• Title/Summary/Keyword: 황화철

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A Study of Hexavalent Chromium Reduction by Iron Sulfide (황화철에 의한 6가 크롬의 환원에 관한 연구)

  • Jo, Se-I;Park, Jae-Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.6
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    • pp.657-662
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    • 2005
  • Iron sulfide(FeS) is significantly produced through both abiotic and biotic processes in natural sediments and pore waters. In this study, chromium(VI) reaction with iron sulfide at various initial concentrations and at pH values of 4 and 8 was conducted to better understand the interactions between Cr(VI) and Fe(II) species dissolved from iron sulfide in both the aqueous and solid phases. Also, the removal efficiency of iron sulfide was compared with zero valent iron and other iron bearing oxides such as ${\alpha}-Fe_2O_3$, ${\alpha}-FeOOH$ and $Fe_3O_4$. The Cr(VI) removal rate by iron sulfide was higher at pH 4 than at pH 8 because more dissolved Fe(II) existed at pH 4 than at pH 8. Chromium and iron(oxyhydroxide) could be identified on the iron sulfide surface with transmission microscopy imaging and energy dispersive spectroscopy. The removal capacity of iron sulfide was much higher than zero valent iron and other iron oxide minerals due to the synergic effect of hydrogen sulfide and ferrous iron.

Study of Corrosion Characteristics of Corroded Iron Objects from Underwater by Sulfides (해저 철제유물의 황화물에 의한 부식특성 연구)

  • Kim, Taek Joon;Wi, Koang Chul
    • Journal of Conservation Science
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    • v.29 no.2
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    • pp.187-196
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    • 2013
  • This study is on the corrosion of iron objects caused by sulfides in undersea environment. The corrosion state of objects in seawater and their damage state after underwater and left in highly humid air were studied. The samples of this study were four iron objects which had been taken out from undersea mud layer located in Taean Mado, Chungcheongnamdo. SEM-EDS and XRD analyse on the objects to check whether they have sulfides or not. The result of analysis suggested that the major component of corrosion product generated in undersea deposit soil is sulfur(S) and iron sulfide(FeS) is formed as sulfide. However, there was no clear corrosion on the surface of objects which was exposed to sea water because of the impact of concretion which covered the surface. In order to check the damage status of iron objects after they had been taken out of sea water, exposure tests in high humidity environment and dehumidified environment were done on the corrosion products. The result of the test suggested that the oxidization of iron sulfide corrosion product makes iron sulfate ($FeSO_4$) and sulfuric acid ($H_2SO_4$) and they can cause secondary corrosion of iron objects. Therefore, it is believed that the iron sulfide corrosion product of iron objects taken out from underwater environment should be removed by all means and the keeping environment of the iron objects should also maintain dehumidified state.

Difference in Bonding Strength of RMGIC according to Type of Hemostatic Agent in Primary Tooth (지혈제의 종류에 따른 레진 강화형 글라스아이오노머 시멘트 결합력의 차이)

  • Back, Seolah;Lee, Joonhaeng;Kim, Jongbin;Han, Miran;Kim, Jong Soo
    • Journal of the korean academy of Pediatric Dentistry
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    • v.48 no.4
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    • pp.460-466
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    • 2021
  • The purpose of this study was to compare the effect of the hemostatic agent containing aluminum chloride with hemostatic agent containing ferric sulfate on the shear bond strength of resin-modified glass ionomer cement(RMGIC) to dentin in primary tooth. Twenty extracted non-carious human primary teeth were collected in this study. The specimens were cut to expose dentin and polished. The specimens were randomly seperated into 3 groups for treatment; group I: polyacrylic acid(PAA), RMGIC; group II: aluminum chloride, PAA, RMGIC; group III: ferric sulfate, PAA, RMGIC Ten specimens from each group were subjected to shear bond strength test. The mean shear bond strength of each group was as follows: 10.07 ± 1.83 MPa in Group I, 7.62 ± 0.78 MPA in group II, 5.23 ± 0.78 MPa in group III. There were significant differences among all groups(p < 0.001). In conclusion, both aluminum chloride hemostatic agent and ferric sulfate hemostatic agent decreased the shear bond strength of RMGIC to dentin. And ferric sulfate hemostatic agent decreased the shear bond strength of RMGIC more than the aluminium chloride hemostatic agent.

