• Title/Summary/Keyword: 1,3-H shift

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Enzymatic hydrolysis of insoluble silk sericin by Alcalase

  • Jung, Hye-Young;Bae, Do-Gyu
    • Journal of Sericultural and Entomological Science
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    • v.42 no.1
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    • pp.48-57
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    • 2000
  • This study was undertaken to figure out the effects of hydrolysis conditions on the solubility of insoluble sericin, molecular weight distribution and thermal characteristics of hydrolysates in enzymatic hydrolysis by Alcalase 2.5L. It was indicated that the optimum treatment temperature and pH for the insoluble sericin were 50$\^{C}$ and 11, respectively. When the insoluble sericin was hydrolyzed with a various treatment conditions, the solubility of all hydrolysates were represented above 85% at given conditions. As the enzyme concentration increased, the solubility increased roughly, but the solubility increasement ratio was less above 2% enzyme concentration. As the treatment time increased, the solubility was also increased. It was showed in the molecular weight distribution of hydrolysates treated various enzyme concentrations and treatment times that when enzyme concentrations were 0.5, 2, 3%, the peaks of the distribution curve were shifted to left side which meant low molecular weight and was distributed much quantity with shifted to be left side, but treatment time was 6 hr. the peak was shifted to right side. When enzyme concentration was 5% and treatment time was below 2 hr., the peaks were shifted to right side, but treatment time was above 4hr. the peak was shifted to left side. The number-average molecular weights were distributed from 300 to 800 and those were decreased when treatment time was up to 4 hr., but increased a little when treatment time was 6hr. It was showed in the DSC curves of hydrolysates treated with treatment time of 0.5, 1, 2, 4, 6 hr. fixed 1% o.w.s enzyme concentration and control that the endothermic peak was observed near at 200$\^{C}$. The denaturation peak of the hydrolysates depending on treatment times had a tendency to shift to higher temperature. But, when the treatment time was 6 hr., the peak was shifted to lower temperature comparing another hydrolysates.

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The Korean Fricatives in Acquisition: A Case Study

  • Kang, Kyung-Shim
    • Speech Sciences
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    • v.11 no.2
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    • pp.71-87
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    • 2004
  • Korean has a pair of voiceless fricatives, whose laryngeal manifestation comes in parallel to stops and affricates with a three-way lexical contrast. Prior phonetic studies by Kagaya (1974), Iverson (1983), and Kang (1999, 2000) point out /s/ is associated with multiple characteristics of the larynx shared with not only the lax but also the aspirated series, whereas /s' / carries a laryngeal distinction typical of the tense consonants. The complex dual nature of /s/ is again supported by a psycholinguistic study by Kang (2004), as /s/ was found to interact with /$c^h$/ (17% of the time) as well as /c/ (57%) in speech errors. In addition, a recent work by Cho and Lee (2003) notes an interesting chain shift case in the acquisition of the fricatives. Although they observed a significant phonological pattern between child English and Korean, Cho and Lee's description of acquiring fricatives is far from being precise from the perspective of phonetics. From a longitudinal study of recorded tapes by two children at 1;7-3;8 and 1;7-2;1 respectively, I found that /s' / was usually substituted into tense noncontinuants in young children's early production as predicted, whereas /s/ having both lax and aspirated-like glottal properties revealed a complicated pattern of substitutions into lax, tense, and aspirated noncontinuants with a varying degree of preference relative to the subjects. The current acquisition study supports the previous claims concerning fricatives in other languages, showing that their acquisition comes after stops. Besides, it also notes that Korean fricatives are subject to a series of phonological processes called stopping, affricating, tensifying and palatalizing during the transitional period of phonological development by young children. Moreover, between the two voiceless types, /s/ was acquired earlier than /s'/ as the unmarked segment.

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Synthesis of Nanostructured Si Coatings by Hybrid Plasma-Particle Accelerating Impact Deposition (HP-PAID) and their Characterization (하이브리드 플라즈마 입자가속 충격퇴적(Hybrid Plasma - Particle Accelerating Impact Deposition, HP-PAID) 프로세스에 의한 Si 나노구조 코팅층의 제조 및 특성평가)

