• Title/Summary/Keyword: 황변현상

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Qualitative Development of Herbicide Use in Crop Production -On the Compatibility of Herbicide Use in Soybean Production (농약(제초제)의 품질개발에 관한 연구 -대두 제초제의 사용 적합성을 중심으로)

  • Guh, J.O.;Kim, Y.J.;Choi, W.Y.
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.24 no.2
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    • pp.89-103
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    • 1979
  • The compatibility of herbicide use for soybean cultivation was evaluated from the field and pot trials. Comparing with the check plot, the effects of herbicides at their several doses on the phytotoxic stability of crop plants and on the weeding efficacy were studied. Statistically significant differences were found among the doses, and not among herbicides and interactions between herbicide and dose. Risks on the compatibility for crop plant and weeding efficacy were recognized from the excess-dosed treatments of herbicides tried.

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Improvement of Brightness in UV Curing Type Prism Sheet by Using Aromatic Groups (방향족 도입에 의한 자외선 경화형 프리즘시트의 휘도 개전)

  • Kim, Dong-Ryoul;Kim, Hyung-Il
    • Polymer(Korea)
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    • v.33 no.5
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    • pp.413-419
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    • 2009
  • As the refractive index of the prism layer becomes higher, the optical performance of the prism sheet gets better and the efficiency of the LCD backlight unit is improved. In order to increase the refractive index of the prism layer, the ultraviolet curing type resins were prepared by mixing high refractive index materials containing aromatic groups and the multi-functional reactive diluents. By using 9,9-bis [4-(2-acryloyloxyethoxy)phenyl] fluorene, the refractive index of the prism layer was increased up to 1.58 and the brightness of the backlight unit was improved. Since the light source used in the backlight unit caused the yellowing in the prism sheet and deteriorated the brightness accordingly, the hindered amine light stabilizer was used to improve the yellowing resistance successfully.

Blue (InGaN/GaN) 파장이 백색 LED신뢰성에 미치는 영향

  • Han, Sang-Ho;Kim, Yun-Jung;Kim, Jeong-Hyeon;Jeong, Jong-Yun;Kim, Hyeon-Cheol;;Jo, Gwang-Seop
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.356-356
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    • 2012
  • InGaN/GaN로 제작된 Blue chip의 파장에 따른 백색 LED의 성능 저하를 전기적, 광학적 특성을 고려하여 조사하였다. 4가지 파장으로 제작된 백색 LED Sample들은 60 mA, 75 mA, 90 mA의 주입 전류로 장 시간동안 스트레스를 주었다. 또한 형광체가 없는 상태와 있는 상태를 구분하여 패키지의 감쇠 특성을 확인하였다. Blue 피크 파장 437 nm, 주입전류 90 mA, 형광체가 있는 상태와 형광체가 없는 상태에서 패키지의 출력 광세기는 각각 20%, 36%까지 감소하였다. 이는 Blue Chip에서 출력되는 단파장이 페키지 몰드의 노화(황변)현상에 직접적인 영향을 주기 때문이다. 전기적 특성은 Blue chip의 파장영역에 의존하지 않고, 스트레스 시간에 따른 LED내부 저항이 커지는 현상을 확인하였다. 따라서 InGaN/GaN로 제작된 백색 LED의 장 수명을 얻기 위해서는 Blue chip의 출력 파장 영역과 페키지 몰드 재료 특성의 신뢰성 관계가 중요하다.

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Performance Evaluation of Laminated-Tempered Glass as a Component of Noise Barrier on Metro Railway Elevated Bridge Against Train Induced Vibration and Wind Load (지하철 고가교 접합강화유리 방음판의 열차진동 및 풍하중에 대한 성능평가)

  • Kim, Suk-Su;Lee, Ho-Beom;Song, Jae-Ho
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.5
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    • pp.30-41
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    • 2017
  • Types of noise barrier installed for noise attenuation are largely divided into noise-absorbing format and noise-proofing format. In these days, installation of transparent noise barrier is general trend to solve problems that hinder sunshine and landscape. Some kinds of transparent boards are used to one of components in noise barriers, but in some cases, less transparency and worse pollution due to yellowing phenomena, and severe material deformation are to harm the urban aesthetics Therefore laminated-tempered glass board in that yellowing phenomena does not occur can be replaced as a transparent one to secure those shortcomings. In this paper, the structural safety against train induced vibration and the resistibility to wind load are analyzed for laminated-tempered glass system as a component of noise barrier installed on Metro railway elevated bridges. Also the appropriateness is evaluated through flexural bending performance test, compressive strength test, modulus of elasticity tests, and impact test for the system or the glass material itself. All of these processes are intended to present the deployment of logic to evaluate the adequacy for the system.

