• Title/Summary/Keyword: 흡착탑

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Treatments of VOCs and Odor in Biofilter using Lava Stone (화산석을 이용한 Biofilter에서 VOCs 및 악취저감)

  • 이학성;박진도
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.11a
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    • pp.274-275
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    • 2000
  • 현재 우리 나라는 공단지역에서 발생하는 VOCs(휘발성 유기화합물) 및 악취의 처리에 대한 연구개발 및 기존기술이 매우 취약한 실정이며, 일부 화학공장에서는 축열식 연소장치나 촉매연소장치를 설치하여 운전하고 있지만, 유지비(보조연료비)가 많이 소요되어 제대로 가동하지 못하는 경우가 있다. 대부분 제조업체의 경우, 활성탄 흡착탑을 설치하여 운영하지만, 화학공장에서 발생하는 포름알데히드, 스티렌 등과 같은 일부 물질은 흡착탑 내부에 타-르 같은 물질이 침적하고, 활성탄에 의한 흡착율이 낮다. (중략)

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Treatments of VOCs and Odor of Chemical Plant by Biofilter (Biofilter에 의한 화학공장의 VOCs 및 악취저감)

  • 이학성
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 1999.10a
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    • pp.447-448
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    • 1999
  • 현재 우리나라는 공단지역에서 발생하는 VOCs(휘발성 유기화합물) 및 악취의 처리에 대한 연구개발 및 기존기술이 매우 취약한 실정이며, 일부 화학공장에서는 축열식 연소장치나 촉매연소장치를 설치하여 운전하고 있지만, 유지비(보조연료비)가 많이 소요되어 제대로 가동하지 못하는 경우가 있다. 대부분 제조업체의 경우, 활성탄 흡착탑을 설치하여 운영하지만, 화학공장에서 발생하는 포름알데히드, 스티렌 등과 같은 일부 물질은 흡착탑 내부에 타-르 같은 물질이 침적하고, 활성탄에 의한 흡착율이 낮으며, 저농도에서도 악취가 발생하므로 이러한 저농도 VOCs 물질들의 처리에 Biofilter를 적용하여 처리가능성을 조사하였다.(중략)

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Adsorption Characteristics of Reverse Stratified Tapered Adsorber (역층상 점증형 흡착탑에서의 흡착특성)

  • Lee, Seung-Mok;Kim, Dae-Hyun;Lee, II-Young
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.10
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    • pp.1861-1867
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    • 2000
  • Granular activated carbon(GAC) adsorption is one of the best available technology to remove synthetic organic chemicals(SOCs) from water supplies and wastewater. In order to satisfy enviromental criteria and reduce GAC treatment cost, optimal study of reverse stratified tapered adsorber(RSTA) has been conducted. The RSTA was found to provide on increase in breakthrough time when compared to a conventional cylindrical adsorber(CA). Through the RSTA optimal experiment, optimal mean bed velocity was decided 19.10cm/min and optimal angle was decided RSTA($3.0^{\circ}$). Adsorption efficiency was increased with increasing activated carbon doses and the number of activated carbon layers.

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Removal Characteristics of Heavy Metals by Continuous Neutralization of Plating Wastewater with Waste-Oyster Shells (폐굴껍질에 의한 산성도금폐수의 연속 중화시 중금속제거 특성)

  • 김형석;송동근;성낙창
    • Resources Recycling
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    • v.7 no.3
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    • pp.36-41
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    • 1998
  • Objective of the research is to deteonine the praeLic따 running parameters for neutralization and removal of heavy metals from plating wastewater with waste-oyster shells by the Bohart$.$Adams equation. Waste-oyster shells discharged from the d domestic oyster cultnring fields cause a serious ocean environmental pollution. However, it is expected that those are able to b be recycled for removal of heavy metals through neutralization of plating wastewater because the shells contain approximate 93% $CaCO_3$, and have multi-pore voids. By applying the results of the continuous experiments to Bohart-Adams equation, s service time decreases in the order of Cr>Fe>Cu while removal efficiencies of metals become less in the order of Fe>Cr>Cu.

