• Title/Summary/Keyword: 황 제거

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Comparative Study on Adsorptive Removal of Organic Sulfur Compounds over Cu-Exchanged NaY Zeolites (구리로 이온교환된 NaY 제올라이트에 의한 유기 황 화합물들의 흡착제거 비교연구)

  • Jung, Gap Soon;Lee, Suk Hee;Cheon, Jae Kee;Park, Dong Ho;Woo, Hee Chul
    • Korean Chemical Engineering Research
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    • v.48 no.4
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    • pp.534-539
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    • 2010
  • The adsorptive removal of organic sulfur compounds including tert-butylmercaptane(TBM), tetrahydrothiophene(THT) and dimethylsulfide(DMS) in methane was investigated over NaY and copper-exchanged NaY(CuNaY) zeolites at 303 K and atmospheric pressure. In the ternary adsorption system, the preferential adsorption of THT over other sulfur compounds on NaY and the concurrent adsorption of all sulfur compounds on CuNaY were achieved, which could be explained by the breakthrough curve, the temperature-programmed desorption, and the apparent activation energy for desorption. The sulfur uptake capacity of CuNaY(2.90~3.20 mmol/g) was much higher than that of NaY(0.70~0.90 mmol/g). A comparative study indicated that the $Cu^{1+}$ sites and acidity of CuNaY were probably responsible for the strong interaction with sulfur atom and high sulfur uptake abilities.

The Geochemical Interpretation of Phase Transform and Fe-leaching Efficiency for Pyrite by Microwave Energy and Ammonia Solution (마이크로웨이브 에너지에 의한 황철석의 상변환과 암모니아 용액에 의한 Fe-용출 효율에 관한 지구화학적 해석)

  • Kim, Bong-Ju;Cho, Kang-Hee;Choi, Nag-Choul;Park, Cheon-Young
    • Journal of the Mineralogical Society of Korea
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    • v.26 no.3
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    • pp.139-150
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    • 2013
  • In order to effectively leach Fe from pyrite, the application of microwave energy and ammonia solution has been conducted. Pyrite transforms into hematite and pyrrhotite when treated with microwave radiation for 60 minutes, and in this time the highest amount of Fe was leached by the ammonia solution. Up to 99% of the Fe was leached when the experimental conditions were: 325-400 mesh particle size for the pyrite and 60 min. was the microwave exposure time. The ammonia leaching conditions were 0.3 M sulfuric acid, 2.0 M ammonium sulfate and 0.1 M hydrogen peroxide concentration. The pyrite, hematite, and pyrrhotite were not detected using XRD analysis from the solid-residues treated by the ammonia solution except for quartz.

Reuse of Hydrogen Sulfide by Ferric Chelate Reaction of Food Waste Anaerobic Digestion Gas, Sulfur Recovery and its Economic Evaluation (킬레이트 착화학반응에 의한 음식물폐기물 혐기소화가스 중 황화수소의 제거와 황회수 및 경제성평가)

  • Park, Young G.;Yang, Youngsun
    • Clean Technology
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    • v.20 no.4
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    • pp.367-374
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    • 2014
  • Several experiments have been done to investigate the removal of hydrogen sulfide ($H_2S$) synthetic gas from biogas streams by means of chemical absorption and chemical reaction with 0.1-1 M Fe/EDTA solution. The roles of Fe/EDTA were studied to enhance the removal efficiency of hydrogen sulfide because of oxidizing by chelate. The motivation of this investigation is first to explore the feasibility of enhancing the toxic gas treatment in the biogas facility. The biogas purification strategy affords many advantages. For instance, the process can be performed under mild environmental conditions and at low temperature, and it removes hydrogen sulfide selectively. The end product of separation is elemental sulfur, which is a stable material that can be easily disposed with minor potential for further pollution. As the Fe-EDTA concentration increased, the conversion rate of hydrogen sulfide increased because of the high stability of Fe-EDTA complex. pH as an important environmental factor was 9.0 for the stability of chemical complex in the oxidation of hydrogen sulfide.

Reduce Blocking Artifacts of Video Stream Using Regularized Image Restoration (동영상 스트림의 블록화 현상 방지를 위한 정규화 영상복원 기법)

  • 황인경;정시창;김성진;백준기
    • Proceedings of the IEEK Conference
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    • 2000.09a
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    • pp.709-712
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    • 2000
  • 본 논문에서는 인터 프레임(P-프레임) 압축으로 인해 발생되는 블록화 현상을 모델링 하고 기존에 정의된 제한요소를 효율적으로(reasonable) 축소하고 축소된 제한요소를 이용한 후처리를 통해 블록경계는 물론 블록 내부의 불연속을 효율적으로 제거하는 방법을 제안한다. 다음 프레임의 예측영상을 블록화가 제거된 영상을 사용함으로써 프레임간 영상 스트림에서도 주관적으로나 객관적으로나 현저하게 블록화가 제거된 영상을 얻을 수 있다. 제안된 알고리즘은 HDTV나 영상통신과 같은 영상 스트림의 후처리 과정에 적합하다.

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Studies on the Particular harmonics Elimination inverter Magnetron drive (마그네트론 구동용 인버터의 특정 고조파 제거에 관한연구)

  • Kim, Yang-Bea;Hwang, Jung-Ho
    • Proceedings of the KIEE Conference
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    • 2015.07a
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    • pp.1296-1297
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    • 2015
  • 마이크로 웨이브를 사용하는 기기들은 대량생산 공정에 있어서 식품 가공용 건조기기로 사용되고 있다. 3kW 마그네트론을 구동하기 위해서는 필라멘트를 가열하고 고압의 DC전원을 발생할 수 있는 회로가 필요하게 된다. 반도체 소자를 이용한 전력변환 장치로 DC로 운전이 되면 AC계통으로 혼입되는 고조파가 발생된다. 본 논문에서 AC계통으로 유입되는 특정고조파 제거 방법을 제안한다. 고조파 검출회로를 기반으로 전류를 제어함으로써 기존 LC필터에서 제거되지 못한 고조파성분이 감쇠되는 성능을 보였다.

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A Study on the Removal of Nitrogen and Phosphorus by Addition of Coagulant in the Sulfur Denitrification Process Coupled to the Membrane Bioreactor (MBR과 황탈질 공정에서 응집제 주입에 따른 질소.인 제거에 관한 연구)

  • Lee, Young-Ho;Yoo, Soung-Jong;Oh, Dae-Min;Lee, Young-Sin
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.10
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    • pp.949-956
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    • 2010
  • A method for simultaneous removal of nitrogen and phosphate from sewage by elemental sulfur denitrification with membrane bioreactor was proposed, and capacity $10\;m^3$/day of pilot plant was operated for 350 days. This study was investigated to have the effect of denitrification rate and T-P removal with the addition of Alum in Sulfur denitrification Reactor (SDR). The addition of Alum and alkalinity ($NaHCO_3$) in the effluent of MBR was tried to remove simultaneous phosphate and nitrogen in SDR. Characteristics of total nitrogen (T-N) and total phosphate (T-P) removal was compared without and with the addition of Alum as a coagulant. T-N removal without and with the addition of Alum was 92.1% and 87.8%, respectively. And denitrification efficiency was 93.8% and 87.1%, respectively. T-P removal rate was increased to 75.6% in SDR by addition of Alum (2.6~4 mg/L as Al), but T-P removal rate was about 26.7% without the addition of Alum. Therefore, denitrification rate was 6.7% of reduction but T-P removal rate was increased by addition of Alum.