• Journal of the Korean Chemical Society
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• v.29 no.5
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• pp.482-489
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• 1985

The substituted quinolinium salts of pentachlorooxomolybdate (V) have been synthesized and characterized by means of the investigation of elemental analysis, infrared spectra, electron spectra, electric conductivity. The results of elemental analysis were well coincided with the theoretical value and all prepared salts were mononuclear complexes. The complexes were binary univalent electrolytes and analyzed d-d transition and charge transfer transition.

• The Bulletin of The Korean Astronomical Society
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• v.35 no.1
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• pp.89.2-89.2
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• 2010

우리는 목성의 emission과 absorption 스펙트럼에 영향을 미치는 인자를 알아보고 목성의 대기구조를 연구하기 위하여 2006년 4월 18일부터 8월22일 사이 중 7일간 United Kingdom Infrared Telescope(UKIRT)의 고분산분광기 CGS4(R=37,000)를 이용하여 관측한 목성의 $2.86-3.53{\mu}m$ 분광관측 자료를 분석하였다. 관측자료의 분석에는 $CH_4,\;CH_3D,\;NH_3,\;C_2H_2,\;C_2H_6,\;PH_3$, HCN의 분광선 뿐만 아니라 구름과 Haze의 영향도 포함하는 대기모델을 사용하였다. 대부분의 관측된 분광선은 모델링을 통하여 얻은 synthetic spectrum과 일치하였으나 3.00 에서 $3.10{\mu}m$사이에서 일치하지 않는 다섯 개의 미확인 분광선을 발견하였다. 이들은 각각 $3.003{\mu}m$ 근처와 3.0505, 3.0735, $3.0865{\mu}m$ 그리고 $3.0935{\mu}m$에서 나타나며, 미확인 분광선들이 Seo et al.(2007)이 언급한 태양의 적외선 흡수선에 의해서 나타나는 분광선이 아님을 보였다. 우리는 이 미확인 분광선들을 설명할 수 있는 가능한 분자들을 제시 하고자 한다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2012.11a
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• pp.103-104
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• 2012

고상반응법을 사용하여 $Eu^{3+}$ 이온의 농도를 변화시키면서 $Ba_{1-x}MoO_4:Eu{_x}^{3+}$ 형광체 분말을 제조하였다. 합성한 적색 형광체의 결정 구조, 표면 형상, 발광 및 흡수 스펙트럼은 각각 XRD, SEM, 자외선-가시광선 분광기를 사용하여 조사하였다. 형광체 분말의 결정 구조는 $Eu^{3+}$ 이온의 농도비에 관계없이 $2{\theta}=26.52^{\circ}$에 주 피크를 갖는 정방정계이었으며, 최대 적색 발광 스펙트럼은 618 nm에서 관측되었다.

• Journal of the Korean Chemical Society
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• v.19 no.1
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• pp.16-20
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• 1975

3-Molybdo-9-tungstophosphoric acid, 6-molybdo-6-tungstophosphoric acid and their one-electron and two-electron reduction products have been synthesized. Infrared spectra show that all of them have Keggin structure. Polarograms and optical spectra of the reduced species are reported. Both data indicate that each additional electron is localized on a molybdenum atom.

• Korean Journal of Food Science and Technology
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• v.11 no.3
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• pp.166-170
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• 1979

A rapid and simple method for detecting chemical preservatives was attempted on the basis of emitted fluorescence at the illumination of UVSL-25 mineral light. Absorption and fluorescence spectra of powdered samples dispersed in liquid paraffin revealed characteristic patterns depending on chemical preservatives. Detection of chemical preservatives was more readily accomplished by simultaneous comparison of spectral characteristics at long and short wave ranges of the exciting light.

• Journal of the Korean Magnetics Society
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• v.11 no.2
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• pp.58-62
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• 2001

The L $i_{0.5}$F $e_{2.5-x}$A $l_{x}$ $O_4$ systems (x=0, 0.3, 0.6, 0.9, 1.2, 1.5) were investigated by X-ray diffraction and Mossbauer spectroscopy. The structure of all the samples is cubic spinel type and lattice constant decrease with increasing Al content x. The Moissbauer spectra reveal two sextet for 0$\leq$x$\leq$0.6, two sextet and a doublet for 0.9$\leq$x$\leq$1.2, and a doublet for x=1.5. The cation distribution of the samples is (L $i_{1-a}$$^{+}$F $e_{a}$ $^{3+}$)$^{A}$[L $i_{a-0.5}$$^{+}$A $l_{2.5-a-x}$$^{+}$F $e_{2.5-a-x}$$^{3+}$]$^{B}$ $O_4$$^{2-}$ and substituted $Al^{3+}$ ions decrease the covalency of F $e^{3+}$- $O^{2-}$ bond in B-sites and A-B super-exchange interactions.tions.s.tions.ons.s.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.19 no.1
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• pp.36-44
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• 1986

