• Title/Summary/Keyword: 1-인산암모늄

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Effect of Ammonium Phosphate Concentration on the Growth of Recombinant E. coli (재조합 대장균의 세포성장에 대한 인산암모늄 농도의 영향)

  • 김종수;석근영차월석
    • KSBB Journal
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    • v.11 no.4
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    • pp.389-397
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    • 1996
  • The growth of recombinant E. coli and formation of the by-products were investigated. Ammonium phosphate is known to affect the cell growth as well as the enzyme formation. When initial ammonium phosphate concentration was 0.5g/L, cell mass was 4.1g/L. By adding tryptone to the medium, acetic acid formation increased while lactic acid formation decreased. In cultivating recombinant E. coli, lactic acid and acetic acid turned out to be important by-products which affected cell yield and growth rate. Initial ammonium phosphate and tryptone concentration were optimized in our research and can be applied for other culture of recombinant E. coli.

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Combustive Characteristics of Pinus Rigida Treated with Ammonium Salts (암모늄염으로 처리된 리기다 소나무의 연소특성)

  • Chung, Yeong-Jin;Jin, Eui
    • Fire Science and Engineering
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    • v.24 no.5
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    • pp.115-121
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    • 2010
  • This study was performed to test the combustive properties of Pinus rigida-based materials by the treatment of ammonium salts. Pinus rigida plate was soaked in three 20 wt% ammonium salt solutions such as ammonium sulfate (AMSF), monoammonium phosphate (MAPP), and diammonium phosphate (DAPP), respectively, at the room temperature. After drying specimen treated with chemicals, combustive properties were examined by the cone calorimeter (ISO 5660-1). Comparing with virgin pinus rigida plate, specimens treated with the ammonium salts had lower combustive properties and It is supposed that the combustion-retardation properties improved due to the treated ammonium salts in the virgin Pinus rigida. Also, the specimens with treated ammonium salts showed both the lower peak heat release rate (PHRR) and lower total heat release (THR) than those of virgin plate.

A Comparative Study on the Effect of Fire Retardancy of the Plywood Treated by Ammonium Sulphate and Monoammonium Phosphate (황산암모늄과 제 1 암모늄처리(處理) 합판(合板)의 내화효과에 관(關)한 비교연구(比較硏究))

  • Lee, Phil-Woo;Kim, Cheol-San
    • Journal of the Korean Wood Science and Technology
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    • v.11 no.3
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    • pp.23-30
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    • 1983
  • This experiment was carried out for diminishing the material loss and the damage of human life due to the fire disaster by treating plywood with fire retardant chemical solution. At this study, we observed and measured chemical retention, burning point, maximum flame length, flame exausted time, carbonized area, and weight loss of plywood treated by each solution of ammonium sulphate [$(NH_4)_2SO_4$] and monoammonium phosphate [$NH_4H_2PO_4$]. Obtained results at the study may be summarized as follows: 1. In case of monoammonium phosphate-treated plywood, every tested item of fire retardancy was shown more excellent at the 25% chemical concentration and shown also at 9 hours treatment except maximum flame length compared with ammonium sulphate-treated plywood. 2. However in case of ammonium sulphate-treated plywood, 6 hours treatment of fire retardancy was better than 9 hours treating time. 3. Monoammonium phosphate was generally better than ammonium sulphate in every tested item.

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Study on the Effect of the ABC Dry Chemical on Wood in Pyrolysis (ABC 분말소화약제의 열분해 시 목재에 미치는 영향에 관한 연구)

  • Ko, Wang-Youl;In, Se-Jin
    • Fire Science and Engineering
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    • v.32 no.3
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    • pp.1-7
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    • 2018
  • This study the effect of pyrolysis products ABC dry chemical and of monoammonium phosphate on wood surface. When the pyrolysis product was removed from the wood surface, monoammonium phosphate was removed due to the high viscosity of the transparent pyrolysis product, but the ABC dry chemical was removed in a lump form. Thermal analysis showed that the pyrolysis characteristics of each sample were similar but the weight of pyrolysis residue was 55.9% for ABC dry chemical and 25.2% for monoammonium phosphate. The additives added to the ABC dry chemical also affect the weight of the pyrolysis residue and the fire protection effect of metaphosphoric acid.

Effect of Phosphate Types on the Strength and pH of Magnesia-Phosphate Composites (마그네시아 인산염 복합체의 강도 및 pH에 대한 인산염 종류의 영향)

  • Lee, Kyung-Ho;Yang, Keun-Hyeok
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.2
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    • pp.135-140
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    • 2017
  • As an elementary investigation to develop vegetation concrete with a relatively low pH value, magnesia-phosphate composites (MPC) were examined according to the phosphate types including Monoammonium, Monosodium, Monopotassium, Monocalcium, Diammonium, Disodium, Dipotassium, and Diacalcium phosphates. All of the MPC binders, the ratio of magnesia to phosphate was fixed to be 7:3. MPC mortars activated with Disodium, Dipotassium, and Diacalcium phosphates showed no compressive strength gain, even at age of 28 days. Meanwhile, MPC mortars with Monoammonium and Monosodium phosphates developed 28-day compressive strength of more than 34MPa, and showed a relatively low pH value below 9.8. Hence, Monoammonium and Monosodium phosphates have potentials as an activator for producing MPC-based vegetation concrete.

