• Title/Summary/Keyword: 회분 반응기

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QRA를 이용한 회분식 반응기의 위험특성 조사

  • 강미진;이영순;이근원;김창은
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2003.10a
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    • pp.44-47
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    • 2003
  • 중소규모 사업장의 대부분은 회분식 반응공정을 이용하여 소량 다품종의 제품을 생산한다. 회분식 공정은 연속식 공정에 비해 수동운전의 비율이 높아서 인적오류에 의한 사고발생 가능성이 상대적으로 높으며, 사고 발생 시 인적 피해가 크게 나타날 수 있는 가능성을 내포하고 있다. 또한 대규모의 사업장에 비해 적절한 위험성평가나 안전관리가 이루어지기 어렵다. 따라서 회분식 공정에서의 위험특성을 구체적으로 규명하고, 이를 바탕으로 회분식 반응기에서의 사고를 예방하기 위한 일반적인 가이드를 제시하고자 한다. 이러한 회분식 공정의 위험성평가와 관련하여 영국 및 미국 화공학회에서는 화학반응 및 회분식 반응공정의 위험성평가 지침을 제시하고 있다.(중략)

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Characteristics of $\beta$-Glucosidase Immobilized on the Modified Chitin in Bioresctors (수식 Chitin에 고정된 $\beta$-Glucosidase의 동특성)

  • 이경희;김종덕김병우송승구
    • KSBB Journal
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    • v.5 no.3
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    • pp.279-291
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    • 1990
  • Partial hydrolysed and deacetylated chitin, CHITA and CHITB as supports of immobilized enzyme were obtained by treatment of acid and base respectively. Glutaraldehyde, bifunctional reagent, was employed for crosslinking between $\beta$-glucosidase and support. Immobilized enzyme activities of CHITA-Gase and CHITB-Gase were determined with the reaction of p-nitrophenol-$\beta$-D-glucopyranoside(PNG) in batch reactor, CSTR and PFR. Their optimum temperature, pH and enzymatic characteristics including Km and Vmax values were observed with variation of the flow rates. Mass transfer coefficient(h), effectiveness factor(η), deactivation rate(kd ) of two immobilized enzymes were also examined to compare efficiency of reactors.

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Volatile Organic Compounds Production from Aerobic Biotreatment of Dairy Wastewater by a Sequencing Batch Reactor (연속회분식반응기(SBR)에 의한 낙농폐수의 호기성처리에서 휘발성유기물질 발생)

  • Hong, Ji-Hyung
    • Journal of Animal Environmental Science
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    • v.11 no.1
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    • pp.17-24
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    • 2005
  • Aerobic sequencing batch reactor (SBR) was used to treat screened dairy wastewaters. The study examined the production of volatile organic compounds (VOCs) and volatile fatty acids (VFAs) in the aerobic SBR and raw manure effluent storage over 35 days. The reduction of total VFAs in the aerobic SBR was over $59\%$ removal than that of the raw manure. Acetic acid production in the aerobic SBR and the raw manure effluent storage were kept 138 and 286 mg/L. The propionic acid in the aerobic SBR was 1.9 mg/L, while the raw manure effluent storage was 68 mg/L, respectively. The concentrations of VOCs in the aerobic SBR reactor and effluent fill down remarkably than the raw manure storage. The results confirmed that the aerobic biological treatment is an essential requirement for minimizing odor problems.

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니트로화합물의 혼합위험 특성연구

  • 김관응
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2003.05a
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    • pp.297-302
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    • 2003
  • 국내 화학공업에 있어서 두드러진 특징중의 하나는 의약품, 염·안료 등과 같은 부가가치가 매우 큰 제품을 제조하는 정밀화학공업이 대부분을 차지하고 있으며, 반응기는 회분식으로 대상이 되는 공정의 반응조건 등을 제조자 스스로 결정해야 하는 것이 많아 오조작이나 열분해반응이나 폭주반응과 같은 이상반응 발생 시 조기 제어 미흡 등으로 인한 화재 폭발 등 중대사고가 발생할 위험성이 매우 크다. 실제로 회분식 반응기에 의한 사고가 빈번히 발생하였고 사고에 의한 피해도 심각하다.(중략)

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Development of a Diagnosis Algorithm of Influent Loading Levels Using Pattern Matching Method in Sequencing Batch Reactor (SBR) (연속회분식반응기에서 패턴매칭방법을 이용한 유입수 부하수준 진단 알고리즘 개발)

  • Kim, Ye-Jin;Ahn, Yu-Ga;Kim, Hyo-Su;Shin, Jung-Phil;Kim, Chang-Won
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.2
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    • pp.102-108
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    • 2009
  • DO, ORP and pH values measured during SBR operation can provide information about removal reaction of organic contaminants and nutrient materials in the reactor. It is already generalized control strategy to control reaction phase time using their special patterns indicating the end of the removal reactions. However, those informations are limited to point out the end time of oxidative reaction in the aerobic phase or reductive reaction in the anoxic phase without giving quantitative value of influent loading level. In this research, a diagnosis algorithm which can estimate the loading level of carbon and ammonia as high, medium and low was developed using the basic measurements like DO, ORP, and pH. It will be possible to know the level of influent loading rate from those online measurements without experimental analysis.

