• Title/Summary/Keyword: 휘발성 고형물

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Anaerobic Acid and Methane Fermentation using Paper Wastes (폐지를 이용한 혐기성 산 발효 및 메탄발효 특성)

  • 조건형;김중곤;김성준;김시욱
    • KSBB Journal
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    • v.18 no.4
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    • pp.318-323
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    • 2003
  • This study was carried out to investigate the possibility of reusing newspaper or paperbox waste by methane fermentation. When 15 g of newspaper and box wastes were digested separately for 24 days by batch fermentation, the amount of total organic acids produced were 2461 and 4978 mg/L, respectively. The tCOD removal rates were found to be 60.9 and 62.4%, respectively. In addition, the removal efficiencies of total solid were 34.8 and 33.4%, and those of volatile solid were 40.0 and 39.2%, respectively. During this period, the amounts of biogas produced were 6.95 and 6.43 L. In a semicontinuous reaction, tCOD removal efficiencies for newspaper and box wastes were 64.7 and 65.0%, respectively, after 14 days of digestion. After 25 days, which were needed to stabilize the methane fermentation, the amounts of biogas produced daily were 0.31 and 0.30 L/g.dry wt, respectively. Methane contents were 57.3 and 56.2%, respectively, and the pHs in the anaerobic acidogenic and methanogenic fermenters were 5.0 and 7.5, respectively.

Heavy Metals in Road Deposited Sediments and Control of Them in Urban Areas: A Review (문헌고찰에 의한 도시 지역 도로퇴적물의 중금속 특성 및 적정 관리방안)

  • Kim, Do Gun
    • Land and Housing Review
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    • v.13 no.3
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    • pp.125-140
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    • 2022
  • Road Deposited Sediment (RDS) is the solids formed from the wear of road, wear of vehicles, exhausts, and the input of the emissions from various sources out of the roads. RDS is seriously polluted by organic matter, nutrients, and metals. RDS plays an important role as the sink and the transport medium of the associated pollutants because RDS can be carried to the adjacent water system via stormwater runoff. In this regard, the heavy metals in RDS were investigated based on the publications. The contents of the metals in RDS were highly variable. The concentration of Cr, Ni, Cu, Fe, Zn, As, Cd, and Pb in urban RDS in various regions was in a range of 3.16-3,410, 1.15-1,382, 20.2-9,069, 2,980-124,853, 81-2,550, 2.3-214, 0.19-21.3, and 15.21-1,125 mg/kg, respectively. The anthropogenic enrichment of the metals in RDS was confirmed by the high concentration of Cu, Zn, Cd, and Pb. The contents of the metals were higher in industrial and traffic areas than in residential areas, while they were generally increased with decreasing particle size. It is believed that this study's results would contribute to quantifying the metals' load via RDS and establishing control strategies.

Behaviors of Pollutants and Microorganisms in an Anaerobic Digestion of Propionate Containing High Ammonia Nitrogen Level (고농도 암모니아성 질소를 함유한 프로피온산의 혐기성 분해시 오염물질 및 미생물 거동)

  • Lee, Chae-Young;Kim, Dae-Sung;Ahn, Won-Sik;Shin, Hang-Sik
    • Journal of the Korea Organic Resources Recycling Association
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    • v.14 no.3
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    • pp.126-137
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    • 2006
  • Behaviors of simple organic compound and granular sludge in an upflow anaerobic sludge blanket (UASB) reactor treating propionate at high ammonia nitrogen levels were investigated for 12 months. The UASB reactor achieved about 80% removal of chemical oxygen demand (COD) at ammonia nitrogen concentration up to 6000 mg-N/L. At higher concentration of ammonia nitrogen, the propionate in the effluent increased whereas the acetate was very low. At ammonia nitrogen concentration of 8000 mg-N/L, the volatile suspended solids (VSS) increased sharply due probably to the decrease of the content of extracellular polymer (ECP) although methane production was very low. The specific methanogenic activity (SMA) using formate, acetate, and propionate as substrate to granules decreased as ammonia nitrogen concentration increased. The ammonia nitrogen concentration $I^{50}$, causing 50% inhibition of SMA were 2666, 4778 and 5572 mg-N/L, respectively. The kinetic coefficients of ammonia inhibition using formate, acetate, and propionate as substrate were 3.279, 0.999 and 0.609, respectively. The SMA using formate was severely affected by ammonia nitrogen than those using acetate and propionate. This result indicated that the hydrogenotrophic methanogens was most affected by ammonia nitrogen. Granules were mainly composed of microcolonies of methanothrix-like bacteria resembling bamboo-shape, and several other microcolonies including propionate degrader with juxtapositioned syntrophic associations between the hydrogen-producing acetogens and hydrogen-consuming methanogens.

