• Title/Summary/Keyword: 1-3 복합체

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Effect of EuO$_3$addition on hydrothermal stability of t-ZrO$_2$/Al$_2$O$_3$composites (t-ZrO$_2$/Al$_2$O$_3$복합체 상 안정성에 대한 Eu$_2$O$_3$첨가 효과)

  • 이득용;김대준;최성갑;이명현
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.3
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    • pp.233-238
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    • 2000
  • t-$ZrO_2/Al_2O_3$composites having a superior biocompatability and phase stability were prepared by adding 0~4 mol% of $Eu_2O_3$and sintered for 1 h at $1600^{\circ}C$ to evaluate phase stability, chromaticity and mechanical properties of the composites. No tetragonal to monoclinic phase transformation was observed for the composites containing $Eu_2O_3$after heat treatment for 20 h at $180^{\circ}C$ under 3.5 MPa water vapor pressure condition. As $Eu_2O_3$content increased, the color of the composites was changed from a slight white ivory to a light pink. The strength and the fracture toughness of the composites containing $Eu_2O_3$were above 620 MPa and 7.6 MPa.$m^{1/2}$, respectively, when $Eu_2O_3$was added up to 3 mol%.

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Effects of Sus1, a component of TREX-2 complex, on growth and mRNA export in fission yeast (분열효모에서 TREX-2 복합체의 구성요소인 Sus1이 생장 및 mRNA 방출에 미치는 영향)

  • Bae, Soo Jeong;Yoon, Jin Ho
    • Korean Journal of Microbiology
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    • v.53 no.1
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    • pp.49-54
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    • 2017
  • Sus1 / ENY2 is a tiny conserved protein that is involved in chromatin remodeling and mRNA biogenesis. Sus1 is associated to two nuclear complexes, the transcriptional coactivator SAGA and the nuclear pore associated TREX2. In fission yeast, Schizosaccharomyces pombe, ortholog of Sus1 / ENY2 was identified from the genome database. Tetrad analysis showed that the S. pombe sus1 is not essential for growth. However, deletion of the sus1 gene caused cold-sensitive growth retardation with slight accumulation of $poly(A)^+$ RNA in the nucleus. And the Sus1-GFP protein is localized mainly in the nucleus. Yeast two-hybrid analysis and co-immunoprecipitation experiment showed that Sus1 interacts with Sac3, another subunit of TREX2 complex. These results suggest that S. pombe Sus1 is also involved in mRNA export from the nucleus as a component of TREX-2 complex.

Oxygen Reduction Mechanism and Electrode Properties of (La,Sr)$MnO_3$-YSZ Composite Cathode for Solid Oxide Fuel Cell (Part II: Electrode Properties) (고체산화물 연료전지용 (La,Sr)$MnO_3$-YSZ 복합체 양극의 산소환원 반응기구 및 전극 특성 (Part II: 전극 특성))

  • 김재동;김구대;이기태
    • Journal of the Korean Ceramic Society
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    • v.38 no.1
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    • pp.93-99
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    • 2001
  • (La,Sr)MnO$_3$(LSM)-YSZ 복합체 양극에 있어서 소결온도 및 전극두께와 cathodic potential이 전극 특성에 미치는 영향을 고찰하였다. 양극의 소결은 삼상계면의 양을 결정하는 중요한 변수로 LSM 단미 양극과 YSZ가 40 wt% 포함된 LSM-YSZ 복합체 양극 모두 120$0^{\circ}C$에 소결했을 때 가장 낮은 분극저항을 나타내었다. 또한 양극 후막의 두께가 얇아지면 양극의 in-plane 저항이 증가하여 ohmic 저항이 증가하였는데, LSM-YSZ 복합체 양극의 경우 약 30$mu extrm{m}$ 정도의 전극두께가 가장 효과적인 전극 특성을 나타내었다. 한편, LSM-YSZ 복합체 양극에 -0.5 V의 cathodic potential을 인가함에 따라 양극에서 일어나는 산소환원반응의 활성이 증가하였는데, 1가 산소이온의 표면확산반응의 분극저항은 감소하였으나, 고주파수 영역에서 나타나는 산소이온전달반응의 저항은 거의 변화하지 않았다. 이것은 Mn의 환원에 의한 양극표면에 생성된 산소공공에 기인한다.

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Preparation of Electrically Conductive Composites Filled with Nickel Powder and MWCNT Fillers (다중벽 탄소나노튜브와 니켈 분말을 포함하는 전도성 복합체 제조)

  • Kim, Sunghoon;Park, Seonghwan;Kwon, Jaebeom;Ha, KiRyong
    • Korean Chemical Engineering Research
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    • v.54 no.3
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    • pp.410-418
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    • 2016
  • In this study, we prepared electrically conducting composites using epoxy resin of diglycidyl ether of bisphenol A (DGEBA) as a matrix, triethylenetetramine (TETA) as a hardener and nickel powder or multi-walled carbon nanotubes (MWCNTs) grafted with $-NH_2$ groups (MWCNT-$NH_2$) as electrically conducting fillers. Electrical conductivity of composite films were measured by coating on the slide glass with a doctor blade. We measured modification reactions of MWCNT and reaction of MWCNT-$NH_2$ with DGEBA epoxy resin by fourier transform infrared spectrometer (FTIR), thermogravimetric analyzer (TGA) and elemental analyzer (EA). Morphology of composites was investigated by scanning electron microscope (SEM) and sheet resistances of composites were measured by 4-point probe. We found $(9.87{\pm}1.09){\times}10^4{\Omega}/sq$ of sheet resistance for epoxy composite containing both 40 wt% nickel powder and 0.5 wt% of MWCNT-$NH_2$ as fillers, equivalent to epoxy composite containing 53.3 wt% nickel powder only as a filler.