  • 이형직;권혁병;정해경;장성식;윤상옥;이형복;이홍림
    • Journal of the Korean Ceramic Society
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    • v.40 no.12
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    • pp.1202-1207
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    • 2003
  • Using a recently developed Hybric Plasma-Particle Accelerating Impact Deposition (HP-PAID) process, synthesis of nanostructured silicon coatings has been investigated by injecting vapor-phase TEOS (tetraethosysilane, (C$_2$H$\_$5/O)$_4$Si) into an Ar hybrid plasma. The plasma jet with reactants was expanded through nozzle into a deposition chamber, with the pressure dropping from 700 to 10 torr. Ultrafine particles accelerated in the free jet downstream of the nozzle, deposited by an inertial impaction onto a temperature controlled substrate. By using this process, nanostructured amorphous silicon coatings with grain size smaller than 10 nm could be synthesized. These samples were annealed in an Ar and crystallized at 900$^{\circ}C$ for 30 min. TEM analysis showed that the annealed coatings were also composed of nanoparticles smaller than 10 nm, which showed a good consistency that the average grain size of 7 nm was also estimated from a peak shift of 2.39 cm$\^$-1/ and Full Width at Half Maximum (FWHM) 5.92 cm$\^$-1/ of Raman analysis. The noteworthy is that a strong PL peak at 398 nm was also obtained for this sample, which indicates that the deposited coatings also contained 3∼4 nm nanostructured grains.

Operating Characteristics of 1 $Nm^3/h$ Scale Synthetic Natural Gas(SNG) Synthetic Systems (1 $Nm^3/h$ 규모 합성천연가스(SNG) 합성 시스템의 운전 특성)

  • Kim, Jin-Ho;Kang, Suk-Hwan;Ryu, Jae-Hong;Lee, Sun-Ki;Kim, Su-Hyun;Kim, Mun-Hyun;Lee, Do-Yeon;Yoo, Yong-Don;Byun, Chang-Dae;Lim, Hyo-Jun
    • Korean Chemical Engineering Research
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    • v.49 no.4
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    • pp.491-497
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    • 2011
  • In this work, we proposed the three different reactor systems for evaluating of synthetic natural gas(SNG) processes using the synthesis gas consisting of CO and $H_2$ and reactor systems to be considered are series adiabatic reaction system, series adiabatic reaction system with the recirculation and cooling wall type reaction system. The maximum temperature of the first adiabatic reactor in series adiabatic reaction system raised to 800. From the these results, carbon dioxide in product gas as compared to other systems was increased more than that expected due to water gas shift reaction(WGSR) and the maximum $CH_4$ concentration in SNG was 90.1%. In series adiabatic reaction system with the recirculation as a way to decrease the temperature in catalyst bed, the maximum $CH_4$ concentration in SNG was 96.3%. In cooling wall type reaction system, the reaction heat is absorbed by boiling water in the shell and the reaction temperature is controlled by controlling the amount of flow rate and pressure of feed water. The maximum $CH_4$ concentration in SNG for cooling wall type reaction system was 97.9%. The main advantage of the cooling wall type reaction system over adiabatic systems is that potentially it can be achieve almost complete methanation in one reactor.

Difference in Weed Population as Affected by a Cropping Pattern in Paddy Field (논 작부체계(作付體系) 양식(樣式)에 따른 잡초발생양상(雜草發生樣相)의 변화(變化))

  • Ku, Y.C.;Yun, S.H.;Park, S.H.
    • Korean Journal of Weed Science
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    • v.5 no.2
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    • pp.137-142
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    • 1985
  • This experiment was conducted to know the difference in weed population in the five cropping patterns kept same for six years from 1976 such as ricebarley, potato-rice, pea-rice, rice-rye, and rice-fallow. More and many weeds were growing in single cropping field than double cropping field. Dominant weed species in pea-rice and potato-rice cropping patterns were M. vaginalis and S. hotarui, M. vaginalis and P. distinctus. Coefficient of similarity of the cropping patterns between pea-rice and potato-rice appeared higher than single cropping system. However, pea-rice and rice-fallow cropping patterns showed low coefficient of similarity.

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Assessment of Noise Exposure and Hearing Loss Among Workers in Textile Mill (Thamine), Myanmar: A Cross-Sectional Study