Nondialyzable melanoidins prepared from a glucose-glycine system were investigated as to their decolorization and degradation products on of one treatment. Melanoidins were decolorized to degree of $84\%\;and\;97%$ after ozonolysis at $-1^{\circ}C$ for 10 min and 90 min, respectively, and the mean molecular weight of melanoidins decreased from 7,000 to 3,000 after ozonolysis for 40 min. IR measurement showed that the absorption at $1,290\;cm^{-1}$ disappeared and that at $1,720\;cm^{-1}$ newly appeared on ozonolysis, and the absorption at $1,620\;cm^{-1}$ disappeared on acid hydrolysis after ozonolysis. Furthermore, the major degradation products in the ether-soluble fractions obtained from ozone-treated melanoidins were identified as butanedioic acid, glycolic acid, 2-hydroxybutanoic acid and so on. In the aqueous fraction, one or the major products was glycine, which was produced to the level of $1.05\%$ on ozonolysis which increased to $5.75\%$ per melanoidin on acid hydrolysis after ozonolysis. From these findings and the IR results, it is postulated that glycine was considerably incorporated into melanoidin molecules as the amide form.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.16 no.4
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• pp.397-410
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• 2018

When considering the long-term safety assessment of spent-nuclear fuel management, americium is one of the most radio-toxic actinides. Although spectroscopic methods are widely used for the study of actinide chemistry, application of those methods to americium chemistry has been limited. Herein, we purified $^{241}Am$ to obtain a highly pure stock solution required for spectroscopic studies. Quantitative and qualitative analyses of purified $^{241}Am$ were carried out using liquid scintillation counting, and gamma and alpha radiation spectrometry. Highly sensitive absorption spectrometry coupled with a liquid waveguide capillary cell and time-resolved laser fluorescence spectroscopy were employed for the study of Am(III) hydrolysis and oxalate (Ox) complexation. $Am^{3+}$ ions under acidic conditions exhibit maximum absorbance at 503 nm, with a molar absorption coefficient of $424{\pm}8cm^{-1}{\cdot}M^{-1}$. $Am(OH)_3(s)$ colloidal particles formed under near neutral pH conditions were identified by monitoring the absorbance at around 506-507 nm. The formation of ${Am(Ox)_3}^{3-}$ was detected by red-shifts of the absorption and luminescence spectra of 4 and 5 nm, respectively. In addition, considerable enhancements of the luminescence intensities were observed. The luminescence lifetime of ${Am(Ox)_3}^{3-}$ increased from 23 to 56 ns, which indicates that approximately six water molecules are replaced by carboxylate ligands in the inner-sphere of the Am(III). These results suggest that ${Am(Ox)_3}^{3-}$ is formed through the bidentate coordination of the oxalate ligands.

• Journal of Korean Ophthalmic Optics Society
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• v.12 no.1
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• pp.23-33
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• 2007

It has been reported high concentrations of zinc and taurine in ocular tissue, especially the retina-choroid, and the presence of physiological levels of zinc and taurine in these tissues seem essential for their normal function. In addition, several studies have reported temperature as another effector to the visual sensitivity. But, in spite of many studies, there are still remained many questions about their function and correlation in visual adaptation system. The purpose of present study was to clarify these points using electroretinogram(ERG) recording and absorption spectra scanning, before and after zinc and taurine treatments and hypothermic-effect in bullfrog(Rana catesbeiana) which is one of the poikilothermal animal. The optimal zinc concentration used in this study was determined $10^{-4}M$ while the optimal taurine concentration was 10-5 M, and temperature change for hypothermic-effect went through '$25^{\circ}C {\rightarrow}0^{\circ}C{\rightarrow}25^{\circ}C$'. In ERG recording, it is obtained that dark-adapted threshold became elevated and b-wave amplitudes was increased with zinc and taurine treatment and hypothermic-effect. In absorption spectra scanning, there is distinct absorbance increment over the whole spectral range(400~750 nm) after zinc and taurine treatment and hypothermic-effect. Furthermore there are some synergism effects between zinc and taurine as well as between zinc and hypothermic-effect as a result of co-treatment, respectively.

• Journal of the Korean Magnetics Society
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• v.6 no.6
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• pp.397-404
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• 1996

The magnetic properties of $Ni_{1-x}Zn_{x}Fe_{2}O_{4}$ have been studied by X-ray diffractometry and $M\"{o}ssbauer$ Spectroscopy at room temperature. The X-ray diffraction study show that spinel structure is formed in all x, lattice constants linearly increased from $8.3111{$\AA$}~8.4184{$\AA$}({\pm}0.0003)$ with increasing x from 0 to 1, and oxygen parameter increase with increasing x. $M\"{o}ssbauer$ spectrum shows that $Ni_{1-x}Zn_{x}Fe_{2}O_{4}(x=0)$ has two antiparallel magnetic structure due to $Fe^{3+}$ octahedral site and $Fe^{3+}$ tetrahedral site. $Ni_{1-x}Zn_{x}Fe_{2}O_{4}$ with $0.2{\leq}x{\leq}0.6$ has magnetic structure of Yafet and Kittel, in particularly, specimen with x=0.6 shows relaxation effect. Specimen with $x{\geq}0.8$ show paramagnetic quadrupole splitting. The isomer shift is independent of x, but quadrupole splittings decrease with increasing x in the range of $0.8{\leq}x{\leq}1$, and nuclear magnetic fields decrease with in¬creasing x in the range of $0{\leq}x{\leq}0.6$. The magnetic properties of $Ni_{1-x}Zn_{x}Fe_{2}O_{4}$ change from ferrimagnetics to pararnagnetics with increasing x.