• Title/Summary/Keyword: 1,2-디메틸하이드라진

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Synthesis of the Tetrazolium Derivatives for Ionic Liquid Rocket Fuel and a Study of Their Ignition Delay Time and Viscosity (이온성 액체로켓 연료용 테트라졸리윰 유도체의 합성 및 점화지연시간 및 점도에 대한 연구)

  • Lee, Hyun-Woong;Choi, Seong-Ho
    • Journal of the Korea Institute of Military Science and Technology
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    • v.25 no.3
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    • pp.285-291
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    • 2022
  • In order to use the liquid rocket fuel, 1,5-diamino-4-methyltetrazolium azide, [DMT]+[N3]- and 1,5-diamino-4-methyltetrazolium cyanide, [DMT]+[CN]- were synthesized and prepared the ionic liquid rocket fuel after dissolving the synthesized solid-type energetic chemicals in hydrazine, respectively. The thermal decomposition temperatures(Td) and densities(d) of the prepared ionic liquid rocket fuels were about 200 ℃ and above 1.0 g/cm3 respectively. The ignition delay times(Idt) of the ionic liqud rock fuels with [DMT]+[N3]- and [DMT]+[CN]- were in a range of 26.6 - 82.5 ms and the 44.0 - 98.5 ms, respectively. These results mean that the synthesized tetrazolium salts could be used as an ionic liquid rocket fuels. The viscosities of the ionic liqud rock fuels with [DMT]+[N3]- and [DMT]+[CN]-, which were dissolved in mixture solution of hydrazine/2-hydroxyethylhydrazine were to be 1.34 - 101 cP, and 1.29 - 80.5 cP, respectively. The synthesized ionic liquid rocket fuels in this study could be used as rocket fuel because the [Idt(100 ms or less), Td(150 ℃ or more), d(1.00 g/cm3 or more), and η(40.0~ 100 cP)] were achieved to satisfy the range of the used liquid rocket fuels.

The Chemopreventive Effect of Heat-treated Radish Complex Extracts on Rat Colonic Aberrant Crypt Foci Induced by 1,2-Dimethylhydrazine (1,2-Dimethylhydrazine에 의해 유발된 Colonic Aberrant Foci에 대한 초임계 열처리된 무복합추출물의 대장암 효과)

  • Kim, Hyun Kyoung
    • The Journal of the Convergence on Culture Technology
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    • v.5 no.4
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    • pp.431-438
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    • 2019
  • The present study was designed to investigate the chemopreventive effects of supercritical heat radish extracts with anti-constipation acitivity in loperamide-treated rats, on 1,2-dimethylhydrazine(DMH)-induced aberrant crypt foci(ACF) in rat colonic mucosa. Supercritical heat radish extracts was administered in the drinking water(3.2 mg/ml) during the initiation (for 12 weeks) or postinitiation phase(for 9 weeks) of DMH-induced carcicogenesis. Supercritical heat radish extracts coupled with DMH for 12 weeks decreased significantly total number of aberrant crypts(pre-neoplastic lesions) and the number of ACF to 35% and 30%, respectively. The number of ACF with more than four aberrant crypts (crypt multiplicity) was significantly reduced in the colon of rats receiving Supercritical heat radish extracts for 12 weeks. In the group receiving Supercritical heat radish extracts after post-initiation for 9 weeks, only the number of ACF with ${\geq}4$ abberant crypts significantly decreased. Supercritical heat radish extracts, given alone for 12 weeks, did not induced the development of ACF. These results indicate that Supercritical heat radish extracts possess chemopreventive effects on chemically induced rat colon carcinogenesis.