A Study on Mechanical Properties of Strand/Particle Composites(I) - Effect of Layer Constructions - (스트랜드/파티클 복합체의 기계적 성질에 관한 연구(I) - 단면구성이 기초물성에 미치는 영향 -)

  • Kim, Yu-Jung;Shibusawa, Tatsuya
    • Journal of the Korean Wood Science and Technology
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    • v.28 no.3
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    • pp.1-8
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    • 2000
  • To develop the technology of producing structural board from low grade materials, an attempt was made to produce strand/particle composites from split wood strand(S) and particle(P) of (Cryptomeria japonica D. Don), which changed the layer construction and the ratio of S/P. The influence of layer construction on board properties was determined, focusing on the number and alignment of the S layers. The effect of weight ratio of S/P (3:7, 1:1, 7:3) on mechanical properties was also discussed on seven layered panel. Mechanical properties were determined from static bending tests to give parallel and perpendicular modulus of rupture (MOR) and modulus of elasticity (MOE), and the internal bond (IB) strength. In general, the surface strand layers contributed to the MOR and MOE. The parallel MOR and MOE values were the largest for the single layered S panel (only Slayers: S1), but the perpendicular MOR and MOE was the smallest. Perpendicular MOR and MOE were the largest for seven layered composite that had two cross oriented strand layers (SPSPSPS: SP7). Specimens retained more than half of their MOE and MOR after two hours in boiling water and one hour soaking. IB was the largest for the panel having only P layers, however, differences in IB strength were not identified among the other multi-layered composite panels thus the effect of layer construction on IB strength was small. Thickness swelling (TS) and surface roughness were smaller for the composite having P layers on the surface than for those having S layers. The addition of strands did not enhance the mechanical properties (MOR, MOE, IB). TS values for the panels, with which the S/P ratio was over than 1:1, was the similar to the value for the single layered S panels.

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Low-temperature phase stability and mechanical properties of $Y-Nb-TZP/Al_2O_3$ compoites ($Y-Nb-TZP/Al_2O_3$ 복합체의 저온 상안정성 및 기계적 특성)

  • 이득용;김대준;조경식;장주웅
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.4
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    • pp.634-639
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    • 1998
  • $Y_2O_3$ and $Nb_2O_5$ co-doped zirconia composites containing 10~30 vol% $Al_2O_3$ with two different particle sizes were sintered for 5 h at $1550^{\circ}C$ to evaluate low-temperature phase stability of the composite using X-ray diffractometry after heat-treatments for 1000 h at $250^{\circ}C$ in air or for 5 h at $180^{\circ}C$ in 0.3 MPa $H_2O$ vapor pressure. No tetragonal to monoclinic phase transformation during degradation, so called enhanced low-temperature phase stability, was observed for all composites. It is concluded that Nb addition to the composite for the phase stability is more effective than $Al_2O_3$ addition. The optimum combination of strength (670 MPa) and fracture toughness ($7.1{\textrm} {MPam}^{1/2}$) were obtained for the composite containing 20 vol% of $Al_2O_3$ with 2.8 $\mu$m to 0.2 $\mu$m, the flexural strength increases but the fracture toughness decreases.

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Geometric and Kinematic Characteristics of Fracture System in the Sancheong Anorthosite Complex, Korea (산청 회장암복합체 내 발달하는 단열계의 기하학적·운동학적 특성)

  • Lee, Deok-Seon;Kang, Ji-Hoon
    • The Journal of the Petrological Society of Korea
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    • v.25 no.4
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    • pp.389-400
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    • 2016
  • The study area, which is located in the southeastern part of the Jirisan province of the Yeongnam massif, Korea, consists mainly of the Precambrian Sancheong anorthosite complex and the Jirisan metamorphic rock complex, the Mesozoic granitoids which intruded them. Several fracture sets with various geometric indicators, which determine their relative timing and shear sense, are well observed in the Sancheong anorthosite complex. The aim of this study is to determine the development sequence of extension fractures, the movement sense and development sequence of shear fractures in the Sancheong anorthosite complex on the basis of detailed analysis of their geometric indicators. This study suggests fracture system of the Sancheong anorthosite complex was formed at least through five different fracturing events, named as Dn to Post-Dn+3 phases. (1) Dn phase: extension fracturing event of NNW trend. The fracture set experienced the reactivations of dextral ${\rightarrow}$ sinistral shearing with the change of stress field afterward. (2) Dn+1 phase: extension fracturing event of (N)NE trend. The fracture set experienced the reactivations of sinistral ${\rightarrow}$ sinistral ${\rightarrow}$ dextral. (3) Dn+2 phase: extension fracturing event of NW trend. The fracture set experienced the activated of dextral shearing. (4) Dn+3 phase: extension fracturing event of N-S trend. (5) Post-Dn+3 phase: extension fracturing event of (E)NE trend. Dn deformation formed during the early Songnim orogeny. Dn+1 deformation formed during the late Songnim orogeny. Dn+2 deformation formed during the Daebo orogeny. Dn+3 deformation formed during the Bulguksa orogeny.

