• Journal of the Korean Institute of Intelligent Systems
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• v.15 no.7
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• pp.846-851
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• 2005

In this paper, we propose Genetic Algorithms(GAs)-based Optimized Polynomial Neural Networks(PNN). The proposed algorithm is based on Group Method of Data Handling(GMDH) method and its structure is similar to feedforward Neural Networks. But the structure of PNN is not fixed like in conventional neural networks and can be generated in a dynamic manner. As each node of PNN structure, we use several types of high-order polynomial such as linear, quadratic and modified quadratic, and it is connected as various kinds of multi-variable inputs. The conventional PNN depends on the experience of a designer that select the number of input variables, input variable and polynomial type. Therefore it is very difficult to organize optimized network. The proposed algorithm leads to identify and select the number of input variables, input variable and polynomial type by using Genetic Algorithms(GAs). The aggregate performance index with weighting factor is proposed as well. The study is illustrated with tile NOx omission process data of gas turbine power plant for application to nonlinear process. In the sequel the proposed model shows not only superb predictability but also high accuracy in comparison to the existing intelligent models.

• Resources Recycling
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• v.12 no.3
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• pp.13-24
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• 2003

The production characteristics of activated carbon from waste walnut shell have been investigated by taking activation temperature, activation time, amount of activating agent, and kind of activating agent as the major influential factors. The adsorption capacity of the activated carbon which was produced using phosphoric acid as the activating agent increased with activation temperature and showed its greatest value at about $550^{\circ}C$. Yield for activated carbon was observed to decrease continuously as the activation temperature was raised. The optimal activation time for the highest adsorption capacity was found to be about 2 hr, and as the activation time increased the yield for activated carbon was showed to decrease continuously. The increase in the amount of activating agent resulted in the increase of the yield for activated carbon, however, excessive amount of activating agent deteriorated its adsorption capacity reversely. The variations of the microstructure of activated carbon observed by SEM with several influential factors, correlated very well with its changes in the adsorbability with the same factors and the kind of activating agent was found to play an important role in the determination of the adsorption capacity of activated carbon. To investigate the adsorption characteristics of the produced activated carbon, the adsorption reactions of $Cu^{2+}$ ion were examined using the produced activated carbon as the adsorbent. In general, the kinetics of the adsorption of $Cu^{2+}$ ion was observed to follow a 2nd-order reaction and the rate constant for adsorption reaction increased as the initial concentration of adsorbate was diminished. The equilibrium adsorption of $Cu^{2+}$ was explained well with Freundlich model and its adsorption reaction was found to be endothermic. The activation energy for adsorption was calculated to be 13.07 kcal/mol, which implied that the adsorption reaction was very irreversible, and several thermodynamic parameters of adsorption reaction were estimated using van't. Hoff equation and thermodynamic relationships.

• Journal of the Korean Chemical Society
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• v.37 no.12
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• pp.995-1002
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• 1993

The thermal decomposition of trimethylaluminum (TMA) with ammonia has been investigated by in-situ Fourier transform infrared spectroscopy. The spectroscopic reaction cell, which permits heating interna lly up to 1100$^{\circ}C$, consists of stainless-steel hexagonal-port chamber containing two NaCl windows installed in parallel. In this work, the stoichiometric reaction between TMA and $NH_3$ is found to be completed immediately after mixing. FTIR spectra observed in the range of temperature 25∼1100$^{\circ}C$ show that TMA and TMA : $NH_3$ adduct decompose into methane as a predominant product around 500$^{\circ}C$. The assignments of the IR bands due to the gaseous TMA, $NH_3$ and TMA : $NH_3$ adduct are attempted on the basis of the published data. Furthermore, the decomposition of TMA can be described as a first-order reaction. Kinetic data about the decompositon of TMA and TMA : $NH_3$adduct will also be discussed.

• Korean Chemical Engineering Research
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• v.60 no.3
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• pp.377-385
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• 2022

Surface morphology and adsorption characteristics of charcoals prepared from Korean traditional kiln were analyzed, and their moisture adsorption capacities were examined with respect to humidity and temperature change. Moisture adsorption capacities of red-clay powder, activated carbon fiber fabric (ACF fabric) and activated carbon fiber paper(ACF paper) were also examined to compare with those of charcoals. Moisture adsorption capacity of charcoal was low less than 45% humidity due to its hydrophobic property, but it slowly and linearly increased as increasing the humidity. Moisture adsorption capacity of red-clay powder was similar to charcoal at low level humidity, it increased exponentially as increasing the humidity showing Type V adsorption isotherm. Therefore, the weather forecast annal prepared by employee of weather centre in Joseon Dynasty is experimentally approved. ACF fabric and ACF paper show excellent moisture adsorption capacities, which can be used to humidity measuring sensor. Adsorption isotherm of charcoal slice was peculear showing the mixed Type I and Type IV due to low-pressure hysteresis that was occurred from embedment of nitrogen in crevice of charcoal. The specific surface area of charcoal increased by grinding charcoal slice to powder, resulted in increasing the desorption amount of adsorbent at low relative pressure.