An Experimental Study of Metal Polishes Applied on Surface Cleaning of Silver Metal Archival Objects (은제 행정박물의 표면 클리닝에 적용되는 금속광택제 실험연구)

  • Cho, Ha Nui;Cho, Nam Chul
    • Journal of Conservation Science
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    • v.30 no.2
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    • pp.157-168
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    • 2014
  • This study, by selecting 3 kinds(Polish T, H, C) of metal polish being frequently used for silver archival objects treatment at present, a polish having excellent conservative property that minimizes damage of silver surface while effectively removing its yellow discolored layer by each using tool was intended to be discovered by comparing performance of tarnish inhibitor, corrosion inhibitor contained in each polish. As a result of analysis, it was confirmed that specimen that was cleaned with cotton swab and lint-free wipe by using Polish C provides not only uniformed surface expression and minimum damage but also removal function of corrosion layer. In addition, even though tarnish inhibition film should be formed after polish treatment, discolored phenomenon is unable to be prevented but among those polishes, Polish C was represented to be most stable against UV and yellowing and it showed relatively better features than that of Polish H and T in terms of hydrophobic, dispersive property. Through this, it is confirmed that Polish C would show the most excellent performance among polishes being used for conserving silver archival objects.

A study on aging characteristics of epoxy resins for conservation treatment of cultural heritage by adding UV stabilizer (자외선 안정제 첨가에 따른 문화재 보존처리용 에폭시계수지의 노화특성 연구)

  • Jeong, Se-Ri;Cho, Nam-Chul
    • Analytical Science and Technology
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    • v.24 no.5
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    • pp.336-344
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    • 2011
  • The study attempted to find out any effect to prevent photo aging of epoxy resin used for conservation by way of adding UV stabilizer, one of plastic additives. Specimens were made by adding HALS and UVA UV stabilizer as each concentration to 3 kinds of epoxy resin, which are most frequently used for artifacts joining and restoration process, and aging effects were investigated through Color change, SEM, contact angle, FTIR analysis during UV aging experiments. Last, usage suitability was checked when UV stabilizer was added through Universal Tensile strength tester. In result, it is impossible to prevent decomposition of chemical structure in spite of adding UV stabilizer but in the case of epoxy A and R, it is believed that photo aging such as yellowing or crack can be minimized without giving a big influence to adhesive strength of epoxy resin through adding less than 0.1% of UVA. It is expected that above will solve photo aging problem of epoxy resin used for joining and restoration of artifacts and will extend its life as joining and restoration materials.

Deinking process of Old Newsprint(ONP) by using Modified Cellulase with synthesized copolymer (기능성 고분자를 이용한 수식 셀룰라아제의 폐 신문용지 탈묵에 관한 연구)

  • Kim, Honghyun;Kwak, Tae-Heon;Park, Jinwon;Park, Kwinam
    • Clean Technology
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    • v.10 no.4
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    • pp.195-201
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    • 2004
  • Cellulase was modified with copolymer with polyethylene(PE)/polypropylene(PP) oxide and maleic anhydride(MA) by maleylation reaction, and modified cellulase was applied to the reprocessing of old newsprint (ONP). Cellulase of modified cellulase enhanced the detachment of ink particles by fibrillation of fiber. The copolymer, which acted as the surfactant formed bubbles and removed the ink particles in the floatation process. Modified cellulase showed the same deinking ability without excess dosage compared with the conventional method. And, it improved the physical properties including tensile strength, brightness, and whiteness compared with the conventional deinking process. The bond between the ink and fiber got stronger as the storage time increased, and it became very difficult to remove the ink particle. But, modified cellulase increased the deinking ability by 41% compared with the conventional process at the experiment of the ONP for 1 year storage time. It removed the yellowing and increased the whiteness and brightness as well as tensile strength and internal bond strength.

