• Title/Summary/Keyword: 1-Benzyl-3-methyl imidazolium hydrogen sulphate [bnmim][$HSO_{4}$]

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1-Benzyl-3-Methyl Imidazolium Hydrogen Sulphate [bnmim][HSO4] Promoted Synthesis of α-Aminophosphonates

  • Sadaphal, Sandip A.;Sonar, Swapnil S.;Kategaonkar, Amol H.;Shingare, Murlidhar S.
    • Bulletin of the Korean Chemical Society
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    • v.30 no.5
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    • pp.1054-1056
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    • 2009
  • We have demonstrated a one-pot three component coupling of an aldehydes, an amines, and triethyl phosphite using 1-benzyl-3-methyl imidazolium hydrogen sulphate [bnmim][][$HSO_{4}$] as an efficient catalyst. All the reactions proceed under solvent-free conditions at room temperature. This methodology afforded the corresponding $\alpha$-aminophosphonates in shorter reaction times with excellent yields.