• Korean Journal of Soil Science and Fertilizer
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• v.22 no.3
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• pp.221-227
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• 1989

This study was conducted to understand the influence of soil compaction on root growth and nutrient uptake characteristics of the soybean roots grown in two soils with different texture. Tap root elongation was measured on young seedling grown in cores compacted to different bulk densities of 1.2, 1.4 and $1.6/cm^3$ with different soil water retention in laboratory. The soil used were Samgag sandy loam and Baegsan loam soils. The wet and dry weight, total length, average radius and total surface area of roots were measured on soybean plants grown in 1/5000 a Wagner pots compacted to different bulk density of 1.2 and $1.4g/cm^3$. The nutrient uptake of soybean shoot was measured and evaluated with the unit surface area of roots at the 7th, 17th and 27th days after germination. The results were as follows: 1. The tap root elongation rate was faster in the loam soil with low bulk density than in the sandy loam soil with high bulk density. The elongation rates were remarkedly decreased when soil water was lower than the retention of 4 bars in loam soil and that of 1 bars in sandy loam soil. 2. Tap root elongation rate sharply decreased as increased soil strength higher than $2kgf/cm^2$ measured by ELE penetrometer showing curvillinear regression. However, it was low regardless of soil strength when soil water retention was 10 bars in sandy loam soil. 3. From the pot experiment, the total length of roots were longer in loam soil than in sandy loam soil and was longer in the soils with lower bulk density. The average radius of fine roots grown in sandy loam soil was larger than that grown in loam soil. The total surface area of roots was greater in the loam soil with low bulk density than in the sandy loam soil with high bulk density as the total length of roots. 4. The amounts of nutrient uptake by soybean shoots were greater in loam soil primarily due to more production of dry matter than in sandy loam soil. The nitrogen influx rates through the unit surface area were 597 to $753nmoles/day-cm^2$ in loam soil and 222 to $365nmoles/day\;cm^2$ in sandy loam soilshowing higher value in higher bulk density. The potasium influx rates were 99 to $175nmoles/day-cm^2$, and those of phosphate were 26 to $46nmoles/day\;cm^2$. Those of Ca and Mg were 175 to 246 and 163 to $205nmoles/day\;cm^2$. The difference in nutrient influx rates between bulk densities of these elements were lower than that of nitrogen.

• Korean Chemical Engineering Research
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• v.44 no.6
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• pp.659-668
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• 2006

The optimization of supercritical water oxidation (SCWO) process for decomposing nitromethane was studied by means of a design of experiments. The optimum operating region for the SCWO process to minimize COD and T-N of treated water was obtained in a lab scale unit. The authors had compared the results from a SCWO pilot plant with those from a lab scale system to explore the problems of scale-up of SCWO process. The COD and T-N in treated waters were selected as key process output variables (KPOV) for optimization, and the reaction temperature (Temp) and the mole ratio of nitromethane to ammonium hydroxide (NAR) were selected as key process input variables (KPIV) through the preliminary tests. The central composite design as a statistical design of experiments was applied to the optimization, and the experimental results were analyzed by means of the response surface method. From the main effects analysis, it was declared that COD of treated water steeply decreased with increasing Temp but slightly decreased with an increase in NAR, and T-N decreased with increasing both Temp and NAR. At lower Temp as $420{\sim}430^{\circ}C$, the T-N steeply decreased with an increase in NAR, however its variation was negligible at higher Temp above $450^{\circ}C$. The regression equations for COD and T-N were obtained as quadratic models with coded Temp and NAR, and they were confirmed with coefficient of determination ($r^2$) and normality of standardized residuals. The optimum operating region was defined as Temp $450-460^{\circ}C$ and NAR 1.03-1.08 by the intersection area of COD < 2 mg/L and T-N < 40 mg/L with regression equations and considering corrosion prevention. To confirm the optimization results and investigate the scale-up problems of SCWO process, the nitromethane was decomposed in a pilot plant. The experimental results from a SCWO pilot plant were compared with regression equations of COD and T-N, respectively. The results of COD and T-N from a pilot plant could be predicted well with regression equations which were derived in a lab scale SCWO system, although the errors of pilot plant data were larger than lab ones. The predictabilities were confirmed by the parity plots and the normality analyses of standardized residuals.