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Stabilization/Solidification of Radioactive LiCl-KCl Waste Salt by Using SiO2-Al2O3-P2O5 (SAP) inorganic composite: Part 1. Dechlorination Behavior of LiCl-KCl and Characteristics of Consolidation (SiO2-Al2O3-P2O5 무기복합체를 이용한 LiCl-KCl 방사성 폐기물의 안정화/고형화: Part 1. LiCl-KCl의 탈염화 반응거동 및 고형화특성)

  • Cho, In-Hak;Park, Hwan-Seo;Ahn, Soo-Na;Kim, In-Tae;Cho, Yong-Zun
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.1
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    • pp.45-53
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    • 2012
  • The metal chloride wastes from a pyrochemical process to recover uranium and transuranic elements has been considered as a problematic waste difficult to apply to a conventional solidification method due to the high volatility and low compatibility with silicate glass. In this study, a dechlorination approach to treat LiCl-KCl waste for final disposal was adapted. In this study, a $SiO_2-Al_2O_3-P_2O_5$ (SAP) inorganic composite as a dechlorination agent was prepared by a conventional sol-gel process. By using a series of SAPs, the dechlorination behavior and consolidation of reaction products were investigated. Different from LiCl waste, the dechlorination reaction occurred mainly at two temperature ranges. The thermogravimetric test indicated that the first reaction range was about $400^{\circ}C$ for LiCl and the second was about $700^{\circ}C$ for KCl. The SAP 1071 (Si/Al/P=1/0.75/1 in molar) was found to be the most favorable SAP as a dechlorination agent under given conditions. The consolidation test revealed that the bulk shape and the densification of consolidated forms depended on the SAP/Salt ratios. The leaching test by PCT-A method was performed to evaluate the durability of consolidated forms. This study provided the basic information on the dechlorination approach. Based on the experimental results, the dechlorination method using a $SiO_2-Al_2O_3-P_2O_5$ (SAP) could be considered as one of alternatives for the immobilization of waste salt.

Analysis and Research of Water Quality in the Gun-Po (군포시 수질 기초조사 및 분석(약수 및 퇴적토 중심으로))

  • Bae Joon-Sam;Lee Sang-Ho;Kim Sun-Hee
    • Proceedings of the KAIS Fall Conference
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    • 2004.06a
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    • pp.270-274
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    • 2004
  • 군포시는 인구 27만 376명(2001)의 도시로서 녹지지역, 공업지역, 주거지역, 상업지역이 혼재되어 있는 복합기능의 기존 도시지역과 최근의 도시계획에 의하여 도시기능들이 분리되어 있는 신도시지역으로 구성되어 있어서 전체적으로 복합도시의 성격을 갖고 있다. 이러한 특성으로 인하여 지역별 환경오염의 정도가 다르게 나타나고 있다. 따라서 본 연구는 군포시 환경현황을 알아보기 위해 17개 지점의 퇴적토와 16개 지점의 약수터를 선정하여 군포시의 환경문제 가운데 하상퇴적물과 음용수로 사용하고 있는 약수터의 수질환경 변화를 월별로 비교$\cdot$분석하였다. 그 결과 휘발성고형물(VSS)은 도시권 영역인 당정천 지역(9,10)에서 높은 농도를 보였으며, 영양염류의 지표인 총질소(T-N)와 총인(T-P)의 경우 생활하수의 직접적인 영향을 받고 있는 15지점이 T-N 12.2mg/kg, T-P 6.09mg/kg의 농도를 보이고 있으며 중금속의 농도는 공업지역 부근인 3,9,10지점에서 납의 농도가 다른 중금속에 비하여 높은 것으로 조사되었다. 약수의 경우 모든 음이온 항목이 먹는물 수질기준을 만족하고 있으므로 건강상 유해한 영향이나 심미적인 영향을 미치지 않을 것으로 사료된다.

