• Title/Summary/Keyword: 희토류 원소

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Genetic Implications of Ultramafic Rocks from the Bibong Area in the Kyeonggi Gneiss Complex (경기편마암복합체내 비봉지역에 분포하는 초염기성암에 대한 성인적 적용)

  • Song, Suck Hwan;Choi, Seon Gyu;Woo, Jun Gie
    • Economic and Environmental Geology
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    • v.30 no.5
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    • pp.477-491
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    • 1997
  • In the Bibong area of the western part of Chungcheongnam-do, ultramafic masses occur as discontinuous isolated lenticular bodies in the Precambrian Kyeonggi gneiss complex. They extend for about 200 m long to NNE directions which are parallel to fault lines in the gneiss complex. The ultramafic masses contact with the adjacent gneiss complex as steeply dipping faults. They are dunites and harzburgites and many of them are partially or completely serpentinized. The ultramafic rocks dominantly show protogranular, equigranular and equigranular-$m{\grave{o}}saic$ textures. They also show porphyroclastic (megacrystic) or recrystallized textures reflecting several stages of metamorphism. They contain varying amounts of olivine $(Fo_{89-92})$, enstatitic to bronzitic orthopyroxene, diopsidic clinopyroxene, tremolitic to pargasitic hornblende, and spinel with serpentine, talc, chlorite, calcite and magnetite. The ultramafic rocks have high magnesium numbers and transitional element contents, low alkali contents and show deplete REE patterns. Comparing with available data, geochemical and mineralogical characteristics shown in the ultramafic rocks of the Bibong area are similar to those of worldwide mantle xenoliths and orogenic related ultramafic rocks. The field evidences, petrographical, geochemical and mineralogical characteristics shown in the ultramafic rocks of the Bibong area are similar to alpine type ultramafic rocks emplaced into the crust by the faulting as mantle slab types. With the petrographical characteristics, these mineralogical compositions suggest that the ultramafic rocks of the Bibong area have experienced several stages of retrogressive metamorphism in a condition ranging from the upper amphibolite facies to greenschist facies.

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A Study on the Relationships between White Wares and Raw Materials Excavated at Goseong-ri Kiln Site in Chuncheon, Yeongseo Province, Gangwon-do (강원 영서지역 춘천 고성리 가마터 출토 백자 및 태토 원료의 상관관계 연구)

  • Lee, Byeong Hoon
    • Journal of Conservation Science
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    • v.36 no.3
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    • pp.152-161
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    • 2020
  • The purpose of this study was to compare the chemical properties of white soil and refined clay sediment, which are produced early in the refining process. The characteristics of the white wares made at the kiln site in Goseong-ri, Chuncheon were also examined. Three groups of materials were examined: white wares excavated from the white wares kiln, raw material from white soil collected from the surface, and a refined clay sediment group. There were also three analysis methods, which were a main components analysis, a trace components analysis, and a mineral analysis. The main components analysis found that the white wares clay was in the RO24.04~4.28 and the RO + R2O 0.30~0.31 mole areas, which were similar to the results for the refined clay sediment. However, the refining process used to produce better quality white wares meant that the large differences in the early white soil raw material appeared in the refined sediment. The mineral phase analysis showed that the crystals detected in the early white soil raw materials and refined clay sediment were almost identical. However, quartz and mullite mineral phases, which can occur above a certain temperature, were detected in the excavated white wares clay. Rare earth elements that were not affected by the pottery making process and the weathering of clay materials were found to have the same origin in all three groups.

Mineralogical Characteristics and Genetic Environment of Zeolitic Bentonite in Yeongil Area (영일 지역 제올라이트질 벤토나이트의 광물특성 및 생성환경)

  • 노진환;고상모
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.2
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    • pp.135-145
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    • 2004
  • A zeolitic bentonite, which exhibits whitish appearance and contains considerable amounts (nearly 〉 5%) of zeolites, frequently occurs as thin beds less than 1 m in Yeongil area. The bentonites are mostly found in closely association with zeolite beds in the Nuldaeri Tuff and Coal-bearing formations of the Janggi Croup. A discordant occurrence of the bentonite against the bedding plane is also locally found. Montmorillonite, the major mineral constituent of the bentonite, is mostly associated with clinoptilolite as a zeolite. However, instead of clinoptilolite, mordenite is sometimes included in the case of more silicic bentonite, and heulandite in the less silicic one. It is characteristic that the mordenite is accompanied by lots of opal-CT in the silicic bentonite. SEM observations characteristically indicate that these authigenic phases, especially the montmorillonite and zeolite, nearly coexist as mixtures not forming a fine-scale zoning. The zeolitic bentonite seems to be formed in the comparatively silicic pore fluid at the alkaline condition accompanying pH fluctuation Compared to the zeolite-free normal bentonite, the zeolitic types exhibit somewhat higher REE abundance. These chemical characteristics, together with modes of occurrences and authigenic mineral associations, may suggest that the zeolitic bentonite is not merely diagenetic products and a possible hydrothermal alteration could not be excluded in the bentonite genesis.