  • Zaw, Aung K.;Myat, Aung M.;Thandar, Mya;Htun, Ye M.;Aung, Than H.;Tun, Kyaw M.;Han, Zaw M.
    • Safety and Health at Work
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    • v.11 no.2
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    • pp.199-206
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    • 2020
  • Background: In a wide range of industries, noise-induced hearing loss remains one of the most prevalent occupational problems. This study aimed to assess the noise exposure level and associated factors of hearing loss among textile workers in Yangon Region, Myanmar. Methods: A cross-sectional study was conducted at a Textile mill (Thamine), Yangon Region, from April to December 2018. In total, 226 workers who were randomly selected from 3 weaving sections participated in face-to-face interviews using a structured questionnaire. A digital sound level meter and pure-tone audiometer were used for the assessment of noise exposure level and hearing loss, respectively. Logistic regression analysis was performed to assess the associated factors of hearing loss. Results: In total workers, 66.4% were exposed to ≥85 dB(A) of noise exposure, and the prevalence of hearing loss was 25.7%. Age ≥35 years, below high school education, hearing difficulty, tinnitus, hypertension, > 9 years of service duration in a textile mill were positively associated with hearing loss. After adjusting confounding factors, age ≥35 years (adjusted odds ratio = 6.90, 95% confidence interval = 3.45-13.82) and tinnitus (adjusted odds ratio = 2.88, 95% confidence interval = 1.13-7.37) were persistently associated with hearing loss. Conclusion: Providing occupational hazard education and enforcement of occupational safety regulations should be taken to decrease the noise exposure level. The regular audiometry test should be conducted for assessment of hearing threshold shift. The employer needs to implement a hearing conservation program in workplace when noise exposure reaches or exceeds 85 dB(A) for 8 hours.

Solid $CO_2$ sorbents and WGS catalyst for pre-combustion $CO_2$ capture (연소전 $CO_2$ 회수를 위한 고체 흡수제 및 WGS 촉매 특성 평가)

  • Eom, Tae Hyoung;Lee, Joong Beom;Park, Keun Woo;Choi, Dong Hyuk;Baek, Jeom-In;Ryu, Chong Kul
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.111.1-111.1
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    • 2010
  • 석탄가스화복합발전(IGCC: Integrated Gasification Combined Cycle)의 고온 고압 합성가스로부터 $CO_2$를 저비용으로 포집하기 위한 연소전 포집 기술 중 유동층 촉진수성가스전환(SEWGS) 공정이 제안되어 연구개발 중에 있다. 연소전 $CO_2$ 포집을 위한 SEWGS 공정은 동일한 2탑 순환 유동층 반응기에서 고온 고압의 합성가스($H_2$, CO)를 유동층 WGS 촉매를 사용하여 CO를 $CO_2$로 전환하는 동시에 전환반응으로 생성된 $CO_2$를 흡수제를 이용하여 포집하는 기술이다. 본 연구는 $CO_2$ 회수와 WGS 반응이 동시에 이루어지는 공정에 적용 가능한 건식 재생 흡수제 및 유동층 WGS 촉매 개발을 목표로 $CO_2$ 흡수제(P Series) 및 WGS 촉매(PC Series) 조성을 제안하고 분무건조기를 이용하여 6~8kg/batch로 성형 제조하였다. 제조된 $CO_2$ 흡수제 및 촉매의 특성 평가 결과 내마모도(Attrition resistance)를 포함한 물리적 특성이 유동층 공정의 요구조건을 만족하는 결과를 얻을 수 있었다. 또한, 모사 석탄 합성가스를 이용하여 20bar, $200^{\circ}C$ 흡수/$400^{\circ}C$ 재생 조건에서 열중량 분석기(TGA) 및 가압 유동층(Fluidized-bed) 반응기를 통한 흡수제의 $CO_2$ 흡수능 평가를 수행하였다. 그 결과 내마모도(AI) 3% 이하로 기계적 강도가 우수하며, $CO_2$ 흡수능 17.6 wt%(TGA) 및 11wt%(가압 유동층)를 나타냈다. 유동층 WGS 특성 평가 결과 내마모도가 7~35%로 우수하였고, CO 전환율은 $200^{\circ}C$에서 80% 이상으로, 유동층 SEWGS 공정에 적용 가능한 특성을 확인하였다.

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A of Radiation Field with a Developed EPID

  • Y.H. Ji;Lee, D.H.;Lee, D.H.;Y.K. Oh;Kim, Y.J.;C.K. Cho;Kim, M.S.;H.J. Yoo;K.M. Yang
    • Proceedings of the Korean Society of Medical Physics Conference
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    • 2003.09a
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    • pp.67-67
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    • 2003
  • It is crucial to minimize setup errors of a cancer treatment machine using a high energy and to perform precise radiation therapy. Usually, port film has been used for verifying errors. The Korea Cancer Center Hospital (KCCH) has manufactured digital electronic portal imaging device (EPID) system to verify treatment machine errors as a Quality Assurance (Q.A) tool. This EPID was consisted of a metal/fluorescent screen, 45$^{\circ}$ mirror, a camera and an image grabber and could display the portal image with near real time KIRAMS has also made the acrylic phantom that has lead line of 1mm width for ligh/radiation field congruence verification and reference points phantom for using as an isocenter on portal image. We acquired portal images of 10$\times$10cm field size with this phantom by EPID and portal film rotating treatment head by 0.3$^{\circ}$, 0.6$^{\circ}$ and 0.9$^{\circ}$. To check field size, we acquired portal images with 18$\times$18cm, 19$\times$19cm and 20$\times$20cm field size with collimator angle 0$^{\circ}$ and 0.5$^{\circ}$ individually. We have performed Flatness comparison by displaying the line intensity from EPID and film images. The 0.6$^{\circ}$ shift of collimator angle was easily observed by edge detection of irradiated field size on EPID image. To the extent of one pixel (0.76mm) difference could be detected. We also have measured field size by finding optimal threshold value, finding isocenter, finding field edge and gauging distance between isocenter and edge. This EPID system could be used as a Q.A tool for checking field size, light/radiation congruence and flatness with a developed video based EPID.