Study of Continuous Production of Alcohol using Biologically Sandwich-styled Immobilization Carrier (샌드위치식 고분자담체를 이용한 알코올 연속생산연구)

  • Park, Young-G.;Kim, Hee-Jung
    • KSBB Journal
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    • v.23 no.3
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    • pp.213-218
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    • 2008
  • The present study was to investigate the continuous production of alcohol using immobilized carrier manufactured by polymeric materials. Fermentation runs with a crushed rice, with constituents recovered from batch culture and with ones from continuous culture were thus compared. The performances of immobilized carrier were governed by sandwitched synthetic polymers, the evolution of the continuous culture was steadily governed by the production of alcohol in the lag time of batch culture. The main focus was set on the enhancement of the alcohol production by an newly-developed polymeric forms. This polymeric form led to a drastic increase of the microorganism and the production cost in the continuous reactor was thereby reduced. The sandwitched polymeric-formed carrier, which was resistant to external environments, serves as an interesting alternative to maintain the stability of biological process. These whole results were discussed with the aim to better understand the continuous process implied in the microorganism's build-up during cultivation of fermentation broth.

Pyrolysis of Polyethylene using Batch Microreactor (회분식 미분반응기를 이용한 폴리에틸렌의 열분해특성 연구)

  • CHa, Wang-Seog;Kim, Sang-Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.553-556
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    • 2005
  • Pyrolysis of polyethylene was carried out in the stainless steel reactor of internal volume of $40cm^3$. Pyrolysis reactions were performed at temperature $390-450^{\circ}C$ and the pyrolysis product were collected separately as reaction products and gas products. The molecular weight distributions(MWDs) of each liquid product were determined by GC-SIMDIS. Molecular weight of each product were decreased wi th increase of react ion temperature and time.

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A Study on High Strength Nitrogen Wastewater Treatment and Sludge Granulation Characteristics in a Pilot-scale Air-lift Sequencing Batch Reactor (파일럿 규모의 공기 유동 연속회분반응기에서 고농도 질소제거 및 슬러지 그래뉼화 특성 연구)

  • Lee, Soochul;Kim, Dong-Jin
    • Clean Technology
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    • v.18 no.4
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    • pp.398-403
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    • 2012
  • Selective nitrification and granulation have been carried out in a pilot scale air-lift sequencing batch reactor (SBR) for stable and economical nitrogen removal from wastewater. The SBR showed about 100% nitrification efficiency up to 1.0 kg ${NH_4}^+-N/m^3{\cdot}d$, about 90% efficiency at 1.0-2.0 kg ${NH_4}^+-N/m^3{\cdot}d$, and it was less than 90% when the load was higher than 2.0 kg ${NH_4}^+-N/m^3{\cdot}d$. Nitrite accumulation was induced by selective inhibition of nitrite oxidizing bacteria by free ammonia inhibition and dissolved oxygen limitation. For the purpose, high nitrite ratio (> 0.95) was obtained by keeping the pH higher than 8.0 and dissolved oxygen lower than 1.5 mg/L. In addition, sludge granulation was achieved by keeping reactor settling time to 5 minutes to wash out poor settling sludge and to promote the growth of granulation sludge. The operation accelerated sludge granulation and the sludge volume index (SVI) decreased and stably maintained to less than 75 in 60 days.

UV light transmittance in modified two-dimensional fluidized bed photocatalytic reactor (변형된 이차원 유동층 광촉매 반응기에서의 자외선 투과도 측정)

  • 임탁형;김상돈
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1999.11a
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    • pp.67-70
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    • 1999
  • 최근에 들어서 태양에너지의 화학적 에너지로의 변환에 대한 연구는 에너지 부족에 대한 대안으로서 각광을 받고 있는 분야이다. 이런 관심을 바탕으로 한 다양한 연구는 연속식 또는 회분식 반응기를 이용한 불균일계 촉매를 이용함으로써 진행되고 있고, 특히 기-액, 기-고 그리고 기-액-고상 반응기를 응용하는 광촉매 반응에 관심이 증폭되고 있다. 그리고 광촉매 반응이 실제 산업계에서 활용되기 전에 먼저 불균일계 광촉매 반응기의 설계기준에 대한 연구가 선행되어야 하며 실제 산업적인 응용측면에서도 광촉매 반응의 충분한 이용가능성에 관심이 이루어져야 한다.(중략)

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Citric Acid Production Using Immobilized Yeast Activated with $CaCl_2$ - containing Medium (고정화효모를 사용한 시트르산 생성에 있어서의 $CaCl_2$ 함유배지에 의한 활성화 효과)

  • 임동준;최차용
    • Microbiology and Biotechnology Letters
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    • v.14 no.4
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    • pp.285-291
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    • 1986
  • Immobilized Candida lipolytica cells were prepared by entrapping the whole cells in calcium alginate gel. To enhance citric acid productivity, immobilized cells were Incubated with activation medium in fluidized-bed reactors. When the activation was done in batch operation, maximum citric acid productivity appeared in a much shorter time than in continuous operation. Activated immobilized cells were enhanced about 10-fold in citric acid production relative to non-activated immobilized cells. The productivity of citric acid was also influenced by bead size. When Immobilized cells were reacted in a fluidized-bed reactor with the same quantity of cells, the citric acid productivity was increased as the bead size was decreased.

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