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Effect of Compression Treatment on Characteristics of Solidified Cow Manure Fuel (우분 압착 처리가 우분 고체연료 특성에 미치는 영향)

  • Jeong, Kwang-Hwa;Kim, Jung-Kon;Lee, Dong-Jun;Cho, Won-Mo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.24 no.2
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    • pp.67-74
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    • 2016
  • This study was purposed to evaluate the characteristic changes of the solidified livestock manure fuel(SLMF) through the application of compression treatment process. The compression process led to an increase of VS/TS ratio (Volatile solids/Total solids ratio) and moisture removal effect of SLMF. The amount of leachate withdrawn from dairy cattle manure and Hanwoo manure by compression were 21~26%(w/w) and 15~20%(w/w), respectively. The specific gravity of the leachate of dairy cattle manure and Hanwoo manure were 1.01 and 0.99, respectively. The dehydrated cow manure was easily processed into ball-shaped solidified fuel. The drying time of the SLMF was proportional to the diameter of the solidified fuel. The highest heating value was observed in diameter range of 10~15mm SLMF. It is concluded that the higher heating value of 10~15mm SLMF was related with the amount of fibrous matter contained in the SLMF.

Study on Torrefaction Characteristics of Solid Biomass Fuel and Its Combustion Behavior (바이오매스 고형연료의 반탄화 특성 및 반탄화물의 연소특성에 관한 연구)

  • Lee, Weon Joon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.23 no.4
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    • pp.86-94
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    • 2015
  • Torrefaction is a thermochemical process proceeded at the temperature around $250^{\circ}C$ in an inert gas condition. By torrefaction, the hemicellulose portions contained in biomass are broken down to change into the volatile gas which is removed from biomass eventually. The main purpose of biomass torrefaction is to improve the energy density of the biomass to minimize the transport energy consumption, though the flammability can be elevated for transportation. In this study two types of solid biomass fuel, waste wood and rice straw, were torrefied at various temperature range from $200^{\circ}C$ to $300^{\circ}C$ to evaluate the torrefied biomass characteristics. In addition torrefied biomass were tested to evaluate the combustion characteristics using TGA (Thermogravimetric Analysis). After the torrefaction of biomass, the C/H (carbon to hydrogen ratio) and C/O (carbon to oxygen ratio) were measured for aquisition of bio-stability as well as combustion pattern. Generally C/H ratio implies the soot formation during combustion, and the C/O ratio for bio-stability. By torrefaction temperature at $300^{\circ}C$, C/H ratio and C/O ratio were increased by two times for C/H and three times for C/O. The torrefied biomass showed similar TGA pattern to coal compared to pure biomass; that is, less mass decrease at lower temperature range for torrefied biomass than the pure biomass.

Quality Characteristics of Kimchi Prepared for the Winter around Chonnam Area (전남지역 김장 배추김치의 품질 특성)