• Journal of Animal Science and Technology
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• v.45 no.5
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• pp.711-724
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• 2003

Some growth curve models were used to fit individual growth of 1,083 Hanwoo cows born from 1970 to 2001 in Daekwanryeong branch, National Livestock Research Institute(NLRI). The effects of year-season of birth and age of dam were analyzed. In analysis of variance for growth curve parameters, the effects of birth year-season were significant for mature weight(A), growth ratio(b) and maturing rate(k)(P〈.01). The effects of age of dam were significant for growth ratio(b) but not significant for mature weight(A) and maturing rate(k). The linear term of the covariate of age at the final weights was significant for the A(P〈.01) and k(P〈.01) of Gompertz model, von Bertalanffy model and Logistic model. For the growth curve parameters fitted on individual data using Gompertz model, von Bertalanffy model and Logistic model, resulting the linear contrasts(fall-spring), Least square means of A in three nonlinear models were higher cows born at fall and A of Logistic model was significant(P〈.05) between the seasons. According to the results of the least square means of growth curve parameters by age of dam, least square means of mature weight(A) in Gompertz model was largest in 6 year and smallest estimating for 3 and 8 years of age of dam. The growth ratio(b) was largest in 2 year of age of dam and smallest estimating in 8 year. The A and k were not different by age of dam(p〉.05), On the other hand, the b was different by age of dam(p〈.01). The estimate of A in von Bertalanffy model was largest in 6 year and smallest in 8 and 9 years of age of dam. The b was largest in 2 year and tend to decline as age of dam increased. The A and k were not different by age of dam(p〉.05), On the other hand, the b was highly significant by age of dam(p〈.01).

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.25 no.4
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• pp.81-96
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• 2020

Berthlot's reaction spectrophotometric method is generally used for the analysis of dissolved ammonium in seawater, but in recent years, a fluorescence method using an orthophthaldialdehyde-sulfite (OPA) fluorescent reagent is actively used internationally. In this study, we investigated the effects of the detection limit between the analysis methods, the reagent refractive index inherent in the spectrophotometric method, and the use of different calibration curves to understand the cause of the difference in dissolved ammonium concentration (about 0.31 𝜇M) observed in the seawater samples and a nutrient reference material between two institutions (KIOST (spectrophotometric method, one-order linear regression gradient only), Australia CSIRO (fluorescence method, quadratic formula)) conducted onboard the Australian R/V Investigator in 2017. The method detection limit (0.063 𝜇M) and the reagent refractive index background value (0.054 𝜇M) of the spectrophotometric method measured in this study could explain the difference in dissolved ammonium concentration values of the two institutes about 20% and 17%, respectively. However, when the concentration of the calibration curve of the spectrophotometric method was calculated using the same quadratic as the fluorescence method or the slope and intercept of linear regression, the difference in the dissolved ammonium concentration between the two institutions was reduced to less than the detection limit of the spectrophotometric method. Therefore, the difference in the concentration of dissolved ammonium between the two institutions, found in the nutrient reference materials and the seawater field sample during the international onboard nutrient inter-comparison experiment, may be attributed to be the effect of the different calibration curves used in the two methods rather than the effect of the difference in two analytical methods. When comparing the dissolved ammonium data from seawater samples in the future, it is recommended to pay attention to the information on the baseline, number of standard solutions, and calibration curve used in the analysis.

• Korean Journal of Soil Science and Fertilizer
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• v.7 no.3
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• pp.177-184
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• 1974

An attempt was made to determine simple and the most reasonable fertilizer recommendation for barley utilizing the present knowledge about the effect of soil and climatic factors on barley response to NPK fertilizer in Korea and establishing the critical contents of available nutrients in soils. The results were summarized as follows. 1. The relationships between relative yields or fertilizers rates for maximum yields from quadratic response curves and contents of organic matter, available $P_2O_5$, exchangeable K in soils were examined. The trend was more prospective with relative yields because of smaller variation than with fertilizer rates. 2. Since the relationship between N relative yields and organic matter contents in soils was almost linear over the practical range, it was difficult to determine the critical content for nitrogen response by quadrant methods. However, 2.6%, country average of organic matter content in upland soils was recommended as the critical point. 3. There showed a trend that average optimum nitrogen rater was higher in heavy texture soils, colder regions. 4. The critical $P_2O_5$ contents in soil were 96 or 118 ppm in two different years, which were very close to the country average, 114 ppm of $P_2O_5$ contents in upland soils. The critical K content in soil was 0.32 me/100g, which was exactly coincident to the country average of exchangeable K in upland soils. 5. According to the contents of avaiiable $P_2O_5$ and exchangeable K, several ranges were established for the purpose of convenience in fertilizer recommendation, that is, very low, Low, Medium, High and very High. 6. More phosphate was recommended in the northern region, clayey soils, and paddy soils, whereas less in the southern region and sandy soils. More potash was recommended in the northern region and sandy soils, whereas less in the southern region and clayey soils. 7. The lower the PH, the more fertilizers were recommended. However, liming was considered to be more effective than increas in amount of fertilizers.