Studies on the Fire Retardant Treatment of Wet Forming Mat for Hardboard (경질섬유판(硬質纖維板)의 습식(濕式)매트 내화처리(耐火處理)에 관(關)한 연구(硏究))

  • Shin, Dong-So;Lee, Hwa-Hyoung;Shim, Chong-Supp
    • Journal of the Korean Wood Science and Technology
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    • v.10 no.3
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    • pp.180-188
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    • 1982
  • This study was carried out to make hardboard fire retardants and to examine the properties of the hard-board treated with them. The fire retardant treatment was achieved by surface impregnation of water soluble retardant chemicals into the forming mat with 55 percent of moisture content. followed by the hot pressing process. Ammonium monophosphate, ammonium diphosphate, sodium borate, and boric acid were used as the fire retardants. Fire retardant test was carried out by using the differential thermal analysis thermogram. The results are summarized as follows: 1. Fire retardant-treated hardboard showed higher values of the specific gravity. water absoption, and flexural strength than those of untreated hardboard. Especially, the treatment of ammonium monophosphate gave the best results in the flexural strength, and a 10 gr/$ft^2$ loading of the fire retardant compound of ammonium monophoshate, ammonium diphosphate, and sodium borate drew the best flexural strength value among the three different experimental loadings of 10, 20 and 30 gr/$ft^2$. 2. There were no definite differences in moisture content between the fire retardant-treated hardboard and the untreated hardboard. 3. The fire retardant compound of ammonium monophosphate, ammonium diphosphate, and sodium borate resulted in the best fire retardancy, and its fire retardancy was increased in proportion to the increase of loading.

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Oxygen Index of Fire-Retardant-Treated Plywood in Burning Test (산소지수법(酸素指數法)에 의한 내화처리합판(耐火處理合板)의 연소시험(燃燒試驗))

  • Lee, Phil Woo;Eom, Young Geun;Kim, Hyun Joong
    • Journal of Korean Society of Forest Science
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    • v.78 no.4
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    • pp.419-424
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    • 1989
  • To obtain relative effectiveness in fire resistance among fire retardant chemicals, oxygen indices were determined for 3.5 mm thick, three-ply, meranti plywoods, treated with 5 commercial chemicals and water and then press-dried, through Up and Down method following oxygen index test of ASTM D 2863-77. The oxygen indices obtained were 28.4 for ammonium sulfate, 26.9 for monoammonium phosphate, 43.4 for diammonium phosphate, 30.1 for borax-boric acid, 32.4 for minalith, and 25.5 for water. Therefore, diammonium phosphate was found to rank first in fire-retardant effectiveness, followed by minalith, borax-boric acid, ammonium sulfate, and monoammonium phosphate in turn, judging from the fact that highly flammable materials are likely to have a low oxygen index.

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A study on synthesis of polyurethane dispersion by $H_{12}MDI$ and how effect to mechanical properties by ammonium dihydrogen phosphate ($H_{12}MDI$를 이용한 수분산 폴리우레탄 수지의 합성 및 ammonium dihydrogen phosphate에 의한 물성변화에 관한 연구)

  • Lee, Joo-Youb;Nam, Sang-Sung
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.1
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    • pp.74-82
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    • 2014
  • For this research, prepared ammonium dihydrogen phosphate aqueous solution and polyurethane dispersion. Use these resin, this article has been analyzed about change of mechanical properties by increasing amount of ammonium dihydrogen phosphate aqueous solution in polyurethan resin on coated leather and dried film. According to measure data for solvent resistance, DPU(polyurethane dispersion) resin and DPU-AD1, D2, D3(samples of polyurethaneresin with ammonium dihydrogen phosphate aqueous solution) had good property. As known in the results, increase of ammonium dihydrogen phosphate constant did not influence to big change of polyurethane resin properties. As test of tensile strength, DPU had highest tensile characteristic($3.114kg_f/mm^2$) and DPU-AD3 had lowest tensile characteristic($2.510kg_f/mm^2$). As same as tensile characteristic, abrasion test determined DPU(50.5 mg.loss) had highest properties. In elongation case, DPU had best properties(602 %) in this experiment.