  • 박복희;조희숙;유맹자
    • Korean Journal of Human Ecology
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    • v.6 no.2
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    • pp.57-65
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    • 2003
  • To investigate quality characteristics of kimchi prepared for the winter around Chonnam area, home made kimchi samples collected from 22 area, and they were stored at -1${\pm}$1$^{\circ}C$. The results were as follows : The pH and acidity of kimchi samples were 4.75 and 0.84%. respectively. Salt concentration was 3.50% and in Redox potential measurement, Eh value was -134.08mV. Ascorbic acid and reducing sugar contents were 10.l8mg% and 13.25mg%, respectively, In color measurement, L value was 52.29 and a and b values were 19.68 and 27.69, respectively. Total viable count was 5.5${\times}$10$\^$6/ and lactic acid bacteria count and yeast were 4.6${\times}$10$\^$5/ and 8.8${\times}$10$\^$5/. respectively. Properties of hardness of kimchi measured instrumentally was 9.26kgf. Alcohol insoluble solids(AIS) content was 5.53% and hot water soluble pectin(HWSP) content and sodium hexametaphosphate soluble pectin(NaSP) content were 17.35% and 29.65%, respectively, also hydrochloric acid soluble pectin(HClSP) content was 53.0%.

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Characteristics of Variation of Suspended Matters in the Cheju Coastal Area of Korea (제주 연안해역의 부유물질 변화특성)

  • Youn, Jeung-Su;Pyen, Choong-Kyu
    • Journal of Aquaculture
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    • v.5 no.1
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    • pp.93-108
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    • 1992
  • This study was conducted to understand the variation of suspended matters in coastal waters of Cheju Island. Water sampling was carried out at 22 stations along the coast of this island from March 1988 to November 1989. Analyzed and/or observed items were water temperature, salinity, total solids (TS), total dissolved solids (TDS), volatile suspended solids (VSS), and fixed suspended solids (FSS). Inter-relationships between wind velocity, precipitation and total suspended solids (TSS) were also investigated. More windy days prevail in winter season (December, January and February) in Cheju Island. Thirty-six points seven percent of total windy days of a year appeared in this season. The rate of windy days in spring was $27.3\%$ and those in summer and fall were $17.9{\%}$ each. From February to July, the heaviest precipitation was observed in the southeastern area and that from August to January was observed in the eastern part of this island. TS and TDS were firmly related with the fluctuation of salinity. Therefore, there were higher in spring and lower in summer. The highest TSS (7.73 $mg/{\ell}$) was observed in February and was the lowest (4.73 $mg/{\ell}$) in September. Annual mean value of TSS was 6.3$mg/{\ell}$. The highest VSS (2.03 $mg/{\ell}$) was observed in July and lowest (1.42 $mg/{\ell}$) in September. The percentage of VSS per 755 was $30.6{\%}$ in average that was not much higher level compared to the other polluted areas. This value became higher in summer (av. $34.17{\%}$) and lower in winter (av. $24.2{\%}$). Fluctuation of TSS was mainly related with the freshwate. discharge, tidal action, and re-suspension of bottom sediments by the wind waves. Therefore, TSS concentration was low in summer and hish in winter.

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Comparison of Volatile Flavor Compounds in Bokbunja [Rubus coreanus Miquel] Wines With and Without Mushroom Extracts (일반 복분자주와 버섯 추줄물을 함유한 복분자주의 향기성분 비교)

  • Shin, H.J.;Nam, H.G.;Lim, I.J.;Cha, W.S.
    • KSBB Journal
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    • v.21 no.6 s.101
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    • pp.410-413
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    • 2006
  • The composition of two Bokbunja (Rubus coreanus Miquel) wines (one without mushroom extracts (wine A) and the other is with the extracts (wine B)) has been investigated to improve the quality of Bokbunja wine. The content of solid particle, acidity, crude ash, crude protein of the wine A were 10.5%, 1.36%, 0.45% and 0.05% and those of wine B were 7.4%, 0.54%, 0.31%, and 0.22%, respectively. Crude fat and crude fiber were not detected in both samples. To verify the flavor quality of Bokbunja wine, the volatile components from ethylether extracts of two wines were analyzed using GC/FID and GC/MS. A total number of 12 volatile flavor compounds (6 alcohols, 3 ketones, 1 acid, 1 ester and 1 anhydride) were identified in the two Rubus wines. The major volatile compounds of the wines were 2,3-butanediol, 2,5-furanedione, phenylethyl alcohol, and butanedioic acid and they might affect the major role in the unique flavor of Bokbunja wines.