고온가압소결한 SiCf/SiC 복합체에서 보호층으로써의 SiC 층이 기계적 물성에 미치는 영향

  • Jeong, Myeong-Hun;Kim, Dae-Jong;Kim, Won-Ju;Yun, Sun-Gil;Park, Ji-Yeon
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.105.1-105.1
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    • 2012
  • 고온가압소결으로 제조된 SiCf/SiC 복합체는 부식과 침식에 강하고 우수한 열적 성질과 고온에서의 높은 기계적 강도를 유지하는 장점을 가진 복합체다. 복합체의 파괴인성은 섬유와 기지 사이에 존재하는 열분해탄소 (PyC) 계면층에 의해 큰 영향을 받는데, 고온가압소결중 첨가되는 소결조제 ($Y_2O_3$, MgO, $Al_2O_3$)와 반응하여 계면이 손상되어 복합체의 기계적 특성치가 낮아지는 결과를 보였다. 본 연구에서는 계면의 손상을 보호하고자 PyC 계면상 위에 SiC 층을 증착하였는데 계면층과 SiC 층의 증착은 화학기상 증착법(CVD)을, 기지채움 공정은 전기영동법(EPD)과 고온가압소결방법(Hot Pressing)을 이용하여 복합체를 제조하였다. Tyranno-SA 섬유에 소스가스인 메탄을 열분해 하여 200nm 두께로 PyC 계면상을 증착하고, 두께를 달리하여 보호층으로써의 SiC 층을 single 과 double layer로 증착하였다. SiC 나노분말과 소결 첨가제인 $Y_2O_3$, $Al_2O_3$, MgO를 첨가한 슬러리를 전기영동법(EPD)을 이용하여 섬유내부에 슬러리를 함침시켰고, 이러한 프리폼을 $1750^{\circ}C$/20MPa의 조건으로 고온 가압소결 하여 $SiC_f$/SiC 복합체를 제조하였다. 이렇게 single layer와 double layer로 제조된 $SiC_f$/SiC 복합체에 대해 밀도와 미세구조를 관찰하였고, 기계적 특성을 비교하여 보호층으로써의 SiC 증착효과를 고찰하고자 하였다.

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Oxygen Reduction Mechanism and Electrode Properties of (La,Sr)$MnO_3$-YSZ Composite Cathode for Solid Oxide Fuel Cell (Part I: Oxygen Reduction Mechanism) (고체산화물 연료전지용 (La,Sr)$MnO_3$-YSZ 복합체 양극의 산소환원 반응기구 및 전극 특성 (Part I: 산소환원 반응기구))

  • 김재동;김구대;이기태
    • Journal of the Korean Ceramic Society
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    • v.38 no.1
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    • pp.84-92
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    • 2001
  • (La,Sr)MnO$_3$(LSM)-YSZ 복합체 양극의 산소환원 반응기구에 대해 고찰하였다. YSZ를 첨가함에 따라 복합체 양극의 ohmic 저항이 증가하고, 분극 저항은 YSZ를 40 wt%~50 wt% 혼합하였을 때 최소값을 나타내었다. 또한 LSM-YSZ 복합체 양극의 산소환원 반응기구는 1가 산소이온의 표면확산과 산소이온전달반응에 의해서 지배됨을 알 수 있었다. 임피던스 분석 결과에 따르면 고주파수 영역에서 나타나는 반원은 산소이온전달반응으로 산소분압 의존성이 거의 없고, YSZ가 40 wt% 첨가되었을 때 최소값을 나타내었다. 중간주파수 영역에서 나타나는 반원은 1가 산소이온의 표면확산반응으로 산소분압 의존성은 약 1/4이고, YSZ가 40~50 wt% 첨가되었을 때 최소값을 나타냈다. 한편, 저주파수 영역에 나타나는 반원은 가스확산반응으로 산소분압 의존성이 1이고, 온도에 따른 의존성이 거의 없었다.

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3차원 쾌속조형 기술의 마이크로/나노 복합체를 이용한 기능성 경사 구조 제작에의 응용

  • Jeong, Ha-Seung
    • Journal of the KSME
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    • v.50 no.1
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    • pp.55-57
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    • 2010
  • 3차원 쾌속조형(RP: Rapid Prototyping) 기술의 일종인 Selective Laser Sintering(SLS)을 기능성 경사구조(FGM: Functionally graded Materials)의 제작에 응용하기 위하여 마이크로/나노 복합체의 제작 공정을 최적화하고 실험으로 1차원의 FGM 제작을 수행하였다.

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