Effect of burn additives on the combustibility of cigarette paper (조연제가 궐련지 연소성에 미치는 영향에 관하여)

  • SEONG, Y.S.;KIM, Y.H.;RHIM, K.S.;RAH, H.H.
    • Journal of the Korean Society of Tobacco Science
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    • v.8 no.1
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    • pp.33-39
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    • 1986
  • 조연제종류 및 함량 변화가 궐련지의 연소성과 회색상에 미치는 영향을 연구한 결까 flax와 kenaf의 연소속도 띤 회고결성이 NBKP보다 양호하였으며 탄산칼숨 함량이 증가함에 따라 각 펄프 공히 연소속도는 빨라지나 회고결성은 저하되었다. 구연산·초산·주석산나트륨은 첨가량이 3%까지 증가되어도 연소속도에는 큰차가 없으나 4호이상부터 빨라지는경향이었다. 인산나트륨은 함량이 증가하면서 연소속봉는 늦어진 반면 회고결성은 양호해졌다. 구연산나트룸에 요소·푸말산나트륨·인산암모늄·인산·말레인산나트륨 및 guanyl urea phosphate를 첨가시 인산암모늄의 회죈변동율이 170%로 회고결성이 가장 양호하였으나 연소속도는 대체로 늦어지는 경향이다. 조연제의 함량이 증가함에 따라 회의 백색도는 55전후에서 30으로 감소하는 경향이다.

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Studies on Press Drying of Fire-Retardant Treated Plywood (내화처리합판(耐火處理合板)의 열판건조(熱板乾燥)에 관(關)한 연구(硏究))

  • Kim, Jong Man
    • Journal of Korean Society of Forest Science
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    • v.56 no.1
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    • pp.1-25
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    • 1982
  • Plywood used for construction as a decorative inner material is inflammable and can cause fire accidents. causing destruction of human life and property. To diminish the fire disaster, fire retardant plywood is indeed required. In the methods of manufacturing the fire retardant plywood, a soaking method is occasionally used. However after soaking plywood into fire retardant chemical solutions redrying of soaked plywood is of the utmost importance. In this study 3.5mm and 5.0mm thickness plywoods were selected for fire retardant treatment. Treating solutions were prepared for 20% dilute solutions of ammonium sulfate, monoammonium phosphate, diammonium phosphate, borax-boric acid minalith, and water solution, 1-, 3-, 6-, and 9 hour-soaking treatments in borax-boric acid and minalith, and 6- and 9 hours in the other chemicals were applied and after the treatment hot drying was applied to treated plywoods at $90^{\circ}C$, $120^{\circ}C$ and $150^{\circ}C$ of press temperature. Drying rates, drying curves, water absorption rates of fire retardant chemicals, weight per volume and fire retardant degree of plywood were investigated. The results may be summarized as follows: 1) In the 9 hours-soaking treatment of fire retardants by hot and cold bath method, the chemical retentions of 3.5mm thickness plywood could be attained within the range ($1.125-2.25kg/(30cm)^3$) of minimum retention specification as follows: $1.353kg/(30cm)^3$ in monoammonium phosphate, $1.331kg/(30cm)^3$ in diammonium phosphate, $1.263kg/(30cm)^3$ in ammonium sulfate, $1.226kg/(30cm)^3$ in borax-boric acid. But the chemical retention, $0.906kg/(30cm)^3$, in minalith could not be attained within the range of minimum retention specification. And also in case of 5.0mm thickness plywood, chemical retentions, as $1.356kg/(30cm)^3$ and $1.166kg/(30cm)^3$ respectively, of ammonium sulfate and diammonium phosphate could be attained within the range minimum retention specification, but the other fire retardant chemicals could not. 2) In the 6- and - hours-soaking treatments of 3.5mm and 5.0mm thickness plywood, the drying curve sloped of chemical treated plywood was smaller than that of water treated. The drying rate related to thickness of treated plywood, was about three times as fast in 3.5mm thickness plywood compared with 5.0mm thickness plywood. 3) In the treatment at $120^{\circ}C$ of hot platen temperature, the drying rates of chemical-treated plywood showed the highest quantity in diammonium phosphate of 3.5mm and 5.0mm thickness plywood. But the drying rate of water treated plywood was highest during the 6- and 9 hours-soaking treatments. 4) The drying rate remarkably increased with proportion to increase of the platen temperature, and the values were respectively 1.23%/min., 6.54%/min., 25.75%/min. in hot platen temperature of $90^{\circ}C$, $120^{\circ}C$, $150^{\circ}C$ in 3.5mm thickness plywood and 0.55%.min., 2.49%/min., 8.19%/min. in hot platen temperature of $90^{\circ}C$, $120^{\circ}C$, $150^{\circ}C$ in 5.0mm thickness plywood. 5) In the fire retardant degree of chemical treated plywood, the loss in weight was the smallest in diammonium phosphate, next was in monoammonium phosphate and ammonium sulfate, and the greatest was in borax-boric acid and minalith. And the fire-retardant effect in burning time, flame-exhausted time and carbonized area were greatest in diammouniun phosphate, next were in monoammonium phosphate and ammonium sulfate, and the weakest were in borax-boric acid and minalith.

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