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A Study of Usability of Micro Shell as a Filler for Restoration of Iron Objects (Micro Shell을 이용한 철기 문화재 복원용 충전제의 사용성 연구)

  • Lee, Hyunji;Wi, Koangchul
    • Conservation Science in Museum
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    • v.27
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    • pp.91-102
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    • 2022
  • Silica-based inorganic fillers for restoration of iron objects have been used for the reduction of thermal expansivity and the improvement of melt flow index. However, the higher the amount of filler is applied, the more degradation of mechanical properties and the yellowing occur, which could cause retreatment of the objects with adding stress to them. Thus, research on not only the quantification of a mixture of resin and filler but also the yellowing should be emphasized. Experiments on mechanical properties were carried out with a silica-based light filler, Micro Shell as a comparison group. The results of the experiment showed Micro Shell reduced the number of occurrences of the yellowing by 34% compared to existing fillers. The value of adhesion and specific gravity was also improved depending on the filler amount. The results of this research indicate the possibility of using Micro Shell as a new filler.

Study on the Mixed Materials and Epoxy Materials for Restoration of Ceramics - chromaticity·porosity·sedimentary rate - (도자기 보존을 위한 복원제의 특성 연구 - 색도(色度)·기공률(氣孔率)·침전률(沈澱率)·황변도(黃變度)를 중심으로 -)

  • Lee, Haesoon
    • Conservation Science in Museum
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    • v.6
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    • pp.55-66
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    • 2005
  • Three types of epoxy resins (Epo-Tek 301, Araldite 103, and Araldite 106) and three types of pigments (bunche, pastel, and conté), which are materials for porcelain restoration, were selected as examination materials. The tone change, porosity, and sedimental resulting from the mixtures of varying ratios of these three materials were observed. Samples were also made from the mixture of Epo-teck 301, four kinds of white pigments, and six types of fillers and subjected to ultraviolet ray penetration for 200 hours to observe the oxidation of the epoxy resins. The result showed that the chemical composition of pastel drastically changed when mixed with Epo-tek 301. Although bunche and conté displayed clear colors, those of conté were less clear when it was mixed with other substances. Adding a small amount of Epo-tek 301 tended to be driven into the corner, whereas mixing a large amount caused saturation and boiling. On the other hand, AW 106 did not display clear colors owing to its high viscosity; when mixed in large amounts, however, the clarity of colors improved. For AY 103, a similar standard of color clarity was maintained regardless of the mixture ratio. The following was ranked according to the level of porosity: [Pastel>bunche≒conté]. In terms of sedimentary, however, [bunche>conté>Pastel], [Epo-tek 301> AY 103> AW 106]. The result of measuring the degree of yellowing revealed that titanium, pastel, silicon dioxide, and kaolin tended to turn yellow, whereas bunche, conté, diatomaceous earth, and calcium hydroxide tended to resist yellowing.

Study on the Development and Properties of Ceramics Restoration Purpose Urethane resin with Excellent Reversibility (가역성이 우수한 도자기 복원용 Urethane resin의 개발 및 물성에 대한 연구)

  • Oh, Seung Jun;Park, Gi Jung;Wi, Koang Chul
    • Journal of Conservation Science
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    • v.31 no.1
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    • pp.37-46
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    • 2015
  • In the case of adhesives & restoration agents currently being used for the preservation treatment of ceramics and earthenware, epoxy type, cellulose type and cellulose type are mainly being used. However, they are showing various problems such as re-detachment from severe contraction, color change from yellowing, work inconvenience of staining on tools and hand during usage and irreversibility. For the purpose of solving the issues of yellowing and irreversibility of epoxy resin being used to restore ceramics, urethane synthetic resin with low yellowing excellent reversibility has been developed in this study. The adhesive strength of urethane resin that has been developed has excellent properties with 2.07MPa for undiluted solution, which is 1.5 times higher than that of existing material EPO-$TEK301^{(R)}$ 1.21MPa. The result of workability measurement showed that the wear rate of urethane resin (in Talc 50wt%) was 1.09%, which was somewhat higher than that of existing material Quick $Wood^{(R)}$ (1.02%). In addition, its wear rate is two times higher than that of $EPO-TEK301^{(R)}$ (0.41%) and $L30^{(R)}$ (0.39%), thereby showing an advantage in its forming process compared to existing materials. As for the advantage of urethane resin of reversibility experiment, 12 hours after acetone, ethyl alcohol deposition, urethane resin and filler talc were dissolved 100% while showing powdering phenomenon. Compared to 0% reversibility of existing epoxy resin, it has much superior reversibility. The result of UV rays experiment to evaluate its durability showed that ${\Delta}E^*ab$ color change value based on undiluted solution of urethane resin was 2.76 before & after UV rays exposure, which was a decrease by about 7-20 times compared to that of existing resin, thereby minimizing the issue of heterogeneity.