Introduction of Several Albitite-greisen Type Deposits of Korea (한국 알비타이트-그라이젠형 광상의 소개)

  • Yoo, Jang Han;Koh, Sang Mo;Moon, Dong Hyeok
    • Journal of the Mineralogical Society of Korea
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    • v.25 no.4
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    • pp.221-231
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    • 2012
  • Uljin cassiterite deposit had been known to be a pegmatitic origin derived from the Wangpiri (Buncheon) granitic gneiss of Precambrian period. Lithium ore also shows the same origin and its lithium bearing mineral was ascertained to be a taeniolite. But the presence of leucocratic granites which played the role of host rocks haven't been clearly designated yet in these provinces. Even though Bonghwa and Youngweol sericite deposits situated in the vicinities of Hambaeg syncline had been known to have their host rocks as Hongjesa Granites of Precambrian period and Pegmatitic migmatite of unknown age respectively. But younger leucocratic granites are characterized by more amounts of albite and sericite (muscovite-3T type) than those of the older granitic rocks which contain plenty of biotite and chlorites. Although the younger granites show rather higher contents of alkalies such as $Na_2O$ (0.13~8.03 wt%) and $K_2O$ (1.71~6.38 wt%), but CaO (0.05~1.21 wt%) is very deficient due to the albitization and greisenization. Manisan granite, which is assumed to be Daebo granite which intruded the Gyunggi Gneiss Complex was again intruded by leucocratic granite whose microclinized part changed into kaolins. Taebaegsan region shows a wide distribution of carbonate rocks which are especially favorable to the ore depositions. And the presence of alkali granites which formed in the later magmatic evolution are well known to be worthwhile to the prospections of various rare metals and REEs resources.

Comparative Study on Material Characteristics of Joseon White Wares Excavated from Gangwon Wonju Province (강원 원주지역 조선백자의 재료학적 특성 비교연구)

  • Lee, Byeong Hoon;So, Myoung-Gi
    • Journal of Conservation Science
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    • v.33 no.4
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    • pp.225-239
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    • 2017
  • This study aimed to investigate the chemical properties and production techniques for white wares from the Gwirae-1ri 3rd, Songok-3ri 2nd kiln sites in Kangwon Wonju regions. Further, another aim was to determine the correlation among the materials used to produce the white wares. The analysis of white wares in Kangwon Wonju regions produced the following results. The excavated white wares were analyzed using the Seger formula, and all the samples showed similar clay sources ($RO_2:4.33-5.82$, $RO+R_2O:0.32-0.43$) and glaze sources. Moreover, the white wares were made of host rocks of the same geological origin, according to the results of the rare earth elements analysis. When the crystalline phases of the white wares were investigated via the XRD analysis, quartz and mullite were found in all the samples, and their proportions were similar to each other. Although the firing temperatures for the samples were different, most were fired at a temperature below $1,200^{\circ}C$, with some being fired at temperatures as low as $1,000{\pm}20^{\circ}C$.

Geochemical Characteristics of A-type granite in Dongcheondong, Gyeongju (경주 동천동 일대에 분포하는 A-형 화강암의 지화학적 특성)

  • Myeong, Bora;Ju, Jiwon;Kim, Junghoon;Jang, Yundeuk
    • The Journal of the Petrological Society of Korea
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    • v.26 no.3
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    • pp.271-280
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    • 2017
  • The Dongcheondong granite is alkali feldspar granite in Dongcheondong, Gyeongju. The granite is coarse grained and consists of alkali feldspar, quartz, amphibole, and biotite. Alkali feldspar is perthitic orthoclase and quartz often shows undulatory extinction. Plagioclase often shows albite twins, and biotite and amphibole emplace as interstitial minerals. The Dongcheondong granite is plotted in A-type area having high ($Na_2O+K_2O)/Al_2O_3$ and low (MgO+CaO)/FeOT ratio. The Dongcheondong A-type granite has higher $SiO_2$, $Na_2O$, $K_2O$, Zr, Y, and REE contents (except for Eu) and lower $TiO_2$, $Al_2O_3$, CaO, MgO, Sr, Ba, and Eu contents than I-type granites in Gyeongsang Basin. These results show that the geochemical characteristics of the Dongcheondong A-type granite are distinguished from I-type granite in Gyeongsang Basin. A-type granite in the Dongcheondong is thought to has been generated by partial melting of I-type tonalite or granodiorite.