A Study for Reductive Degradation and Surface Characteristics of Hexachloroethane by Iron Sulfide ($FeS,\;FeS_{2}$) (황화철($FeS,\;FeS_{2}$)을 이용한 헥사클로로에탄의 환원적 분해반응과 표면특성에 관한 연구)

  • Park Sang-Won;Kim Sung-Kuk;Heo Jae-Eun
    • Journal of Soil and Groundwater Environment
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    • v.11 no.5
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    • pp.35-42
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    • 2006
  • The following results were obtained in the reductive degradation of hexachloroethane (HCA), and surface characteristics by using iron sulfide ($FeS,\;FeS_{2}$) mediators. HCA was degraded to pentachloroethane (PCA), tetrachloroethylene(PCE), trichloroethylene(TCE) and cis-l,2-dichloroethylene (cis-1,2-DCE) by complicated pathways such as hydrogenolysis, dehaloelimination and dehydrohalogenation. FeS had more rapid degradation rates of organic solvent than $FeS_{2}$. In liquidsolid reaction, the reaction rates of organic solvents were investigated to explain surface characteristics of FeS and $FeS_{2}$.. To determine surface characteristics of FeS and $FeS_{2}$, the specific surface area and surface potential of each mineral was determined and the hydrophilic site ($N_{s}$) was calculated. The specific surface area ($107.0470m^{2}/g\;and\;92.6374m^{2}/g$) and the $pH_{ZPC}$ of minerals ($FeS\;PH_{ZPC}=7.42,\;FeS_{2},\;PH_{ZPC}=7.80$) were measured. The results showed that the Ns of FeS and $FeS_{2}$ were $0.053\;site/mm^{2}\;and\;0.205\;site/mm^{2}$, respectively. $FeS_{2}$ had more hydrophilic surface than FeS. In other words, FeS have more hydrophobic surface site than $FeS_{2}$.

교육기관의 마케팅 패러다임 변화에 대한 고찰

  • Hwang, Hwa-Cheol
    • Journal of Global Scholars of Marketing Science
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    • v.2
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    • pp.261-280
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    • 1998
  • 본 연구는 비영리기관인 교육기관에 있어서 마케팅 패러다임이 어떻게 변화되고 있는지에 대한 포괄적인 내용을 검토해 보는데 주안점을 두고 있다. 마케팅개념이 주로 영리기관을 중심으로 소비자의 욕구만족이라는 개념으로 받아들여져 기업은 내적으로 효율적인 생산과 제품에 초점을 두는 경영철학을 견지하면서 기존의 마케팅 패러다임인 마케팅믹스 사고로 접근해 왔다. 그러나 최근 기업이 성장 발전하기 위해서는 고객의 현재적 욕구뿐만 아니라 잠재적 욕구까지도 미리 찾아내어 충족시킴으로 고객을 창조하고 더 나아가 고객을 감동시키고 지속적 관계유지를 위한 마케팅 패러다임으로 이동하고 있다. 비영리기관인 교육기관에 있어서도 마케팅개념의 도입과 전개과정은 영리기관의 마케팅패러다임의 변화와 일치하고 있다. 본 연구에서는 교육기관에 있어서 기존의 마케팅믹스 사고로 접근한 비영리 마케팅과 서비스마케팅을 재음미 해보고 새로운 통찰력을 제시해 주고 있는 마케팅패러다임의 변화와 새롭게 등장한 관계마케팅을 비영리기관인 교육기관에의 적용에 대해서 향후 구체적 연구에 대하여 문제제기를 하고 있다는 점에서 큰 의의를 찾을 수 있다.

