• Resources Recycling
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• v.31 no.2
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• pp.49-55
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• 2022

In the present study, the thermodynamic evaluation of the sulfate-roasting process was conducted to extract vanadium from the Korean vanadium titano-magnetite ore. The leaching efficiency of vanadium and other impurities was analyzed for varying roasting temperatures and addition of Na₂SO₄. In the case of sulfate roasting, the roasting temperature was 200 ℃ higher than that previously observed Na₂CO₃ roasting. However, the higher leaching efficiency of vanadium and lower leaching efficiency of other impurities, such as aluminum and silicon, were observed. The high selectivity for the extraction of vanadium in sulfate roasting would result from the reaction mechanism between SO₂ gas and vanadium concentrate.

• Resources Recycling
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• v.19 no.3
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• pp.9-15
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• 2010

Domestic gold mine tailings, generally, contain a lot of non-metallic silica and clay minerals. These minerals can be separated from the tailings by various physical separation methods and used as raw materials for cements and ceramic products. In these physical separation procedures, metallic complex sulfides, in which Au and metallic constituents such as Pb, As and Fe were concentrated, were obtained as a by-product. These metallic constituents should be removed or separated from the by-product to extract Au efficiently. In this work, removal and separation processes of Pb, As, and Fe from the by-product were investigated. Pb was removed to under 3% by using alkaline oxidative leaching at the leaching condition of $120^{\circ}C$, 2M NaOH, 100psi $Po_2$, 250r.p.m., 4 wt.% solid and 30 min. leaching time. The leached residue was roasted and separated magnetically to obtain a non-magnetic product contained <0.2% As, <3% Fe and high concentrated Au more than 8,000 ppm.

• Resources Recycling
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• v.3 no.1
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• pp.17-24
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• 1994

Recovery of precious metal values from petrochemical spent catalyst is important from the viewpoint of environmental protection and resource recycling. Two types of spent catalysts were used in this study. One used in the manufacture of ethylene contains 0.3% Pd in the alumina substrate. The other used in oil refining contains 0.3% Pt and 0.3% Re. Both spent catalysts are roasted to remove volatile matters as carbon and sulfur. Then, metallic Pd powder from Pd spent catalyst is obtained in the course of grinding, hydrochloric acid or aqua regia leaching and cementation with iron. For the recovery of Pt and Re from Pt-Re spent catalyst, Pt and Re are leached with either HCI or aqua regia, first. Metallic Pt powder is recovered from the leach solution by cementation with Fe powder. Re in sulfide form is precipitated by the addition of sodium sulfide to the solution obtained after Pt recovery. It is found that 6N HCI can be successfully used as leaching agent for both types of spent catalyst. 6N HCI is considered to be better than aqua regia in consideration of reagent and equipment cost.

• Resources Recycling
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• v.24 no.4
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• pp.12-21
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• 2015

Almost all copper slags contain a considerable amount of Cu (0.5 - 3.7%) close to or even higher than copper ores. A number of methods for metal recovery from copper slag were reported These methods can be classified into three categories, flotation, leaching and roasting. Sulfide flotation method for the recovery of copper from Kazahstan copper furnace slag is discussed in this investigation. 50% of copper from the slag was recovered by sulfide flotation at pH 4. meanwhile 67% of copper from the slag was recovered at pH 11. Higher copper recovery result at pH 11 rather than that at pH 4 was caused by the fact that copper sulfides were floated in particle size fraction over $100{\mu}m$ in concentrates at pH 11. When the slag were ground below $74{\mu}m$by ball milling, the recovery of copper by floation in slag improved to 78 - 83% because of copper liberation effect.