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Investigation of Optimum Condition of Heat Treatment and Flow to Improve H2S Adsorption Capacity for Practical use of an Activated Carbon Tower (활성탄 흡착탑의 실용화를 위한 최적 유동특성 선정 및 열처리 조건에 따른 황화수소 포집능 향상 연구)

  • Jang, Younghee;Kim, Bong-Hwan;Kim, Sung Su
    • Applied Chemistry for Engineering
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    • v.32 no.1
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    • pp.91-96
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    • 2021
  • This study was conducted to improve the operating conditions of an adsorption tower filled with potassium impregnated activated carbon for high hydrogen sulfide capture capacity. Heat treatment modified the surface properties of activated carbon, and ultimately determined its adsorption capacity. The activated carbon doped with potassium showed 57 times more adsorption at room temperature than that of using the raw adsorbent. It is believed that uniform pore formation and strong bonding of the potassium on the surface of carbon contributed to the chemical and physical absorption of hydrogen sulfide. The SEM analysis on the surface structure of various commercial carbons showed that the modification of surface properties through the heat treatment generated the destruction of pore structures resulted in the decrease of the absorption performance. The pressure drop across the activated carbon bed was closely related with the grain size and shape. The optimum size of irregularly shaped activated carbon granules was 2~4 mesh indicating economical feasibility.

Adsorption/desorption of CO2 on Activated Carbon Fibers Using Electric Swing Adsorption (활성탄소섬유상에서 전기변동법을 이용한 CO2의 흡/탈착)

  • Shim, JaeWoon;Moon, SeungHyun
    • Korean Chemical Engineering Research
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    • v.43 no.3
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    • pp.432-437
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    • 2005
  • An electric swing adsorption (ESA) process for recovering highly pure $CO_2$ from the mixed gases was tested. In this study, activated carbon fibers were used as an adsorbent. The activated carbon fibers showed fast adsorption rate and the high adsorption capacity for $CO_2$ adsorption under the condition of the ambient pressure. Activated carbon fiber with higher specific surface area was suitable to repeated adsorption-desorption cycle process, showing consistent breakthrough curve. Especially, the regeneration method by vacuum combined with ESA improved the performance of desorption process by an additional 17% regeneration efficiency compared to a vacuum only method, and showed the high regeneration efficiency at comparatively low 7-8 Wh energy.

Characteristics of Desorption for Benzene in Activated Carbon and Zeolite 13X Packed Bed (벤젠에 대한 활성탄 및 제올라이트 13X를 충진한 흡착탑에서 탈착 특성)

  • Kang, Sung-Won;Suh, Sung-Sup;Min, Byung-Hoon
    • Applied Chemistry for Engineering
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    • v.17 no.2
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    • pp.201-209
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    • 2006
  • Various desorption methods were investigated for an activated carbon and zeolite 13X packed bed after benzene adsorption. Desorption experiments using hot steam, purge gas, and evacuation were performed. As a result, the desorption with hot steam showed the best performance. Hot steam makes the temperature in the adsorption column increase and gives arise to the desorption. Drying process should be accompanied to increase the efficiency because steam vapor prevents the adsorption later. The vacuum desorption showed poor performance and it reveals that temperature swing operation is more effective than pressure swing operation. In the purge gas desorption, good performance was achieved using evacuation.

Effects of activated carbon packing length in PSA process for production of high-purity hydrogen (고순도 수소제조를 위한 PSA 공정에서 활성탄 충전길이 효과)

  • Paik, Eun-gyu;Choi, Min-Ho;Suh, Sung-Sup
    • Clean Technology
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    • v.7 no.2
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    • pp.127-132
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    • 2001
  • The effects of activated-carbon (AC) packing length on the Pressure Swing Adsorption (PSA) performance was investigated for the hydrogen separation from the multicomponent mixture gas. Linear driving force model was used to describe mass transfer between two phase and coupled Langmuir isotherm was used for each component as a nonlinear adsorption isotherm. When two adsorbents with a different adsorption capacity were packed consecutively in one bed, it is very important to determine the packing ratio of zeolite to activated carbon affecting the purity and recovery of the product. The activated carbon packing length in adsorption tower of 120 cm was determinated by the ending point of $CO_2$ contration. The optimum length of an activated carbon layer was 65 cm for production of high-purity hydrogen.

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