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A Study on Embrittlement of Fast Neutron-irradiated Nuclear Reactor Pressure Vessel Steels at Room- and Liquid Nitrogen-temperature (상온 및 액체질소 온도에서 고속 중성자 조사된 원자로 압력 용기의 취화 현상에 관한 연구)

  • Kim, H.B.;Kim, H.S.;Kim, S.K.;Shin, D.H.;Yu, Y.B.;Ko, J.D.
    • Journal of the Korean Magnetics Society
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    • v.15 no.2
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    • pp.142-147
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    • 2005
  • The embrittlement of fast neutron-irradiated reactor pressure vessel (RPV) steels was investigated by X-ray diffraction patterns at room temperature and $M\ddot{o}ssbauer$ spectroscopy at room- and liquid nitrogen-temperature. Neutron fluence on the samples were $10^{12},\;10^{13},\;10^{14},\;10^{15},\;10^{16},\;10^{17},\;10^{18}\;n/cm^2$. The X-ray diffraction patterns showed that the structure of the neutron unirradiated sample was bcc type, where as but the neutron irradiated samples with the fluence higher than $10^{17}\;n/{\cal}cm^2$ were so severely damaged, that bcc type structure disappeared. The $M\ddot{o}ssbauer$ spectra of all samples showed superposition of two or more sextets. In this paper all $M\ddot{o}ssbauer$ spectra were fitted by three set of sextet. The isomer shift and quadrupole splitting values were found around zero. At liquid nitrogen temperature, magnetic hyperfine field and absorption area increase rapidly S 1 sextet in the samples of $10^{17}\~10^{18}\;n/{\cal}cm^2$ neutron fluences. And at room temperature, magnetic hyperfine field and absorption increased rapidly at SI sextet in the samples of $10^{17}\~10^{18}\;n/{\cal}cm^2$ neutron fluences. This rapid increase of magnetic hyperfine field and absorption area were inferred to be caused by the change of $^{56}Fe,\;^{55}Mn$ into $^{57}Fe$ due to by neutron irradiation.

Effects of Temperature and Photoperiod on Male Activity in Laspeyresia pomonella (L.) in New York (온도와 광주기 조건이 코드링나방 수컷의 활동력에 마치는 영향)

  • SONG, YOO HAN;Ridel, Helmut
    • Korean journal of applied entomology
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    • v.24 no.2 s.63
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    • pp.71-77
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    • 1985
  • The male activity in Laspeyresia pomonella (L.) measured by an activity recording device in New York had two distinct peaks, the first peak at lights-off and the second one at ligts-on signal, under the defined conditions of temperature above $23^{\circ}C$ and light:dark (LD) 16:8 regime. The activity initiation of the first activity was observed four to six hours prior to the onset of scotophase and seened to be entraind by lights-off cue. Under the continuous photophase (LL) the activity period freeran with a period slightly greater than 24 hours, indicating that the rhythmicity is circadian The activity pattern was measured in eight different temperature conditions ranging from $11.3^{\circ}\;to\;30^{\circ}C$ under LD 16:8 regime. No activity was observed at $11.3^{\circ}C$ which seems to be temperature threshold for activity. The second peak of activity at lights-on signal disappeared at the temperature below $20^{\circ}C$ and the activity in scotophase was also suppressed at the temperature lower than $18^{\circ}C$. At the temperature range from $20^{\circ}\;to\;30^{\circ}C$, as temperature increased the second peak in the morning became larger and the activty in the scotophase was also increased. Because of the activity increase in the scotophase with rising temperature, the mean time of activity shifted towards the scotophase. The shift of the moth male activity period with the change of ambient temperature appears to be due to the suppression of activity under cool temperature (below $20^{\circ}C$) in scotophase.

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