• 한국의류산업학회지
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• 제10권6호
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• pp.1051-1057
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• 2008

Safflower red and Amur Cork Tree dyes have used for dyeing on cotton fabrics largely. But they have low degree of lightfastness, So this study investigated the effect of BTCA pre-treatment on lightfastness of cotton fabrics dyed with Safflower red and Amur Cork Tree. The result is as the following; By FT-IR spectra, crosslingking was proved in cotton fabric pre treated with BTCA. K/S value of Safflower red dyed cotton fabric pretreated with BTCA was much more decreased than untreated cotton fabric with BTCA. It showed that the hue of the Safflower red dyed cotton fabric changed from reddish purple to red. However, K/S value of Amur Cork Tree dyed cotton fabric pre treated with BTCA was much more increased than untreated cotton fabric with BTCA. It showed that the hue of the Amur Cork Tree dyed cotton fabric changed from green yellow to yellow. For K/S value of Combination dyed cotton fabric pre treated with BTCA, Safflower red color was much more decreased than untreated cotton fabric. But Amur Cork Tree color was much more increased than untreated cotton fabric. It changed from reddish purple, red, yellowe red, to yellow in hue. ${{\Delta}E^*}_{ab}$ of Combination dyed cotton fabric in 40 hours irradiation was 15.7, however ${{\Delta}E^*}_{ab}$ of Combination dyed cotton fabric treated with 2% BTCA was 8.0, and that treated with 3% BTCA was 9.8. So, pre-treatment with BTCA to combination dyed cotton fabric with Safflower red and Amur Cork Tree showed more effective improvement of Lightfastness than untreated cotton fabric with BTCA.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2009년도 제41차 학술발표회
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• pp.15-16
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• 2009

Poly(vinyl alcohol) was crosslinked by UV irradiation in the presence of water soluble photoinitiators. The crosslinking of PVA films with 1,2,3,4-Butanetetracarboxylic acid(BTCA) and sodium phosphinate monohydrate(SPM) was also achieved via thermal curing. Different factors in the crosslinking including thermal and radiation methods were studied. Gel fraction of PVA films increased with increasing photoinitiator concentration. The maximum gel fraction on the crosslinking method was reached about 81%. The glass transition and maximum decomposition temperature improved by both thermal and radiation crosslinking.

• 한국가정과학회지
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• 제9권1호
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• pp.43-50
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• 2006

The main colorant of Chelidonium majus extracts is a berberine which shows relatively good dyeability onto silk fabrics in the appropriate dyeing conditions without mordant, But cotton fabrics are difficult to dye with berberine because of the low substantivity the cationic to cellulosic fibers. we treated cotton fabrics using three types of polycarboxylic acid, DL-malic acid, citric acid, 1,2,3,4-butanetetracarboxylic acid(BTCA) to increase dyeability of Chelidonium majus extracts onto cotton fabrics. As a result the cotton fabrics treated with polycarboxylic acid could be dyed with Chelidonium majus extracts and also showed yellow vividly. The dye uptake were increased with increasing the number of carboxy groups. And so dye uptake resulted the largest in the BTCA solutions which have four carboxylic groups in the molecular unit. The optimal dyeing temperature a of Chelidonium majus extracts onto polycarboxylic acid treated cotton fabrics were $60^{\circ}C$. The dye equilibrium was reached 20 minutes after dyeing. Neutral pH of dye solutions showed in higher K/S value than acidic or alkaline conditions. But the colorfastness to washing and light according to polycarboxylic acid treat was not enhance.

• 폴리머
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• 제32권1호
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• pp.70-76
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• 2008

UV 조사방법으로 poly(ethersulfone) PES 막에 1,2,3,4-butanetetracarboxylic acid(BTCA)를 그래프트 공중합하고, 이를 아민화시켜 PES 음이온교환막을 합성하였으며, 이들의 구조 및 특성을 확인하였다. PES 음이온교환막의 그래프트율과 아민화율은 반응 시간에 따라 증가하였으며, 80분에서 최대 134%, 1.20 mmol/g이었다. PES 음이온교환막의 초기 열분해온도는 $400^{\circ}C$로 표면개질반응이 진행됨에 따라 감소하였다. PES 음이온교환막의 접촉각은 아민화율이 증가함에 따라 $68.1^{\circ}{\sim}40.2^{\circ}$로 감소하였으며, 함수율과 이온교환용량은 UV 조사시간이 증가함에 따라 80분까지 선형적으로 증가하였다. 또한 막의 평균 기공의 크기와 비표면적은 PES 막, PES-g-BTCA 공중합체막, PES 음이온교환막의 순이었으며, 평균기공 크기값은 624.8, 359.7, 138.5 ${\AA}$, 비표면적은 10.1, 9.7, 1.7 $m^2/g$이었다.

• 한국염색가공학회지
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• 제21권1호
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• pp.38-45
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• 2009

First of all, the properties imparted to PET fabrics are resistance to and recovery from creasing or wrinkling when wet or dry; high resistance to stretch in the filament yarns but not in the staple; high abrasion resistance; good texture and appearance; resistance to heat ageing; good chemical resistance and good resistance, behind glass, to sunlight. But, the low moisture regain of PET fabric conduces to static troubles in textile processing. Furthermore, garments made from PET may, during wear, develop electric charges which attract to the fabric particles of soil(dirt, swarf, dust) flying in the air, so that the cuffs of shirts, for example, become soiled quickly and are not easily laundered clean. The sericin constitutes 25$\sim$30％ of silk protein and surrounds the fibroin fiber with sticky layer that supports the formation of a cocoon. The useful biochemical properties of sericin protein are oxidation resistant, antibacterial, UV resistant, hydrophilic property, and good affinity with hydrophobic material. These properties can be used as an improving reagent or a coating agent for natural and synthetic fibers, fabrics, and other intermediate products. The sericin is also applied to cross-link, and can be blended with other materials. In this study, we modified the surface of PET fabric by mixture of sericin finishing agent; sericin, polyuretane binder and 1,2,3,4-butanetetracarboxylic acid (BTCA) cross-link agent. Also, we investigated the finshing effect; moisture regain, stiffness, handle, drape and electrostatic. The moisture regain of PET fabric treated with sericin finishing agent was higher than that of untreated PET fabric. As a result of evaluating influence about handle of PET fabrics treated with sericin finishing agent, it was confirmed that the sericin finishing agent could be use as a linen like finishing agent.