Axial Pressing Method Using Pulse Magnetizing Field for the Preparation of Nd-Ee-B Sintered Magnets (펄스자장을 이용한 고이방화 Nd-Fe-B자석의 종축자장성형방법)

  • Kim, Dong-Hwan;Kang, Byung-Kil;Jang, Dong-Youl;Kim, Andrew S.;Kim, Sang-Myun;Jang, T.S.
    • Journal of the Korean Magnetics Society
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    • v.13 no.4
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    • pp.182-186
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    • 2003
  • A new axial pressing method using pulse magnetizing field was studied to improve the remanence of Nd-Fe-B sintered magnets. In order to make near-net shape green compacts of butterfly, disk, or coin magnets, conventional axial-type pressing has been normally used. However, compared to the transverse-type pressing, it is not possible to obtain higher remanence by this method because the magnetic alignment of powder begins to deteriorate when the density of green compacts increases over a critical value. On the other hand, we found that an axial pressing under pulse magnetizing field was very effective to increase the degree of magnetic alignment of powder, yielding remanences even higher than those obtained by the transverse pressing. In this study, it was revealed that appropriate tapping density and how to apply pulse magnetic held were important to improve the grain alignment and thus remanence of Nd-Fe-B sintered magnet.

Manufacturing Techniques and Provenance of Earthen Wares in Daecheonri Prehistory Site of Okcheon County, Korea (옥천 대천리 유적지 토기의 제작기법 및 원료산지 분석)

  • Lee, Hyo-Min;Yang, Dong-Yun;Gu, Ja-Jin;Kim, Ju-Yong;Han, Chang-Gyun;Choe, Seok-Won
    • The Korean Journal of Quaternary Research
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    • v.18 no.1 s.22
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    • pp.1-20
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    • 2004
  • A geoscientific research was performed on 12 samples of comb-pattern potteries which were excavated at Daecheonri neolithic site, Korea. The texture and compositions of 12 potteries and surrounding metrix of soil and rocks were compared with the help of petrographic microscope, XRD and REE data. As to the manufacturing techniques thick potteries are caused by the amount and number of coarse grains which are assumed to be added shards when their distributional pattern are considered. DC1, DC3, DC 7 and DC11 samples have clearly oriented textures, and the orientation of vesicles in DC3 and DC11 samples arranged in the same direction with those on the pottery surface. This indicates the use potter's wheel technique in manufacturing potteries. Burning temperature is assumed over $800^{/circ}C$, particularly under reduction environment. As to the source, raw materials of pottery matrix are derived from the bottom of excavation site, or in an extracted outcrop of the northwestern foothill from site, while the shard materials are very similar with those extracted from sandy loams near sites. Finally any use pattern of pottery may control the pottery thickness, shard addition, and matrix selection.

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Material Characteristics and Archaeological Scientific Implication of the Bronze Age Potteries from the Cheonan-Asan Area, Korea (천안-아산 지역 청동기시대 무문토기의 재료학적 특성과 고고과학적 의미)

  • Lee, Chan Hee;Cho, Seon Yeong;Eo, Eon Il;Kim, Ran Hee
    • Journal of Conservation Science
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    • v.31 no.1
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    • pp.47-64
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    • 2015
  • The excavated potteries and raw clays of the Bronze Age from the archaeological sites in the Cheonan-Asan area were studied on material scientific characteristics and homogeneity. Under the microscope, grainsize of the tempers in the potteries were distributed from less than 1mm to 10mm. Microtexture of the potteries showed various shapes and sizes of pores. In addition to the main minerals such as quartz, feldspar, mica, hornblende, chlorite and talc were found from the X-ray diffraction analysis of potteries, while talc was not found in the raw clay. Therefore, it was considered as an artificially added mineral. Firing temperature of the potteries, which did not contain chlorite, are assumed that they were baked below $850^{\circ}C$. On the other hand, the potteries which had mica and talc, are assumed that they were fired below $900^{\circ}C$. The geochemical characteristics of the potteries and raw clays showed very similar patterns, that means the potteries were produced by using the raw clay sources from each site.

Separation Properties of Sm/Nd with Karr Column (Karr column을 이용한 Sm/Nd 분리특성)

  • Eom Hyoung-Choon;Lee Jin-Young;Kim Sung-Don;Park Kye-Sung;Kim Jun-Soo
    • Resources Recycling
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    • v.14 no.6 s.68
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    • pp.10-15
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    • 2005
  • In this study, the separation of samarium to neodymium with Karr column was investigated. Separation properties of Sm/Nd binary system was estimated with experimental parameters such as flow rate, initial pH of aqueous phase, saponification of PC88A in organic phase and agitation speed. The extraction rate and distribution coefficient increased with increasing initial pH of aqueous phase at 16.5 ml/min(retention time 10 minute) of flow rate of organic and aqueous phase, and equilibrium pH of aqueous phase after extraction was maintained at 1.5 by saponified PC88A. Also, the extraction rate and distribution coefficient were drastically increased with increasing saponification degree of PC88A and agitation speed, and optimal saponification degree was $40\%$. Extraction rate of Nd and Sm was $19.6\%$ and $72.5\%$ respectively at retention time 10 minute, initial pH 1, saponification degree $40\%$ and agitation speed 120 rpm.