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A model of internet customer long-term orientation: The moderating effect of relationship length (인터넷 이용고객의 장기지향성에 대한 탐색적 연구 -관계기간의 조절효과-)

  • Hwang, Hwa-Cheol;Suh, Yong-Han
    • Journal of Global Scholars of Marketing Science
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    • v.7
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    • pp.147-165
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    • 2001
  • To sustain successful relations with its customers, an internet business enterprise has to understand precisely the difference between customers' behaviour and their purchasing behaviour pattern on its customer basis. For this purpose, I closely looked into what difference there was between a leading variable which had an effect on internet customer long-term orientation and a special variable depending on period of transactions To prove this research, I analyzed collected data in which customers had experienced in shopping at internet shopping mall and discussed strategic current issues about its analytic results.

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Evaluaton of Corrosion-resistant Alloys for Safety Metal Filter of IGCC System (석탄가스 정제를 위한 safety filter 제작용 내식 합금의 평가)

  • 박영철;최주홍
    • Journal of Energy Engineering
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    • v.10 no.2
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    • pp.132-139
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    • 2001
  • 석탄가스화 복합발전의 집진 공정에 사용하기 위한 금속제 safety filter의 재질 선정을 위하여 황화수소 가스 분위기에서 합금강의 부식 특성을 규명하였다. 사용 합금강은 SUS 310, SUS 316, Inconel 600과 Hastelloy X이다. 전기로 내에 설치된 지름 50mm의 qualtz 튜브 반응기에서 부식실험이 행하여졌다. 40$0^{\circ}C$부터 $700^{\circ}C$까지의 등은 조건에서 실험이 행하여졌고, 분위기 가스의 영향을 보기 위하여 H$_2$S 가스를 함유한 $N_2$(dry), $N_2$(saturation), $CO_2$(dry), 그리고 석탄가스 분위기에서 실험하였다. 부식 생성물을 파악하기 위하여 X-ray 회절기와 주사전자현미경 분석이 함께 이루어졌다. 1.7% H$_2$S, $600^{\circ}C$ 이하 온도 조건에서는 니켈계 내식강 중 Hastelloy X와 철계 내식강 중 SUS 310 등 고크롬 합금강이 IGCC 용 필터 소재 금속으로서 높은 내부식성을 나타내었다. 0.3%~4.99% 황화수소 농도 범위에서 황화수소 농도 변화에 따라서 SUS 310의 경우 3~237mg/d$m^2$.day, Inconel 600의 경우 4~660mg/d$m^2$.day로 부식속도는 크게 증가되었다. 50$0^{\circ}C$, 석탄가스 분위기에서 부식속도는 SUS 310은 45mg/d$m^2$.day, SUS 316은 110mg/d$m^2$.day, Inconel 600은 576mg/d$m^2$.day, 그리고 Hastelloy X 는 140mg/d$m^2$.day로서 합금강 시편 중 SUS 310 합금강이 가장 우수한 내식성을 나타내었다. 부식 표면에는 황화니켈, 황화철 피막이 형성되었다.

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A Note on the Unification on Retail Trade Terminology (소매업태 용어 통일화에 대한 소고)

  • Kwon, Oh-cheul;Kim, Jin-seong;Kim, Pan-jun;Kim, Pan-jin;Kim, Hong-seop;Namkung, Suk;Park, Yeung-kurn;Park, Chul-ju;Park, Hyoung-jin;Youn, Myoung-kil;Lee, Jang-hwan;Hwang, Hwa-cheol;Kim, Yoo-oh
    • Journal of Distribution Science
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    • v.5 no.2
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    • pp.5-16
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    • 2007
  • The objective of the research which it sees is the unification regarding a retail trade terminology. It prevented the confusion of the terminology against retail business area and in order to arrange a terminology definition in domestic retail trade origination properly. This research took charge of from distribution terminology definition commission. in korea distribution science association. The terminology which is defined with Department store, Super Market, Specialty Store, Convenience Store, Drug Store, Non Store Retailing, Discount Store, Shopping Center, shopping street, Market.

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