J.O.;Cho, Y.W.;Lee, Y.M.
    • Korean Journal of Weed Science
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    • v.6 no.1
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    • pp.85-96
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    • 1986
  • From the two differently located orchards (even-site with adult tree and slope-site with young tree), weed emergence and the effect of various orchard herbicides on them were comparatively experimented. Weed emergence was assessed in emergence frequency, biomass, relative frequency, and herbicide responses were checked with the variarions in the above weed emergence characters and the weeding values. Herbicides applied were paraquat, glyphosate, oxyfluorfen, napropamide and ustinex using the recommended rates, respectively. Weeds emerged were 7 life-forms, 23 families and 45 species. Among other families, weeds Umbelliferae, Commelinaceae, Gramineae and Polygonaceae couldn't classified in any similarly correlated cluster. However, according to "1-Q mode cluster analysis" of each herbicide performances, "paraquat or glyphosate" with "napropamide or oxyfluorfen" were selected as the most unrelated herbicide pairs expecting the best combination value in mixture model, respectively.

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